Open Access
Molecules, volume 26, issue 8, pages 2217
Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies
Publication type: Journal Article
Publication date: 2021-04-12
PubMed ID:
33921392
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
With the aim to find new efficient extractants for recovery of f-block elements from processing wastes of different origin, we have compared a series of phosphoryl-containing podands, including (2-(diphenylphosphorylmethoxy)phenyl)diphenylphosphine oxide 1 and its analogues 5–7, where the ArP(O)Ph2 group of phosphine oxide type is replaced by phosphonic fragments. Quantum-chemical modelling of the structures of phosphoryl-containing podands 1 and 5–7 has been performed, which was later confirmed by the data of X-ray diffraction. The features of extraction of nitric acid, as well as U(VI), Th(IV), Nd(III), and Ho(III) with compounds 1 and 5–7 from nitric acid media into 1,2-dichloroethane have been studied. The compositions of extracted complexes have been determined.
Citations by journals
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1
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Nanomaterials
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Nanomaterials
1 publication, 33.33%
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Russian Journal of General Chemistry
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Russian Journal of General Chemistry
1 publication, 33.33%
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1
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Citations by publishers
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1
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 33.33%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 33.33%
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1
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Safiulina A. et al. Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies // Molecules. 2021. Vol. 26. No. 8. p. 2217.
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Safiulina A., Borisova N. E., Grigoriev M. S., Baulin D. V., Baulin V., Tsivadze A. Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies // Molecules. 2021. Vol. 26. No. 8. p. 2217.
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TY - JOUR
DO - 10.3390/molecules26082217
UR - https://doi.org/10.3390%2Fmolecules26082217
TI - Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies
T2 - Molecules
AU - Safiulina, Alfiya
AU - Tsivadze, Aslan
AU - Baulin, Vladimir
AU - Borisova, Nataliya E.
AU - Grigoriev, Mikhail S.
AU - Baulin, Dmitriy V
PY - 2021
DA - 2021/04/12 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 2217
IS - 8
VL - 26
PMID - 33921392
SN - 1420-3049
ER -
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@article{2021_Safiulina,
author = {Alfiya Safiulina and Aslan Tsivadze and Vladimir Baulin and Nataliya E. Borisova and Mikhail S. Grigoriev and Dmitriy V Baulin},
title = {Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies},
journal = {Molecules},
year = {2021},
volume = {26},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {apr},
url = {https://doi.org/10.3390%2Fmolecules26082217},
number = {8},
pages = {2217},
doi = {10.3390/molecules26082217}
}
Cite this
MLA
Copy
Safiulina, Alfiya, et al. “Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies.” Molecules, vol. 26, no. 8, Apr. 2021, p. 2217. https://doi.org/10.3390%2Fmolecules26082217.