Journal of Chemical Physics, volume 139, issue 12, pages 124315
Photolabile xenon hydrides: A case study of HXeSH and HXeH
Publication type: Journal Article
Publication date: 2013-09-28
Journal:
Journal of Chemical Physics
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.4
ISSN: 00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
The photo-induced transformations of HXeSH and HXeH under the action of IR and visible light have been studied using FTIR spectroscopy. The xenon hydrides were produced by the X-ray induced decomposition of H2S and its isotopomers in a solid xenon matrix at 7.5 K followed by thermal annealing at the temperatures up to 45 K. Selective IR-induced photodissociation of HXeSH at 3500–2500 cm−1 was attributed to vibrational excitation of the 3νH–Xe mode. The IR-photodecomposed HXeSH molecules can be almost quantitative recovered below 22 K with very small effective activation energy (∼20 meV) indicating local character of this process. Analysis of the photoactivity of xenon hydrides in the visible region revealed previously unknown absorptions for HXeSH (in the region of 400–700 nm) and HXeH (above 700 nm). The decomposition of HXeH occurs due to both direct photolysis and reactions of “hot” H atoms produced from the photodissociation of HXeSH. The efficiency of thermal recovery for both xenon hydrides after photolysis with visible light was found to be dependent on the excitation wavelength, which was explained by the effect of photon energy on spatial distribution of the dissociation fragments.
Citations by journals
|
1
2
3
4
5
6
7
|
|
|
Physical Chemistry Chemical Physics
|
Physical Chemistry Chemical Physics
7 publications, 23.33%
|
|
Journal of Physical Chemistry A
|
Journal of Physical Chemistry A
4 publications, 13.33%
|
|
Journal of Computational Chemistry
|
Journal of Computational Chemistry
3 publications, 10%
|
|
Chemical Physics Letters
|
Chemical Physics Letters
2 publications, 6.67%
|
|
Radiation Physics and Chemistry
|
Radiation Physics and Chemistry
2 publications, 6.67%
|
|
ChemPhysChem
|
ChemPhysChem
2 publications, 6.67%
|
|
International Journal of Quantum Chemistry
|
International Journal of Quantum Chemistry
2 publications, 6.67%
|
|
Journal of Chemical Physics
|
Journal of Chemical Physics
1 publication, 3.33%
|
|
Journal of Molecular Spectroscopy
|
Journal of Molecular Spectroscopy
1 publication, 3.33%
|
|
ChemistrySelect
|
ChemistrySelect
1 publication, 3.33%
|
|
ChemistryOpen
|
ChemistryOpen
1 publication, 3.33%
|
|
New Journal of Chemistry
|
New Journal of Chemistry
1 publication, 3.33%
|
|
RSC Advances
|
RSC Advances
1 publication, 3.33%
|
|
Chemical Society Reviews
|
Chemical Society Reviews
1 publication, 3.33%
|
|
1
2
3
4
5
6
7
|
Citations by publishers
|
2
4
6
8
10
|
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
10 publications, 33.33%
|
|
Wiley
|
Wiley
9 publications, 30%
|
|
Elsevier
|
Elsevier
5 publications, 16.67%
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
4 publications, 13.33%
|
|
American Institute of Physics (AIP)
|
American Institute of Physics (AIP)
1 publication, 3.33%
|
|
2
4
6
8
10
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","","","","","",""],"datasets":[{"label":"Citations number","data":[1,3,9,5,1,1,2,3,1,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["3.33","10","30","16.67","3.33","3.33","6.67","10","3.33","6.67","3.33","3.33"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Physical Chemistry Chemical Physics","Journal of Physical Chemistry A","Journal of Computational Chemistry","Chemical Physics Letters","Radiation Physics and Chemistry","ChemPhysChem","International Journal of Quantum Chemistry","Journal of Chemical Physics","Journal of Molecular Spectroscopy","ChemistrySelect","ChemistryOpen","New Journal of Chemistry","RSC Advances","Chemical Society Reviews"],"ids":[1773,15255,423,5579,14769,16306,15897,544,14718,8021,23757,1404,3100,20586],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp"],"datasets":[{"label":"","data":[7,4,3,2,2,2,2,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[23.33,13.33,10,6.67,6.67,6.67,6.67,3.33,3.33,3.33,3.33,3.33,3.33,3.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Royal Society of Chemistry (RSC)","Wiley","Elsevier","American Chemical Society (ACS)","American Institute of Physics (AIP)"],"ids":[123,11,17,40,250],"codes":[0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp"],"datasets":[{"label":"","data":[10,9,5,4,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[33.33,30,16.67,13.33,3.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Ryazantsev S. V., Kobzarenko A. V., Feldman V. I. Photolabile xenon hydrides: A case study of HXeSH and HXeH // Journal of Chemical Physics. 2013. Vol. 139. No. 12. p. 124315.
GOST all authors (up to 50)
Copy
Ryazantsev S. V., Kobzarenko A. V., Feldman V. I. Photolabile xenon hydrides: A case study of HXeSH and HXeH // Journal of Chemical Physics. 2013. Vol. 139. No. 12. p. 124315.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1063/1.4822102
UR - https://doi.org/10.1063%2F1.4822102
TI - Photolabile xenon hydrides: A case study of HXeSH and HXeH
T2 - Journal of Chemical Physics
AU - Ryazantsev, Sergey V
AU - Kobzarenko, Alexey V
AU - Feldman, Vladimir I
PY - 2013
DA - 2013/09/28 00:00:00
PB - American Institute of Physics (AIP)
SP - 124315
IS - 12
VL - 139
SN - 0021-9606
SN - 1089-7690
ER -
Cite this
BibTex
Copy
@article{2013_Ryazantsev,
author = {Sergey V Ryazantsev and Alexey V Kobzarenko and Vladimir I Feldman},
title = {Photolabile xenon hydrides: A case study of HXeSH and HXeH},
journal = {Journal of Chemical Physics},
year = {2013},
volume = {139},
publisher = {American Institute of Physics (AIP)},
month = {sep},
url = {https://doi.org/10.1063%2F1.4822102},
number = {12},
pages = {124315},
doi = {10.1063/1.4822102}
}
Cite this
MLA
Copy
Ryazantsev, Sergey V., et al. “Photolabile xenon hydrides: A case study of HXeSH and HXeH.” Journal of Chemical Physics, vol. 139, no. 12, Sep. 2013, p. 124315. https://doi.org/10.1063%2F1.4822102.
Profiles