Russian Journal of Inorganic Chemistry, volume 64, issue 11, pages 1418-1423
Oxidation of Iron Complex with NHC Ligand with Molecular Iodine
Publication type: Journal Article
Publication date: 2019-11-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 2.1
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Complex (η5-C5H5)2Fe2(CO)4 (I) reacts with 1,3-dimethylimidazolium-2-carboxylate Me2ImCO2 to give asymmetric binuclear carbene iron complex (η5-C5H5)2Fe2(CO)3(Me2Im) (II) (Me2Im = 1,3-dimethylimidazol-2-ylidene). The oxidation of compound II with elemental iodine proceeds via two mechanisms, symmetrical and asymmetrical, to form four products: (η5-C5H5Fe(CO)2(Me2Im)I (III), (η5-C5H5)Fe(CO)2I (IV), (η5-C5H5Fe(CO)2(Me2Im)I3 (V), and ferrocene (VI). In each case, two pairs of reaction products have formed, two of which include NHC ligand: neutral iron(III) complex and ionic complex V. Optimal synthesis conditions to obtain preferably one of these complexes have been found. Geometry and transition state energy of supposed reaction mechanism have been calculated by quantum chemistry methods.
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Shapovalov S. S. et al. Oxidation of Iron Complex with NHC Ligand with Molecular Iodine // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 11. pp. 1418-1423.
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Shapovalov S. S., Tikhonova O. G., Skabitskii I. V., Kolos A. V., Sakharov S. G., Torubaev Yu. V. Oxidation of Iron Complex with NHC Ligand with Molecular Iodine // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 11. pp. 1418-1423.
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TY - JOUR
DO - 10.1134/S0036023619110184
UR - https://doi.org/10.1134%2FS0036023619110184
TI - Oxidation of Iron Complex with NHC Ligand with Molecular Iodine
T2 - Russian Journal of Inorganic Chemistry
AU - Shapovalov, S S
AU - Tikhonova, O G
AU - Skabitskii, I V
AU - Kolos, A V
AU - Sakharov, S G
AU - Torubaev, Yu V
PY - 2019
DA - 2019/11/01 00:00:00
PB - Pleiades Publishing
SP - 1418-1423
IS - 11
VL - 64
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2019_Shapovalov,
author = {S S Shapovalov and O G Tikhonova and I V Skabitskii and A V Kolos and S G Sakharov and Yu V Torubaev},
title = {Oxidation of Iron Complex with NHC Ligand with Molecular Iodine},
journal = {Russian Journal of Inorganic Chemistry},
year = {2019},
volume = {64},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134%2FS0036023619110184},
number = {11},
pages = {1418--1423},
doi = {10.1134/S0036023619110184}
}
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Shapovalov, S. S., et al. “Oxidation of Iron Complex with NHC Ligand with Molecular Iodine.” Russian Journal of Inorganic Chemistry, vol. 64, no. 11, Nov. 2019, pp. 1418-1423. https://doi.org/10.1134%2FS0036023619110184.