Open Access
Symmetry, volume 13, issue 7, pages 1119
Encapsulation of rhodamine 6G dye molecules for affecting symmetry of supramolecular crystals of Melamine-Barbiturate
Nesterov Sergey
1
,
Shilovskikh Vladimir V.
1
,
Sokolov Alexander D
1
,
Timralieva Alexandra A.
1
,
Belogub Elena V.
3
,
Kondratyuk Nikolay D.
4, 5
,
Orekhov Nikita D
4, 5, 6
,
1
5
Publication type: Journal Article
Publication date: 2021-06-23
Chemistry (miscellaneous)
Physics and Astronomy (miscellaneous)
General Mathematics
Computer Science (miscellaneous)
Abstract
Supramolecular organic systems can be used as a host for the encapsulation of small organic molecules. Here, we chose melamine barbiturate as a robust system capable of supramolecular assembly and the Rhodamine 6G dye entrapment as a guest molecule. The encapsulation of the dye was investigated by UV-visible spectroscopy, SEM and optical fluorescent microscopy while the insight into the crystal structure of the system was obtained by single crystal and powder XRD. For investigation of the system’s properties on a molecular level, the DFT and Classical Molecular Dynamics methods were utilized. Surprisingly, both theoretical and experimental data show not only the successful encapsulation of Rhodamine 6G molecules inside the supramolecular assembly, but also that inclusion of such molecules leads to the drastic improvement in the organic crystal shape. The melamine barbiturate in presence of the Rhodamine 6G molecules tend to form crystals with lesser degree of twinning and higher symmetry in shape than the ones without dye molecules.
Citations by journals
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1
2
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Crystals
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Crystals
2 publications, 22.22%
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ACS Omega
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1 publication, 11.11%
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1 publication, 11.11%
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Coatings
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1 publication, 11.11%
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Nano Select
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1 publication, 11.11%
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Advanced Intelligent Systems
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1 publication, 11.11%
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1 publication, 11.11%
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1
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Citations by publishers
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1
2
3
4
5
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
5 publications, 55.56%
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Wiley
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Wiley
2 publications, 22.22%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 11.11%
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Elsevier
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Elsevier
1 publication, 11.11%
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1
2
3
4
5
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Nesterov S. et al. Encapsulation of rhodamine 6G dye molecules for affecting symmetry of supramolecular crystals of Melamine-Barbiturate // Symmetry. 2021. Vol. 13. No. 7. p. 1119.
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Nesterov S., Shilovskikh V. V., Sokolov A. D., Gurzhiy V. V., Novikov A. S., Timralieva A. A., Belogub E. V., Kondratyuk N. D., Orekhov N. D., Skorb E. V. Encapsulation of rhodamine 6G dye molecules for affecting symmetry of supramolecular crystals of Melamine-Barbiturate // Symmetry. 2021. Vol. 13. No. 7. p. 1119.
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TY - JOUR
DO - 10.3390/sym13071119
UR - https://doi.org/10.3390%2Fsym13071119
TI - Encapsulation of rhodamine 6G dye molecules for affecting symmetry of supramolecular crystals of Melamine-Barbiturate
T2 - Symmetry
AU - Timralieva, Alexandra A.
AU - Belogub, Elena V.
AU - Sokolov, Alexander D
AU - Orekhov, Nikita D
AU - Skorb, Ekaterina V
AU - Shilovskikh, Vladimir V.
AU - Nesterov, Sergey
AU - Gurzhiy, Vladislav V.
AU - Novikov, Alexander S.
AU - Kondratyuk, Nikolay D.
PY - 2021
DA - 2021/06/23 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 1119
IS - 7
VL - 13
SN - 2073-8994
ER -
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@article{2021_Nesterov,
author = {Alexandra A. Timralieva and Elena V. Belogub and Alexander D Sokolov and Nikita D Orekhov and Ekaterina V Skorb and Vladimir V. Shilovskikh and Sergey Nesterov and Vladislav V. Gurzhiy and Alexander S. Novikov and Nikolay D. Kondratyuk},
title = {Encapsulation of rhodamine 6G dye molecules for affecting symmetry of supramolecular crystals of Melamine-Barbiturate},
journal = {Symmetry},
year = {2021},
volume = {13},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {jun},
url = {https://doi.org/10.3390%2Fsym13071119},
number = {7},
pages = {1119},
doi = {10.3390/sym13071119}
}
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MLA
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Nesterov, Sergey, et al. “Encapsulation of rhodamine 6G dye molecules for affecting symmetry of supramolecular crystals of Melamine-Barbiturate.” Symmetry, vol. 13, no. 7, Jun. 2021, p. 1119. https://doi.org/10.3390%2Fsym13071119.