Journal of Physical Chemistry A, volume 120, issue 40, pages 7847-7858
Mechanisms of Radiation-Induced Degradation of CFCl3 and CF2Cl2 in Noble-Gas Matrixes: An Evidence for "hot" Ionic Channels in the Solid Phase
Publication type: Journal Article
Publication date: 2016-09-30
Journal:
Journal of Physical Chemistry A
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.9
ISSN: 10895639, 15205215
Physical and Theoretical Chemistry
Abstract
The X-ray-induced transformations of simple chlorofluorocarbons (CFCl3 and CF2Cl2) in solid noble-gas matrixes (Ne, Ar, Kr, and Xe) at 7 K were studied in order to elucidate basic mechanisms of the radiation-chemical degradation with possible implications for stratospheric and extraterrestrial ice chemistry. The decomposition of parent molecules and formation of products were monitored by FTIR spectroscopy, and the identification was supported by ab initio calculations at the CCSD(T) level. It was shown that the ionic reaction channels were predominating in most cases (except for CF2Cl2/Xe system). The primary radical cations (CFCl3+• and CF2Cl2+•) are either stabilized in matrixes or undergo fragmentation to yield the corresponding secondary cations (CFCl2+, CCl3+, CF2Cl+) and halogen atoms. The probability of fragmentation through different channels demonstrates a remarkable matrix dependence, which was explained by the effect of excess energy resulting from the exothermic positive hole transfer from matrix atoms to freon molecules. A qualitative correlation between "hot" ionic fragmentation at low temperatures and gas-phase ion energetics was found. However, dissociative electron attachment leads to formation of neutral radicals (CFCl2• or CF2Cl•) and chloride anions. One more possible way of dissociative electron attachment in the case of CF2Cl2 is formation of CF2•• and Cl2-•. A general scheme of the radiation-induced processes is proposed.
Citations by journals
|
1
2
3
4
|
|
|
Radiation Physics and Chemistry
|
Radiation Physics and Chemistry
4 publications, 33.33%
|
|
Journal of Chemical Physics
|
Journal of Chemical Physics
3 publications, 25%
|
|
Physical Chemistry Chemical Physics
|
Physical Chemistry Chemical Physics
2 publications, 16.67%
|
|
Theoretical Chemistry Accounts
|
Theoretical Chemistry Accounts
1 publication, 8.33%
|
|
Journal of Physical Chemistry A
|
Journal of Physical Chemistry A
1 publication, 8.33%
|
|
Journal of Chemical Sciences
|
Journal of Chemical Sciences
1 publication, 8.33%
|
|
1
2
3
4
|
Citations by publishers
|
1
2
3
4
|
|
|
Elsevier
|
Elsevier
4 publications, 33.33%
|
|
American Institute of Physics (AIP)
|
American Institute of Physics (AIP)
3 publications, 25%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
2 publications, 16.67%
|
|
Springer Nature
|
Springer Nature
2 publications, 16.67%
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
1 publication, 8.33%
|
|
1
2
3
4
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","",""],"datasets":[{"label":"Citations number","data":[2,1,1,2,2,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["16.67","8.33","8.33","16.67","16.67","16.67","8.33","8.33"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Radiation Physics and Chemistry","Journal of Chemical Physics","Physical Chemistry Chemical Physics","Theoretical Chemistry Accounts","Journal of Physical Chemistry A","Journal of Chemical Sciences"],"ids":[14769,544,1773,19212,15255,13500],"codes":[0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp"],"datasets":[{"label":"","data":[4,3,2,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[33.33,25,16.67,8.33,8.33,8.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","American Institute of Physics (AIP)","Royal Society of Chemistry (RSC)","Springer Nature","American Chemical Society (ACS)"],"ids":[17,250,123,8,40],"codes":[0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp"],"datasets":[{"label":"","data":[4,3,2,2,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[33.33,25,16.67,16.67,8.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Shiryaeva E. S., Tyurin D. A., Feldman V. I. Mechanisms of Radiation-Induced Degradation of CFCl3 and CF2Cl2 in Noble-Gas Matrixes: An Evidence for "hot" Ionic Channels in the Solid Phase // Journal of Physical Chemistry A. 2016. Vol. 120. No. 40. pp. 7847-7858.
GOST all authors (up to 50)
Copy
Shiryaeva E. S., Tyurin D. A., Feldman V. I. Mechanisms of Radiation-Induced Degradation of CFCl3 and CF2Cl2 in Noble-Gas Matrixes: An Evidence for "hot" Ionic Channels in the Solid Phase // Journal of Physical Chemistry A. 2016. Vol. 120. No. 40. pp. 7847-7858.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.jpca.6b07301
UR - https://doi.org/10.1021%2Facs.jpca.6b07301
TI - Mechanisms of Radiation-Induced Degradation of CFCl3 and CF2Cl2 in Noble-Gas Matrixes: An Evidence for "hot" Ionic Channels in the Solid Phase
T2 - Journal of Physical Chemistry A
AU - Shiryaeva, Ekaterina S
AU - Tyurin, Daniil A
AU - Feldman, Vladimir I.
PY - 2016
DA - 2016/09/30 00:00:00
PB - American Chemical Society (ACS)
SP - 7847-7858
IS - 40
VL - 120
SN - 1089-5639
SN - 1520-5215
ER -
Cite this
BibTex
Copy
@article{2016_Shiryaeva,
author = {Ekaterina S Shiryaeva and Daniil A Tyurin and Vladimir I. Feldman},
title = {Mechanisms of Radiation-Induced Degradation of CFCl3 and CF2Cl2 in Noble-Gas Matrixes: An Evidence for "hot" Ionic Channels in the Solid Phase},
journal = {Journal of Physical Chemistry A},
year = {2016},
volume = {120},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021%2Facs.jpca.6b07301},
number = {40},
pages = {7847--7858},
doi = {10.1021/acs.jpca.6b07301}
}
Cite this
MLA
Copy
Shiryaeva, Ekaterina S., et al. “Mechanisms of Radiation-Induced Degradation of CFCl3 and CF2Cl2 in Noble-Gas Matrixes: An Evidence for "hot" Ionic Channels in the Solid Phase.” Journal of Physical Chemistry A, vol. 120, no. 40, Sep. 2016, pp. 7847-7858. https://doi.org/10.1021%2Facs.jpca.6b07301.