Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 45, issue 10, pages 689-694
Polynuclear Co(II) Myrtenates with 2,4-Lutidine
Publication type: Journal Article
Publication date: 2019-10-03
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reaction of cobalt(II) chloride with potassium myrtenate (KMyr) followed by addition of 2,3-lutidine in ethanol gives the trinuclear compound [Co3(Myr)6(2,4-Lut)2] (I). The central cobalt(II) atom is linked to each of the two other metal atoms by three myrtenic acid anions. The reaction of a solution of compound I with lithium myrtenate (LiMyr) results in the formation of tetranuclear heterometallic complex [Li2-Co2(Myr)6(2,4-Lut)2] (II). Compound II is composed of two binuclear {LiCo(Myr)3(2,4-Lut)} moieties, in which the lithium(I) atoms are linked to cobalt(II) atoms by bridging myrtenate anions. The lithium atoms are connected by two oxygen atoms of acid anions. Compounds I and II were characterized by X-ray diffraction (CIF files CCDC nos. 1898096 (I), 1898097 (II)).
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Zorina-Tikhonova E. N. et al. Polynuclear Co(II) Myrtenates with 2,4-Lutidine // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 10. pp. 689-694.
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Zorina-Tikhonova E. N., Aleksandrov G., Kiskin M. A., Frolova L. L., Kuchin A. V., Sidorov A. A., Eremenko I. L. Polynuclear Co(II) Myrtenates with 2,4-Lutidine // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 10. pp. 689-694.
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TY - JOUR
DO - 10.1134/S1070328419100099
UR - https://doi.org/10.1134%2FS1070328419100099
TI - Polynuclear Co(II) Myrtenates with 2,4-Lutidine
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Zorina-Tikhonova, E. N.
AU - Kiskin, M. A.
AU - Kuchin, A. V.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
AU - Aleksandrov, G.G.
AU - Frolova, L L
PY - 2019
DA - 2019/10/03 00:00:00
PB - Pleiades Publishing
SP - 689-694
IS - 10
VL - 45
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2019_Zorina-Tikhonova,
author = {E. N. Zorina-Tikhonova and M. A. Kiskin and A. V. Kuchin and A. A. Sidorov and I. L. Eremenko and G.G. Aleksandrov and L L Frolova},
title = {Polynuclear Co(II) Myrtenates with 2,4-Lutidine},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2019},
volume = {45},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134%2FS1070328419100099},
number = {10},
pages = {689--694},
doi = {10.1134/S1070328419100099}
}
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Zorina-Tikhonova, E. N., et al. “Polynuclear Co(II) Myrtenates with 2,4-Lutidine.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 10, Oct. 2019, pp. 689-694. https://doi.org/10.1134%2FS1070328419100099.