Organic Letters, volume 23, issue 11, pages 4173-4178

Rhodium-Catalyzed Denitrogenative Diazole–Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands

Publication typeJournal Article
Publication date2021-05-17
Journal: Organic Letters
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.2
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
1,4,8-Triazaocta-1,3,5,7-tetraenes, generated in situ by Rh2(Piv)4-catalyzed denitrogenative coupling of pyrazoles with 1-sulfonyl-1,2,3-triazoles, smoothly form 2,6,8-triazabicyclo[3.2.1]octa-3,6-dienes via intramolecular aza-Diels-Alder cycloaddition. This domino reaction, combined with the subsequent thermal or acid-catalyzed rearrangement of the cycloadducts, provides direct and flexible access to N-sulfonylated (Z)-2-(2-aminovinyl)imidazoles.

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Strelnikova J. O. et al. Rhodium-Catalyzed Denitrogenative Diazole–Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands // Organic Letters. 2021. Vol. 23. No. 11. pp. 4173-4178.
GOST all authors (up to 50) Copy
Strelnikova J. O., Koronatov A., Rostovskii N. V., Khlebnikov A. F., Khoroshilova O. V., Kryukova M. A., Novikov M. S. Rhodium-Catalyzed Denitrogenative Diazole–Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands // Organic Letters. 2021. Vol. 23. No. 11. pp. 4173-4178.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.1c01092
UR - https://doi.org/10.1021%2Facs.orglett.1c01092
TI - Rhodium-Catalyzed Denitrogenative Diazole–Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands
T2 - Organic Letters
AU - Strelnikova, Julia O
AU - Rostovskii, Nikolai V
AU - Khlebnikov, Alexander F
AU - Novikov, Mikhail S.
AU - Koronatov, Aleksandr
AU - Khoroshilova, Olesya V
AU - Kryukova, Mariya A
PY - 2021
DA - 2021/05/17 00:00:00
PB - American Chemical Society (ACS)
SP - 4173-4178
IS - 11
VL - 23
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
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BibTex Copy
@article{2021_Strelnikova,
author = {Julia O Strelnikova and Nikolai V Rostovskii and Alexander F Khlebnikov and Mikhail S. Novikov and Aleksandr Koronatov and Olesya V Khoroshilova and Mariya A Kryukova},
title = {Rhodium-Catalyzed Denitrogenative Diazole–Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands},
journal = {Organic Letters},
year = {2021},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021%2Facs.orglett.1c01092},
number = {11},
pages = {4173--4178},
doi = {10.1021/acs.orglett.1c01092}
}
MLA
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MLA Copy
Strelnikova, Julia O., et al. “Rhodium-Catalyzed Denitrogenative Diazole–Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands.” Organic Letters, vol. 23, no. 11, May. 2021, pp. 4173-4178. https://doi.org/10.1021%2Facs.orglett.1c01092.
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