Russian Journal of Inorganic Chemistry, volume 66, issue 10, pages 1492-1499
Synthesis and Characterization of Coordination Compounds of Nickel(II) Carboxylates with Salicylhydrazide. Crystal Structure of [NiL3 ]Pht (L is Salicylhydrazide, Pht2– is Phthalic Acid Anion)
Sergienko V S
1, 2
,
Koksharova T V
3
,
Churakov A.V.
1
,
Mandzii T V
3
,
Surazhskaya M D
1
,
Egorova O A
4
1
3
Mechnikov National University, Odessa, Ukraine
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Publication type: Journal Article
Publication date: 2021-10-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 2.1
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Coordination compounds of various nickel(II) carboxylates (valerate, benzoate, phthalate, maleate, fumarate) with salicyl hydrazide have been synthesized and studied by IR spectroscopy. The crystal structure of the complex of nickel(II) phthalate with salicyl hydrazide [NiL3]Pht (L is salicyl hydrazide, Pht2– is phthalic acid dianion) has been determined by X-ray diffraction. The structural units of the crystal are complex cations [NiL3]2+ and phthalic acid anions Pht2– joined together by cation–anion N–H…O, O–H…O hydrogen bonds. The nickel atom has distorted octahedron coordination formed by three oxygen and three nitrogen atoms of the three bidentate-chelate ligands L (Ni–O 2.027–2.059, Ni–N 2.067–2.097 Å).
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Russian Journal of Inorganic Chemistry
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Russian Journal of Inorganic Chemistry
1 publication, 100%
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Citations by publishers
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Pleiades Publishing
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Pleiades Publishing
1 publication, 100%
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Sergienko V. S. et al. Synthesis and Characterization of Coordination Compounds of Nickel(II) Carboxylates with Salicylhydrazide. Crystal Structure of [NiL3]Pht (L is Salicylhydrazide, Pht2– is Phthalic Acid Anion) // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 10. pp. 1492-1499.
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Sergienko V. S., Koksharova T. V., Churakov A., Mandzii T. V., Surazhskaya M. D., Egorova O. A. Synthesis and Characterization of Coordination Compounds of Nickel(II) Carboxylates with Salicylhydrazide. Crystal Structure of [NiL3]Pht (L is Salicylhydrazide, Pht2– is Phthalic Acid Anion) // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 10. pp. 1492-1499.
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TY - JOUR
DO - 10.1134/S0036023621100156
UR - https://doi.org/10.1134%2FS0036023621100156
TI - Synthesis and Characterization of Coordination Compounds of Nickel(II) Carboxylates with Salicylhydrazide. Crystal Structure of [NiL3]Pht (L is Salicylhydrazide, Pht2– is Phthalic Acid Anion)
T2 - Russian Journal of Inorganic Chemistry
AU - Koksharova, T V
AU - Churakov, A.V.
AU - Mandzii, T V
AU - Surazhskaya, M D
AU - Egorova, O A
AU - Sergienko, V S
PY - 2021
DA - 2021/10/01 00:00:00
PB - Pleiades Publishing
SP - 1492-1499
IS - 10
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2021_Sergienko,
author = {T V Koksharova and A.V. Churakov and T V Mandzii and M D Surazhskaya and O A Egorova and V S Sergienko},
title = {Synthesis and Characterization of Coordination Compounds of Nickel(II) Carboxylates with Salicylhydrazide. Crystal Structure of [NiL3]Pht (L is Salicylhydrazide, Pht2– is Phthalic Acid Anion)},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134%2FS0036023621100156},
number = {10},
pages = {1492--1499},
doi = {10.1134/S0036023621100156}
}
Cite this
MLA
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Sergienko, V. S., et al. “Synthesis and Characterization of Coordination Compounds of Nickel(II) Carboxylates with Salicylhydrazide. Crystal Structure of [NiL3]Pht (L is Salicylhydrazide, Pht2– is Phthalic Acid Anion).” Russian Journal of Inorganic Chemistry, vol. 66, no. 10, Oct. 2021, pp. 1492-1499. https://doi.org/10.1134%2FS0036023621100156.