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IUCrJ, volume 5, issue 3, pages 293-303

Exploitation of knowledge databases in the synthesis of zinc(II) malonates with photo-sensitive and photo-insensitive N,N′-containing linkers

Voronova Eugenia D. 3
Godovikov Ivan A. 3
Eremenko Igor L. 1, 3
Publication typeJournal Article
Publication date2018-03-27
Journal: IUCrJ
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor3.9
ISSN20522525
General Chemistry
Biochemistry
Condensed Matter Physics
General Materials Science
Abstract

Photoinitiated solid-state reactions are known to affect the physical properties of coordination polymers, such as fluorescence and sorption behaviour, and also afford extraordinary architectures (e.g. three-periodic structures with polyorganic ligands). However, the construction of novel photo-sensitive coordination polymers requires an understanding of the factors which govern the mutual disposition of reactive fragments. A series of zinc(II) malonate complexes with 1,2-bis(pyridin-4-yl)ethylene and its photo-insensitive analogues has been synthesized for the purpose of systematic analysis of their underlying nets and mutual disposition of N-donor ligands. The application of a big data-set analysis for the prediction of a variety of possible complex compositions, coordination environments and networks for a four-component system has been demonstrated for the first time. Seven of the nine compounds possess one of the highly probable topologies for their underlying nets; in addition, two novel closely related four-coordinated networks were obtained. Complexes containing 1,2-bis(pyridin-4-yl)ethylene and 1,2-bis(pyridin-4-yl)ethane form isoreticular compounds more readily than those with 4,4′-bipyridine and 1,2-bis(pyridin-4-yl)ethylene. The effects of the precursor, either zinc(II) nitrate or zinc(II) acetate, on the composition and dimensionality of the resulting architecture are discussed. For three of the four novel complexes containing 1,2-bis(pyridin-4-yl)ethylene, the single-crystal-to-single-crystal [2 + 2] cycloaddition reactions were carried out. UV irradiation of these crystals afforded either the 0D→1D or the 3D→3D transformations, with and without network changes. One of the two 3D→3D transformations was accompanied by solvent (H2O) cleavage.

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Zorina-Tikhonova E. N. et al. Exploitation of knowledge databases in the synthesis of zinc(II) malonates with photo-sensitive and photo-insensitive N,N′-containing linkers // IUCrJ. 2018. Vol. 5. No. 3. pp. 293-303.
GOST all authors (up to 50) Copy
Zorina-Tikhonova E. N., Chistyakov A. S., Kiskin M. A., Sidorov A. A., Dorovatovskii P., Zubavichus Y. V., Voronova E. D., Godovikov I. A., Korlyukov A., Eremenko I. L., Vologzhanina A. Exploitation of knowledge databases in the synthesis of zinc(II) malonates with photo-sensitive and photo-insensitive N,N′-containing linkers // IUCrJ. 2018. Vol. 5. No. 3. pp. 293-303.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1107/S2052252518001641
UR - https://doi.org/10.1107%2FS2052252518001641
TI - Exploitation of knowledge databases in the synthesis of zinc(II) malonates with photo-sensitive and photo-insensitive N,N′-containing linkers
T2 - IUCrJ
AU - Zorina-Tikhonova, Ekaterina N.
AU - Chistyakov, Aleksandr S.
AU - Kiskin, Mikhail A.
AU - Sidorov, Aleksei A.
AU - Dorovatovskii, Pavel
AU - Zubavichus, Yan V.
AU - Voronova, Eugenia D.
AU - Korlyukov, Alexander
AU - Eremenko, Igor L.
AU - Vologzhanina, A.
AU - Godovikov, Ivan A.
PY - 2018
DA - 2018/03/27 00:00:00
PB - International Union of Crystallography (IUCr)
SP - 293-303
IS - 3
VL - 5
PMID - 29755745
SN - 2052-2525
ER -
BibTex |
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@article{2018_Zorina-Tikhonova
author = {Ekaterina N. Zorina-Tikhonova and Aleksandr S. Chistyakov and Mikhail A. Kiskin and Aleksei A. Sidorov and Pavel Dorovatovskii and Yan V. Zubavichus and Eugenia D. Voronova and Alexander Korlyukov and Igor L. Eremenko and A. Vologzhanina and Ivan A. Godovikov},
title = {Exploitation of knowledge databases in the synthesis of zinc(II) malonates with photo-sensitive and photo-insensitive N,N′-containing linkers},
journal = {IUCrJ},
year = {2018},
volume = {5},
publisher = {International Union of Crystallography (IUCr)},
month = {mar},
url = {https://doi.org/10.1107%2FS2052252518001641},
number = {3},
pages = {293--303},
doi = {10.1107/S2052252518001641}
}
MLA
Cite this
MLA Copy
Zorina-Tikhonova, Ekaterina N., et al. “Exploitation of knowledge databases in the synthesis of zinc(II) malonates with photo-sensitive and photo-insensitive N,N′-containing linkers.” IUCrJ, vol. 5, no. 3, Mar. 2018, pp. 293-303. https://doi.org/10.1107%2FS2052252518001641.
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