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Acta Crystallographica Section E: Crystallographic Communications, volume 77, issue 6, pages 588-591

Synthesis and crystal structures of N-H, N-phenyl and N-benzyl-2-(4-hexyloxyphenyl)benzimidazoles

Publication typeJournal Article
Publication date2021-05-14
Quartile SCImago
Q3
Quartile WOS
Impact factor0.6
ISSN20569890
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract

The title compounds, 2-(4-hexyloxyphenyl)-1H-benzimidazole (C19H22N2O; 1), 2-(4-hexyloxyphenyl)-1-phenyl-1H-benzimidazole (C25H26N2O; 2) and 1-benzyl-2-(4-hexyloxyphenyl)-1H-benzimidazole (C26H28N2O; 3) were synthesized and their structures were determined by single-crystal X-ray analysis. The N-substituent at the imidazole moiety slightly affects the interplanar angle between the 4-hexyloxyphenyl ring and the benzimidazole system. The unsubstituted benzimidazole (1) forms intermolecular N—H...N bonds while in the crystal structures of 2 and 3, the molecules are assembled only through π–π and C—H...π interactions.

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Smirnov D. E. et al. Synthesis and crystal structures of N-H, N-phenyl and N-benzyl-2-(4-hexyloxyphenyl)benzimidazoles // Acta Crystallographica Section E: Crystallographic Communications. 2021. Vol. 77. No. 6. pp. 588-591.
GOST all authors (up to 50) Copy
Smirnov D. E., Tatarin S. V., Bezzubov S. I. Synthesis and crystal structures of N-H, N-phenyl and N-benzyl-2-(4-hexyloxyphenyl)benzimidazoles // Acta Crystallographica Section E: Crystallographic Communications. 2021. Vol. 77. No. 6. pp. 588-591.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1107/S2056989021004898
UR - https://doi.org/10.1107%2FS2056989021004898
TI - Synthesis and crystal structures of N-H, N-phenyl and N-benzyl-2-(4-hexyloxyphenyl)benzimidazoles
T2 - Acta Crystallographica Section E: Crystallographic Communications
AU - Smirnov, Daniil E.
AU - Tatarin, Sergei V.
AU - Bezzubov, Stanislav I.
PY - 2021
DA - 2021/05/14 00:00:00
PB - International Union of Crystallography (IUCr)
SP - 588-591
IS - 6
VL - 77
PMID - 34164139
SN - 2056-9890
ER -
BibTex |
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BibTex Copy
@article{2021_Smirnov
author = {Daniil E. Smirnov and Sergei V. Tatarin and Stanislav I. Bezzubov},
title = {Synthesis and crystal structures of N-H, N-phenyl and N-benzyl-2-(4-hexyloxyphenyl)benzimidazoles},
journal = {Acta Crystallographica Section E: Crystallographic Communications},
year = {2021},
volume = {77},
publisher = {International Union of Crystallography (IUCr)},
month = {may},
url = {https://doi.org/10.1107%2FS2056989021004898},
number = {6},
pages = {588--591},
doi = {10.1107/S2056989021004898}
}
MLA
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MLA Copy
Smirnov, Daniil E., et al. “Synthesis and crystal structures of N-H, N-phenyl and N-benzyl-2-(4-hexyloxyphenyl)benzimidazoles.” Acta Crystallographica Section E: Crystallographic Communications, vol. 77, no. 6, May. 2021, pp. 588-591. https://doi.org/10.1107%2FS2056989021004898.
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