European Journal of Inorganic Chemistry, volume 2018, issue 12, pages 1356-1366

Synthesis, Structure, and Magnetic Properties of a Family of Complexes Containing a {CoII 2 DyIII } Pivalate Core and a Pentanuclear CoII 4 DyIII Derivative

Publication typeJournal Article
Publication date2017-12-21
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor2.3
ISSN14341948, 10990682
Inorganic Chemistry
Abstract
A series of new CoII–LnIII complexes with polynuclear {Co2Ln(NO3)(Piv)6} (Ln = La, Gd, Dy; Piv = pivalate) cores were prepared by self-assembly reactions or step-by-step assembly. [Co2Dy(NO3)(Piv)6(MeCN)2] was used as the starting compound for the synthesis of the trinuclear analogue [Co2Dy(NO3)(Piv)6(py)2] (py = pyridine) and the pentanuclear complex [{Co2Dy(NO3)(Piv)6}{CoL(Piv)(H2O)}2][NO3]2 [L = 2,6-bis(2-pyridyl)-4-(4-pyridyl)pyridine]. The effects of the coordination environment and temperature on the distortion of the LnIII coordination polyhedra were analyzed for a series of coordination compounds with MII2LnIII cores and close analogues. The distortion of the LnIII polyhedron depends on both the composition of the compound and the temperature; a temperature increase favors the D2d geometry of the LnIII coordination polyhedron. The magnetic properties of the complexes with CoII2DyIII cores were analyzed with consideration of the anisotropy of the CoII and DyIII ions. The compounds containing diamagnetic LaIII and isotropic GdIII ions, [Co2Ln(Piv)6(NO3)(MeCN)2] (Ln = La, Gd), which are isostructural to the CoIIDyIII analogue, were studied to evaluate the CoII magnetic-anisotropy parameters to minimize the overparameterization of the magnetic properties in the fits for the Co2Dy systems. The magnetic properties of all complexes in this study are governed mainly by the magnetic properties of the isolated ions.

Citations by journals

1
2
3
4
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 4, 20%
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
4 publications, 20%
European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry, 2, 10%
European Journal of Inorganic Chemistry
2 publications, 10%
ChemistrySelect
ChemistrySelect, 2, 10%
ChemistrySelect
2 publications, 10%
Molecules
Molecules, 2, 10%
Molecules
2 publications, 10%
Pure and Applied Chemistry
Pure and Applied Chemistry, 1, 5%
Pure and Applied Chemistry
1 publication, 5%
Polyhedron
Polyhedron, 1, 5%
Polyhedron
1 publication, 5%
Journal of Solid State Chemistry
Journal of Solid State Chemistry, 1, 5%
Journal of Solid State Chemistry
1 publication, 5%
Zeitschrift fur Anorganische und Allgemeine Chemie
Zeitschrift fur Anorganische und Allgemeine Chemie, 1, 5%
Zeitschrift fur Anorganische und Allgemeine Chemie
1 publication, 5%
Inorganic Chemistry
Inorganic Chemistry, 1, 5%
Inorganic Chemistry
1 publication, 5%
Russian Journal of General Chemistry
Russian Journal of General Chemistry, 1, 5%
Russian Journal of General Chemistry
1 publication, 5%
Doklady Chemistry
Doklady Chemistry, 1, 5%
Doklady Chemistry
1 publication, 5%
Zeitschrift fur Kristallographie - Crystalline Materials
Zeitschrift fur Kristallographie - Crystalline Materials, 1, 5%
Zeitschrift fur Kristallographie - Crystalline Materials
1 publication, 5%
CrystEngComm
CrystEngComm, 1, 5%
CrystEngComm
1 publication, 5%
1
2
3
4

Citations by publishers

1
2
3
4
5
6
Pleiades Publishing
Pleiades Publishing, 6, 30%
Pleiades Publishing
6 publications, 30%
Wiley
Wiley, 5, 25%
Wiley
5 publications, 25%
Walter de Gruyter
Walter de Gruyter, 2, 10%
Walter de Gruyter
2 publications, 10%
Multidisciplinary Digital Publishing Institute (MDPI)
Multidisciplinary Digital Publishing Institute (MDPI), 2, 10%
Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 10%
Elsevier
Elsevier, 2, 10%
Elsevier
2 publications, 10%
American Chemical Society (ACS)
American Chemical Society (ACS), 1, 5%
American Chemical Society (ACS)
1 publication, 5%
Royal Society of Chemistry (RSC)
Royal Society of Chemistry (RSC), 1, 5%
Royal Society of Chemistry (RSC)
1 publication, 5%
1
2
3
4
5
6
  • We do not take into account publications that without a DOI.
  • Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
  • Statistics recalculated weekly.
Metrics
Share
Cite this
GOST |
Cite this
GOST Copy
Kiskin M. A. et al. Synthesis, Structure, and Magnetic Properties of a Family of Complexes Containing a {CoII 2 DyIII } Pivalate Core and a Pentanuclear CoII 4 DyIII Derivative // European Journal of Inorganic Chemistry. 2017. Vol. 2018. No. 12. pp. 1356-1366.
GOST all authors (up to 50) Copy
Kiskin M. A., Zorina-Tikhonova E. N., Kolotilov S. V., Goloveshkin A. S., Romanenko G., Efimov N. N., Eremenko I. L. Synthesis, Structure, and Magnetic Properties of a Family of Complexes Containing a {CoII 2 DyIII } Pivalate Core and a Pentanuclear CoII 4 DyIII Derivative // European Journal of Inorganic Chemistry. 2017. Vol. 2018. No. 12. pp. 1356-1366.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/ejic.201701056
UR - https://doi.org/10.1002%2Fejic.201701056
TI - Synthesis, Structure, and Magnetic Properties of a Family of Complexes Containing a {CoII 2 DyIII } Pivalate Core and a Pentanuclear CoII 4 DyIII Derivative
T2 - European Journal of Inorganic Chemistry
AU - Kiskin, Mikhail A.
AU - Zorina-Tikhonova, Ekaterina N.
AU - Romanenko, G.
AU - Efimov, Nikolay N.
AU - Eremenko, Igor L.
AU - Kolotilov, Sergey V.
AU - Goloveshkin, Alexander S.
PY - 2017
DA - 2017/12/21 00:00:00
PB - Wiley
SP - 1356-1366
IS - 12
VL - 2018
SN - 1434-1948
SN - 1099-0682
ER -
BibTex |
Cite this
BibTex Copy
@article{2017_Kiskin
author = {Mikhail A. Kiskin and Ekaterina N. Zorina-Tikhonova and G. Romanenko and Nikolay N. Efimov and Igor L. Eremenko and Sergey V. Kolotilov and Alexander S. Goloveshkin},
title = {Synthesis, Structure, and Magnetic Properties of a Family of Complexes Containing a {CoII 2 DyIII } Pivalate Core and a Pentanuclear CoII 4 DyIII Derivative},
journal = {European Journal of Inorganic Chemistry},
year = {2017},
volume = {2018},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002%2Fejic.201701056},
number = {12},
pages = {1356--1366},
doi = {10.1002/ejic.201701056}
}
MLA
Cite this
MLA Copy
Kiskin, Mikhail A., et al. “Synthesis, Structure, and Magnetic Properties of a Family of Complexes Containing a {CoII 2 DyIII } Pivalate Core and a Pentanuclear CoII 4 DyIII Derivative.” European Journal of Inorganic Chemistry, vol. 2018, no. 12, Dec. 2017, pp. 1356-1366. https://doi.org/10.1002%2Fejic.201701056.
Found error?