Journal of Radioanalytical and Nuclear Chemistry, volume 284, issue 3, pages 641-645
An ESR study of radiation-chemical transformation of 4,4′(5′)- di-(tert-butylcyclohexano)-18-crown-6 and its solution in 1-octanol at 77 K
Publication type: Journal Article
Publication date: 2010-03-26
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 1.6
ISSN: 02365731, 15882780
Spectroscopy
Analytical Chemistry
Health, Toxicology and Mutagenesis
Public Health, Environmental and Occupational Health
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Radiology Nuclear Medicine and imaging
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Abstract
Paramagnetic products stabilized in both 4,4′(5′)-di-(tert-butylcyclohexano)-18-crown-6 (DtBuCH18C6) and its solution in 1-octanol upon low temperature (77 K) X-rays irradiation were studied by ESR spectroscopy. Macrocyclic –O–ĊH–CH2– radicals and acyclic O = C(H)–ĊH–O– radicals were found as main radiolysis products in neat DtBuCH18C6. Fraction of acyclic radicals resulting from the macrocycle cleavage was about 50%. No radical products resulted from t-Bu and cyclohexyl fragments were observed. It was concluded that the primary events were essentially concerned with ionization of the polyether moiety. Irradiation of frozen DtBuCH18C6 solutions in 1-octanol resulted in formation of radicals both from crown ether and alcohol.
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Radiation Physics and Chemistry
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Radiochimica Acta
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Journal of Radioanalytical and Nuclear Chemistry
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Physical Chemistry Chemical Physics
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1 publication, 20%
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Citations by publishers
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1
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Elsevier
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Elsevier
2 publications, 40%
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Walter de Gruyter
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1 publication, 20%
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Springer Nature
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Springer Nature
1 publication, 20%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 20%
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1
2
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Zakurdaeva O. A. et al. An ESR study of radiation-chemical transformation of 4,4′(5′)- di-(tert-butylcyclohexano)-18-crown-6 and its solution in 1-octanol at 77 K // Journal of Radioanalytical and Nuclear Chemistry. 2010. Vol. 284. No. 3. pp. 641-645.
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Zakurdaeva O. A., Nesterov S., Feldman V. I. An ESR study of radiation-chemical transformation of 4,4′(5′)- di-(tert-butylcyclohexano)-18-crown-6 and its solution in 1-octanol at 77 K // Journal of Radioanalytical and Nuclear Chemistry. 2010. Vol. 284. No. 3. pp. 641-645.
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TY - JOUR
DO - 10.1007/s10967-010-0529-1
UR - https://doi.org/10.1007%2Fs10967-010-0529-1
TI - An ESR study of radiation-chemical transformation of 4,4′(5′)- di-(tert-butylcyclohexano)-18-crown-6 and its solution in 1-octanol at 77 K
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Zakurdaeva, O A
AU - Nesterov, S.V.
AU - Feldman, V I
PY - 2010
DA - 2010/03/26 00:00:00
PB - Springer Nature
SP - 641-645
IS - 3
VL - 284
SN - 0236-5731
SN - 1588-2780
ER -
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@article{2010_Zakurdaeva,
author = {O A Zakurdaeva and S.V. Nesterov and V I Feldman},
title = {An ESR study of radiation-chemical transformation of 4,4′(5′)- di-(tert-butylcyclohexano)-18-crown-6 and its solution in 1-octanol at 77 K},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {2010},
volume = {284},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007%2Fs10967-010-0529-1},
number = {3},
pages = {641--645},
doi = {10.1007/s10967-010-0529-1}
}
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Zakurdaeva, O. A., et al. “An ESR study of radiation-chemical transformation of 4,4′(5′)- di-(tert-butylcyclohexano)-18-crown-6 and its solution in 1-octanol at 77 K.” Journal of Radioanalytical and Nuclear Chemistry, vol. 284, no. 3, Mar. 2010, pp. 641-645. https://doi.org/10.1007%2Fs10967-010-0529-1.
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