Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 47, issue 10, pages 707-716
Palladium(I) Coordination Polymers with Unsaturated Dicarboxylic Acids with Stable Paramagnetic Centers
Efimenko I A
1
,
Efimov N. N.
1
,
Erofeeva O S
1
,
Demina L. I.
2
,
Simonenko N P
1
,
Churakov A.V.
1
,
Minin V V
1
Publication type: Journal Article
Publication date: 2021-10-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Palladium(I) coordination polymers with unsaturated dicarboxylic acids, {[cis-Pd(C4H2O4)(H2O)]·(H2O)}n (I) (maleic acid), {[cis-Pd(C5H4O4)(H2O)]·2H2O}n (II) (citraconic acid), and {[trans-Pd(C4H2O4)(H2O)]·(H2O)}n (III) (fumaric acid) with stable paramagnetic centers in the polymer matrix were synthesized for the first time. According to IR and ESR spectroscopy data (determining the number of paramagnetic centers) and results of thermogravimetric analysis, the building blocks of I–III are, at least, tetranuclear Pd(I) clusters, in which palladium atoms are linked by bridging carboxylate groups. Each carboxylate group is coordinated via only one O atom, while the second O atom is linked to the nearest palladium atom of the neighboring cluster, thus giving a multidimensional coordination polymer. The coordination sphere of each Pd(I) atom in the cluster is completed by a water molecule and Pd–Pd bond. Heating of I–III results in the loss of solvation water molecules as the first stage. Above 100°C, the onset of removal of the coordinated water molecules is accompanied by complete decomposition of the complexes. On treatment of I with CH3CN in methanol, redox reaction takes place, in which complex I disproportionates to give Pd(II) complex and Pd(0) to give [Pd(HOOC–CH–CH(CH3O)(CH3CN)2] (IV) (CIF file CCDC no. 2039147).
Citations by journals
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Polymers
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Polymers
1 publication, 100%
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1
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Citations by publishers
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 100%
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1
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Efimenko I. A. et al. Palladium(I) Coordination Polymers with Unsaturated Dicarboxylic Acids with Stable Paramagnetic Centers // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 10. pp. 707-716.
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Efimenko I. A., Efimov N. N., Erofeeva O. S., Demina L. I., Simonenko N. P., Churakov A., Minin V. V. Palladium(I) Coordination Polymers with Unsaturated Dicarboxylic Acids with Stable Paramagnetic Centers // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 10. pp. 707-716.
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TY - JOUR
DO - 10.1134/S1070328421090037
UR - https://doi.org/10.1134%2FS1070328421090037
TI - Palladium(I) Coordination Polymers with Unsaturated Dicarboxylic Acids with Stable Paramagnetic Centers
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Efimov, N. N.
AU - Simonenko, N P
AU - Churakov, A.V.
AU - Minin, V V
AU - Efimenko, I A
AU - Demina, L. I.
AU - Erofeeva, O S
PY - 2021
DA - 2021/10/01 00:00:00
PB - Pleiades Publishing
SP - 707-716
IS - 10
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2021_Efimenko
author = {N. N. Efimov and N P Simonenko and A.V. Churakov and V V Minin and I A Efimenko and L. I. Demina and O S Erofeeva},
title = {Palladium(I) Coordination Polymers with Unsaturated Dicarboxylic Acids with Stable Paramagnetic Centers},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134%2FS1070328421090037},
number = {10},
pages = {707--716},
doi = {10.1134/S1070328421090037}
}
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Efimenko, I. A., et al. “Palladium(I) Coordination Polymers with Unsaturated Dicarboxylic Acids with Stable Paramagnetic Centers.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 10, Oct. 2021, pp. 707-716. https://doi.org/10.1134%2FS1070328421090037.
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