Electrochimica Acta, volume 354, pages 136761

Phase boundary propagation kinetics predominately limit the rate capability of NASICON-type Na3+xMnxV2-x(PO4)3 (0≤x≤1) materials

Anishchenko Dmitrii V ¹

Nikitina Victoria A. ²

Stevenson Keith J

Antipov Evgeny V.

Zakharkin Maxim V. ^{3, 4}

Stevenson Keith J ²

Antipov Evgeny V. ^{3, 4}

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Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1-3, Moscow 119991, Russia. |

Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Nobel Str.3, Moscow, 121205, Russia |

Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Nobel str. 3, Moscow, 121205, Russia |

⁴

Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow, 119991, Russia |

Publication type: Journal Article

Publication date: 2020-09-01

Elsevier

Journal: Electrochimica Acta

Quartile SCImago

Quartile WOS

Impact factor: 6.6

ISSN: 00134686

DOI: 10.1016/j.electacta.2020.136761

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General Chemical Engineering

Electrochemistry

Abstract

Abstract NASICON-type Na3V2(PO4)3 cathode materials can be regarded as promising candidates for high-power Na-ion batteries due to the observed facile kinetics of Na-ion de/intercalation. Substitution of V for Mn provides additional advantages related to the increase in the average operating potential and reduced cost of the active material. In this work, we explore the kinetics of Na+ intercalation into Mn-substituted Na3+xMnxV2-x(PO4)3 (x = 0, 0.1, 0.5, 1) materials with a primary focus on the impact of Mn content on the rate capability of the materials. We demonstrate that Mn substitution results in quite subtle changes in bulk ionic diffusivity and charge transfer rates, while more significant impact is observed on the nucleation kinetics, which induces large hysteresis between charge and discharge curves for Mn-rich materials. The increase in hysteresis between charge and discharge curves does not limit the specific energy retention at high C-rates significantly, yet the performance losses are mainly related to the slow phase boundary propagation for biphasic processes. The Mn-rich materials, which demonstrate wider single-phase regions, are shown to outperform the unsubstituted materials in terms of rate-capability and should be preferred for high-power applications.

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Citations by journals

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Electrochimica Acta	Electrochimica Acta, 3, 11.54% Electrochimica Acta 3 publications, 11.54%
Chemistry of Materials	Chemistry of Materials, 3, 11.54% Chemistry of Materials 3 publications, 11.54%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 2, 7.69% Journal of Materials Chemistry A 2 publications, 7.69%
ACS applied materials & interfaces	ACS applied materials & interfaces, 2, 7.69% ACS applied materials & interfaces 2 publications, 7.69%
ChemSusChem	ChemSusChem, 1, 3.85% ChemSusChem 1 publication, 3.85%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 3.85% ACS Applied Energy Materials 1 publication, 3.85%
Journal of Power Sources	Journal of Power Sources, 1, 3.85% Journal of Power Sources 1 publication, 3.85%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 3.85% Journal of Physical Chemistry C 1 publication, 3.85%
Nature Communications	Nature Communications, 1, 3.85% Nature Communications 1 publication, 3.85%
Current Opinion in Electrochemistry	Current Opinion in Electrochemistry, 1, 3.85% Current Opinion in Electrochemistry 1 publication, 3.85%
Journal of Environmental Chemical Engineering	Journal of Environmental Chemical Engineering, 1, 3.85% Journal of Environmental Chemical Engineering 1 publication, 3.85%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 1, 3.85% Journal of the Electrochemical Society 1 publication, 3.85%
Energies	Energies, 1, 3.85% Energies 1 publication, 3.85%
Solid State Ionics	Solid State Ionics, 1, 3.85% Solid State Ionics 1 publication, 3.85%
Progress in Materials Science	Progress in Materials Science, 1, 3.85% Progress in Materials Science 1 publication, 3.85%
Energy Storage Materials	Energy Storage Materials, 1, 3.85% Energy Storage Materials 1 publication, 3.85%
Advanced Functional Materials	Advanced Functional Materials, 1, 3.85% Advanced Functional Materials 1 publication, 3.85%
Advanced Energy and Sustainability Research	Advanced Energy and Sustainability Research, 1, 3.85% Advanced Energy and Sustainability Research 1 publication, 3.85%
Materials Futures	Materials Futures, 1, 3.85% Materials Futures 1 publication, 3.85%
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Citations by publishers

	1 2 3 4 5 6 7 8 9
Elsevier	Elsevier, 9, 34.62% Elsevier 9 publications, 34.62%
American Chemical Society (ACS)	American Chemical Society (ACS), 7, 26.92% American Chemical Society (ACS) 7 publications, 26.92%
Wiley	Wiley, 3, 11.54% Wiley 3 publications, 11.54%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 2, 7.69% Royal Society of Chemistry (RSC) 2 publications, 7.69%
Springer Nature	Springer Nature, 1, 3.85% Springer Nature 1 publication, 3.85%
The Electrochemical Society	The Electrochemical Society, 1, 3.85% The Electrochemical Society 1 publication, 3.85%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 3.85% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 3.85%
IOP Publishing	IOP Publishing, 1, 3.85% IOP Publishing 1 publication, 3.85%
	1 2 3 4 5 6 7 8 9

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Anishchenko D. V. et al. Phase boundary propagation kinetics predominately limit the rate capability of NASICON-type Na3+xMnxV2-x(PO4)3 (0≤x≤1) materials // Electrochimica Acta. 2020. Vol. 354. p. 136761.

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Anishchenko D. V., Zakharkin M. V., Nikitina V. A., Stevenson K. J., Antipov E. V., Stevenson K. J., Antipov E. V. Phase boundary propagation kinetics predominately limit the rate capability of NASICON-type Na3+xMnxV2-x(PO4)3 (0≤x≤1) materials // Electrochimica Acta. 2020. Vol. 354. p. 136761.

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TY - JOUR

DO - 10.1016/j.electacta.2020.136761

UR - https://doi.org/10.1016%2Fj.electacta.2020.136761

TI - Phase boundary propagation kinetics predominately limit the rate capability of NASICON-type Na3+xMnxV2-x(PO4)3 (0≤x≤1) materials

T2 - Electrochimica Acta

AU - Anishchenko, Dmitrii V

AU - Zakharkin, Maxim V.

AU - Nikitina, Victoria A.

AU - Stevenson, Keith J

AU - Antipov, Evgeny V.

AU - Stevenson, Keith J

AU - Antipov, Evgeny V.

PY - 2020

DA - 2020/09/01 00:00:00

PB - Elsevier

SP - 136761

VL - 354

SN - 0013-4686

ER -

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@article{2020_Anishchenko,

author = {Dmitrii V Anishchenko and Maxim V. Zakharkin and Victoria A. Nikitina and Keith J Stevenson and Evgeny V. Antipov and Keith J Stevenson and Evgeny V. Antipov},

title = {Phase boundary propagation kinetics predominately limit the rate capability of NASICON-type Na3+xMnxV2-x(PO4)3 (0≤x≤1) materials},

journal = {Electrochimica Acta},

year = {2020},

volume = {354},

publisher = {Elsevier},

month = {sep},

url = {https://doi.org/10.1016%2Fj.electacta.2020.136761},

pages = {136761},

doi = {10.1016/j.electacta.2020.136761}

}

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Publisher

Elsevier

Journal

Electrochimica Acta

Quartile SCImago

Quartile WOS

Impact factor

6.6

ISSN

00134686 (Print)

Labs

Laboratory of Materials for Electrochemical Processes

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