Russian Journal of Inorganic Chemistry, volume 66, issue 9, pages 1343-1349

Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties

Publication typeJournal Article
Publication date2021-09-21
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor2.1
ISSN00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The reaction of barium(II) hydroxide with 2-furoic acid (pyromucic acid, Hfur) gave 1D coordination polymer {[Ba3(fur)6(Hfur)2(H2O)8]}n·4nH2O (I). According to X-ray diffraction data, I contains two symmetrically independent barium cations, which have different environments: Ba(1) coordinates six fur– anions, while Ba(2) is a fragment of heteroleptic coordination (fur–, Hfur, and H2O) (CIF file CCDC no. 2063380). The supramolecular polymeric architecture of I is determined by bridging water molecules and numerous hydrogen bonds between coordinated and solvation water molecules to form a 1D motif. The arrangement of Ba2+ ions in the trinuclear moiety {Ba3(fur)6(Hfur)2(H2O)8} of the polymer is nearly linear. The thermal behavior of I, investigated by simultaneous thermal analysis (argon atmosphere), showed a stepwise character of thermal decomposition caused by gradual destruction of the hydrogen-bonded framework and the subsequent partial destruction of the organic part. Analysis of the biological activity of I against the non-pathogenic Mycolicibacterium smegmatis strain showed low sensitivity of the bacterial wall to the complex.

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Nikiforova M. E. et al. Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 9. pp. 1343-1349.
GOST all authors (up to 50) Copy
Nikiforova M. E., Lutsenko I. A., Kiskin M. A., Nelyubina Yu. V., Primakov P. V., Bekker O. B., Khoroshilov A. V., Eremenko I. L. Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 9. pp. 1343-1349.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0036023621090102
UR - https://doi.org/10.1134%2FS0036023621090102
TI - Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties
T2 - Russian Journal of Inorganic Chemistry
AU - Nikiforova, M E
AU - Nelyubina, Yu V
AU - Primakov, P V
AU - Bekker, O B
AU - Khoroshilov, A V
AU - Lutsenko, I A
AU - Kiskin, M. A.
AU - Eremenko, I. L.
PY - 2021
DA - 2021/09/21 00:00:00
PB - Pleiades Publishing
SP - 1343-1349
IS - 9
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
BibTex |
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@article{2021_Nikiforova
author = {M E Nikiforova and Yu V Nelyubina and P V Primakov and O B Bekker and A V Khoroshilov and I A Lutsenko and M. A. Kiskin and I. L. Eremenko},
title = {Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134%2FS0036023621090102},
number = {9},
pages = {1343--1349},
doi = {10.1134/S0036023621090102}
}
MLA
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MLA Copy
Nikiforova, M. E., et al. “Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties.” Russian Journal of Inorganic Chemistry, vol. 66, no. 9, Sep. 2021, pp. 1343-1349. https://doi.org/10.1134%2FS0036023621090102.
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