Open Access
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 47, issue 10, pages 670-678
Sodium and Potassium tert-Butyl Peroxide Hydrates: Crystal Structure and Properties
Publication type: Journal Article
Publication date: 2021-10-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Sodium and potassium tert-butyl peroxide hydrates 2Na+·2C4H9$${\text{O}}_{2}^{ - }$$·7H2O (I) and 2K+· 2C4H9$${\text{O}}_{2}^{ - }$$·4H2O (II) were prepared. According to X-ray diffraction data (CIF files CCDC no. 2081025 (I) and no. 2081024 (II)), the compounds are coordination polymers in which alkali metal atoms have C.N.(Na) of 6 or C.N.(K) of 6 and 8. The crystal packings comprise layers with clearly defined hydrophobic surfaces consisting of hydrocarbon groups and hydrophilic inner areas including water molecules, alkali metal cations, and peroxy groups of the tert-butyl peroxide anions. Compounds were characterized by vibrational spectroscopy, 1H, 13C NMR spectroscopy, thermogravimetry, and differential scanning calorimetry.
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CrystEngComm
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CrystEngComm
1 publication, 100%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 100%
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Medvedev A. G. et al. Sodium and Potassium tert-Butyl Peroxide Hydrates: Crystal Structure and Properties // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 10. pp. 670-678.
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Medvedev A. G., Sharipov M. Yu., Mikhaylov A., Grishanov D. A., Churakov A., Prikhodchenko P. V. Sodium and Potassium tert-Butyl Peroxide Hydrates: Crystal Structure and Properties // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 10. pp. 670-678.
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TY - JOUR
DO - 10.1134/S1070328421100043
UR - https://doi.org/10.1134%2FS1070328421100043
TI - Sodium and Potassium tert-Butyl Peroxide Hydrates: Crystal Structure and Properties
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Medvedev, A G
AU - Sharipov, M Yu
AU - Mikhaylov, A.A.
AU - Grishanov, D A
AU - Churakov, A.V.
AU - Prikhodchenko, P V
PY - 2021
DA - 2021/10/01 00:00:00
PB - Pleiades Publishing
SP - 670-678
IS - 10
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2021_Medvedev,
author = {A G Medvedev and M Yu Sharipov and A.A. Mikhaylov and D A Grishanov and A.V. Churakov and P V Prikhodchenko},
title = {Sodium and Potassium tert-Butyl Peroxide Hydrates: Crystal Structure and Properties},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134%2FS1070328421100043},
number = {10},
pages = {670--678},
doi = {10.1134/S1070328421100043}
}
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Medvedev, A. G., et al. “Sodium and Potassium tert-Butyl Peroxide Hydrates: Crystal Structure and Properties.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 10, Oct. 2021, pp. 670-678. https://doi.org/10.1134%2FS1070328421100043.