Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 47, issue 3, pages 180-185
36-Nuclear Coordination Compounds of Nickel(II) with Malonate Anions and Internal Aquated Magnesium and Sodium Cations
Vologzhanina A. V.
2
,
Babeshkin K A
1
,
Efimov N. N.
1
,
Kiskin M. A.
1
,
Sidorov A. A.
1
,
Eremenko I. L.
1, 2
Publication type: Journal Article
Publication date: 2021-03-21
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The new anionic dimethylmalonate complex {Ni36(H2O)12(OH)20(HMe2Mal)(Me2Mal)29@ [Mg(H2O)6]}5– (Me2Mal2– is the dimethylmalonate anion) containing the internal aquated [Mg(H2O)6]2+ ion and the external [Mg3(OH)(H2O)10(C2H5OH)3]5+ cation was prepared by hydrothermal synthesis. The crystalline compound isolated from the reaction mixture and characterized by X-ray diffraction had the formula [Mg3(OH)(H2O)10(C2H5OH)3]{Ni36(H2O)12(OH)20(HMe2Mal)(Me2Mal)29@[Mg(H2O)6]}·25H2O (I) (CIF file CCDC no. 2038910). The new anionic complex {Ni36(H2O)12(OH)19(O)(Cbdc)30@[Na(H2O)6]}8– (Cbdc2– is the cyclobutane-1,1-dicarboxylate anion) containing the internal aquated [Na(H2O)6]+ ion and outer-sphere tetrabutylammonium cations was prepared from an ethanol–acetonitrile solution. The crystals isolated from the reaction mixture were characterized by X-ray diffraction and were described the formula (NBu4)8{Ni36(H2O)12(OH)19(O)(Cbdc)30@[Na(H2O)6]} (CIF file CCDC no. 2038909) (II). It was found that the magnetic behavior of complex I is due to competing ferro- and antifferromagnetic exchange interactions between paramagnetic nickel(II) ions.
Citations by journals
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1 publication, 33.33%
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Inorganica Chimica Acta
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1 publication, 33.33%
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Monatshefte fur Chemie
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1 publication, 33.33%
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1
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Citations by publishers
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1
2
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Elsevier
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Elsevier
2 publications, 66.67%
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Springer Nature
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Springer Nature
1 publication, 33.33%
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1
2
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Zorina-Tikhonova E. N. et al. 36-Nuclear Coordination Compounds of Nickel(II) with Malonate Anions and Internal Aquated Magnesium and Sodium Cations // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 3. pp. 180-185.
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Zorina-Tikhonova E. N., Vologzhanina A. V., Babeshkin K. A., Efimov N. N., Dorovatovskii P. V., Kiskin M. A., Sidorov A. A., Eremenko I. L. 36-Nuclear Coordination Compounds of Nickel(II) with Malonate Anions and Internal Aquated Magnesium and Sodium Cations // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 3. pp. 180-185.
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TY - JOUR
DO - 10.1134/S1070328421030088
UR - https://doi.org/10.1134%2FS1070328421030088
TI - 36-Nuclear Coordination Compounds of Nickel(II) with Malonate Anions and Internal Aquated Magnesium and Sodium Cations
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Sidorov, A. A.
AU - Zorina-Tikhonova, E. N.
AU - Vologzhanina, A. V.
AU - Babeshkin, K A
AU - Efimov, N. N.
AU - Dorovatovskii, P. V.
AU - Kiskin, M. A.
AU - Eremenko, I. L.
PY - 2021
DA - 2021/03/21 00:00:00
PB - Pleiades Publishing
SP - 180-185
IS - 3
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2021_Zorina-Tikhonova,
author = {A. A. Sidorov and E. N. Zorina-Tikhonova and A. V. Vologzhanina and K A Babeshkin and N. N. Efimov and P. V. Dorovatovskii and M. A. Kiskin and I. L. Eremenko},
title = {36-Nuclear Coordination Compounds of Nickel(II) with Malonate Anions and Internal Aquated Magnesium and Sodium Cations},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134%2FS1070328421030088},
number = {3},
pages = {180--185},
doi = {10.1134/S1070328421030088}
}
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Zorina-Tikhonova, E. N., et al. “36-Nuclear Coordination Compounds of Nickel(II) with Malonate Anions and Internal Aquated Magnesium and Sodium Cations.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 3, Mar. 2021, pp. 180-185. https://doi.org/10.1134%2FS1070328421030088.