Radiation Physics and Chemistry, volume 85, pages 147-151

Reactions of excess electrons with "bridged" amidoesters in low-temperature matrices

Publication typeJournal Article
Publication date2013-04-01
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor2.9
ISSN0969806X
Radiation
Abstract
Abstract Structure of radical anions of “bridged” amidoesters MeOOC(CH2)nCONMe2 (n=0–3) generated by X-ray irradiation was investigated by EPR, optical absorption spectroscopy and quantum-chemical calculations. Amidoester-0 (n=0) has positive calculated electron affinity and the corresponding delocalized radical anion is stabilized independent of matrix polarity. Meanwhile, for amidoesters with n=1–3 groups possessing apparently negative intrinsic electron affinity the role of matrix in stabilization of the corresponding radical anions becomes crucial. Two types of the localized radical anions were observed in the latter case.

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Saenko E. V. et al. Reactions of excess electrons with "bridged" amidoesters in low-temperature matrices // Radiation Physics and Chemistry. 2013. Vol. 85. pp. 147-151.
GOST all authors (up to 50) Copy
Saenko E. V., Laikov D., Feldman V. I., Feldman V. I. Reactions of excess electrons with "bridged" amidoesters in low-temperature matrices // Radiation Physics and Chemistry. 2013. Vol. 85. pp. 147-151.
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RIS Copy
TY - JOUR
DO - 10.1016/j.radphyschem.2012.12.003
UR - https://doi.org/10.1016%2Fj.radphyschem.2012.12.003
TI - Reactions of excess electrons with "bridged" amidoesters in low-temperature matrices
T2 - Radiation Physics and Chemistry
AU - Saenko, Elizaveta V
AU - Laikov, Dimitri
AU - Feldman, Vladimir I
AU - Feldman, Vladimir I.
PY - 2013
DA - 2013/04/01 00:00:00
PB - Elsevier
SP - 147-151
VL - 85
SN - 0969-806X
ER -
BibTex
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BibTex Copy
@article{2013_Saenko,
author = {Elizaveta V Saenko and Dimitri Laikov and Vladimir I Feldman and Vladimir I. Feldman},
title = {Reactions of excess electrons with "bridged" amidoesters in low-temperature matrices},
journal = {Radiation Physics and Chemistry},
year = {2013},
volume = {85},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016%2Fj.radphyschem.2012.12.003},
pages = {147--151},
doi = {10.1016/j.radphyschem.2012.12.003}
}
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