Polyhedron, volume 194, pages 114902

Zinc(II) and cadmium(II) complexes with the decahydro-closo-decaborate anion and phenyl-containing benzimidazole derivatives with linker N[dbnd]N or C[dbnd]N group

Korolenko Svetlana E 1
Kuznetsov Nikolay T.
Malinina Elena A 1
Yu Zhizhin Konstantin
Nefedov Sergey E. 1
Burlov Anatoliy S. 2
Divaeva Lyudmila N 2
Churakov Andrey V
Kuznetsov Nikolay V. 1
Publication typeJournal Article
Publication date2021-01-01
Journal: Polyhedron
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor2.6
ISSN02775387
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Here, we have studied zinc(II) and cadmium(II) complexation with benzimidazole derivatives L1 and L2 (L1 is 1-methylbenzimidazo-2-yl-methyleneaniline; L2 is 1-ethyl-2-(4-methoxyphenyl)azobenzimidazole) containing linker C=N or N=N bonds between the phenyl and benzimidazole rings in the presence of a competitive inorganic ligand, namely the decahydro-closo-decaborate anion [B10H10]2–. The first examples of mixed-ligand cadmium(II) complexes with [B10H10]2– in the inner sphere [Cd(L1)2[B10H10]] have been isolated selectively which are positional isomers with different position of the metal atom around the boron cage (at the 1-2 and 2-6 edges of the boron cluster). The effect of the nature of starting reagents and steric factor of organic ligands L on the composition and structure of reaction products has been found. The structures of single crystals of mixed-ligand complexes [ZnL1(NO3)2(H2O)], [Cd(L1)2[B10H10]] · 1.5 CH3CN, [Cd(L1)2[B10H10]], and [ZnL2(NO3)2(H2O)] with bidentate cyclic coordination of organic ligands L1 and L2 as well as [Cd(L2)2(NO3)2] and [Cd(L2)2(CH3CN)[B10H10]] with monodentate coordination of ligand L2 have been determined. It has been found that ligand L1 with the C=N linker acts only as bidentate ligand whereas ligand L2 with the N=N linker can act both as monodentate and bidentate ligand.

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Korolenko S. E. et al. Zinc(II) and cadmium(II) complexes with the decahydro-closo-decaborate anion and phenyl-containing benzimidazole derivatives with linker N[dbnd]N or C[dbnd]N group // Polyhedron. 2021. Vol. 194. p. 114902.
GOST all authors (up to 50) Copy
Korolenko S. E., Malinina E. A., Avdeeva V. V., Churakov A. V., Nefedov S. E., Kubasov A. S., Burlov A. S., Divaeva L. N., Yu Zhizhin K., Kuznetsov N. T., Churakov A. V., Novikov A. S., Kuznetsov N. V. Zinc(II) and cadmium(II) complexes with the decahydro-closo-decaborate anion and phenyl-containing benzimidazole derivatives with linker N[dbnd]N or C[dbnd]N group // Polyhedron. 2021. Vol. 194. p. 114902.
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RIS Copy
TY - JOUR
DO - 10.1016/j.poly.2020.114902
UR - https://doi.org/10.1016%2Fj.poly.2020.114902
TI - Zinc(II) and cadmium(II) complexes with the decahydro-closo-decaborate anion and phenyl-containing benzimidazole derivatives with linker N[dbnd]N or C[dbnd]N group
T2 - Polyhedron
AU - Korolenko, Svetlana E
AU - Malinina, Elena A
AU - Avdeeva, V. V.
AU - Churakov, Andrey V
AU - Nefedov, Sergey E.
AU - Kubasov, Aleksey S
AU - Burlov, Anatoliy S.
AU - Divaeva, Lyudmila N
AU - Yu Zhizhin, Konstantin
AU - Kuznetsov, Nikolay T.
AU - Churakov, Andrei V.
AU - Novikov, Alexander S.
AU - Kuznetsov, Nikolay V.
PY - 2021
DA - 2021/01/01 00:00:00
PB - Elsevier
SP - 114902
VL - 194
SN - 0277-5387
ER -
BibTex
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BibTex Copy
@article{2021_Korolenko
author = {Svetlana E Korolenko and Elena A Malinina and V. V. Avdeeva and Andrey V Churakov and Sergey E. Nefedov and Aleksey S Kubasov and Anatoliy S. Burlov and Lyudmila N Divaeva and Konstantin Yu Zhizhin and Nikolay T. Kuznetsov and Andrei V. Churakov and Alexander S. Novikov and Nikolay V. Kuznetsov},
title = {Zinc(II) and cadmium(II) complexes with the decahydro-closo-decaborate anion and phenyl-containing benzimidazole derivatives with linker N[dbnd]N or C[dbnd]N group},
journal = {Polyhedron},
year = {2021},
volume = {194},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.poly.2020.114902},
pages = {114902},
doi = {10.1016/j.poly.2020.114902}
}
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