Russian Journal of Inorganic Chemistry, volume 66, issue 9, pages 1343-1349
Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties
Nikiforova M E
1
,
Lutsenko I A
1
,
Kiskin M. A.
1
,
Nelyubina Yu V
2
,
Primakov P V
2
,
Bekker O B
3
,
Khoroshilov A V
1
,
Publication type: Journal Article
Publication date: 2021-09-21
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 2.1
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The reaction of barium(II) hydroxide with 2-furoic acid (pyromucic acid, Hfur) gave 1D coordination polymer {[Ba3(fur)6(Hfur)2(H2O)8]}n·4nH2O (I). According to X-ray diffraction data, I contains two symmetrically independent barium cations, which have different environments: Ba(1) coordinates six fur– anions, while Ba(2) is a fragment of heteroleptic coordination (fur–, Hfur, and H2O) (CIF file CCDC no. 2063380). The supramolecular polymeric architecture of I is determined by bridging water molecules and numerous hydrogen bonds between coordinated and solvation water molecules to form a 1D motif. The arrangement of Ba2+ ions in the trinuclear moiety {Ba3(fur)6(Hfur)2(H2O)8} of the polymer is nearly linear. The thermal behavior of I, investigated by simultaneous thermal analysis (argon atmosphere), showed a stepwise character of thermal decomposition caused by gradual destruction of the hydrogen-bonded framework and the subsequent partial destruction of the organic part. Analysis of the biological activity of I against the non-pathogenic Mycolicibacterium smegmatis strain showed low sensitivity of the bacterial wall to the complex.
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Polyhedron
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1 publication, 16.67%
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Journal of Structural Chemistry
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1 publication, 16.67%
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1
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Citations by publishers
1
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Multidisciplinary Digital Publishing Institute (MDPI)
|
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2 publications, 33.33%
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Pleiades Publishing
2 publications, 33.33%
|
Elsevier
|
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1 publication, 16.67%
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Springer Nature
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Springer Nature
1 publication, 16.67%
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1
2
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- Statistics recalculated weekly.
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Nikiforova M. E. et al. Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 9. pp. 1343-1349.
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Nikiforova M. E., Lutsenko I. A., Kiskin M. A., Nelyubina Yu. V., Primakov P. V., Bekker O. B., Khoroshilov A. V., Eremenko I. L. Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 9. pp. 1343-1349.
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TY - JOUR
DO - 10.1134/S0036023621090102
UR - https://doi.org/10.1134%2FS0036023621090102
TI - Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties
T2 - Russian Journal of Inorganic Chemistry
AU - Nikiforova, M E
AU - Nelyubina, Yu V
AU - Primakov, P V
AU - Bekker, O B
AU - Khoroshilov, A V
AU - Lutsenko, I A
AU - Kiskin, M. A.
AU - Eremenko, I. L.
PY - 2021
DA - 2021/09/21 00:00:00
PB - Pleiades Publishing
SP - 1343-1349
IS - 9
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2021_Nikiforova
author = {M E Nikiforova and Yu V Nelyubina and P V Primakov and O B Bekker and A V Khoroshilov and I A Lutsenko and M. A. Kiskin and I. L. Eremenko},
title = {Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134%2FS0036023621090102},
number = {9},
pages = {1343--1349},
doi = {10.1134/S0036023621090102}
}
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Nikiforova, M. E., et al. “Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties.” Russian Journal of Inorganic Chemistry, vol. 66, no. 9, Sep. 2021, pp. 1343-1349. https://doi.org/10.1134%2FS0036023621090102.