Inorganic Chemistry, volume 58, issue 3, pages 1905-1911
Crystalline Ammonium Peroxogermanate as a Waste-Free, Fully Recyclable Versatile Precursor for Germanium Compounds
Mikhaylov Alexey
1
,
Lev Ovadia
2
,
Publication type: Journal Article
Publication date: 2019-01-16
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
High, nearly 100%, yield synthesis of ammonium peroxogermanate (APG), (NH4)6[Ge6(μ-OO)6(μ-O)6(OH)6]·6H2O, is presented, and its crystal structure is determined by single crystal X-ray study. It comprises centrosymmetric hexanuclear peroxogermanate anions [Ge6(μ-OO)6(μ-O)6(OH)6]6- with six μ-oxo- and six μ-peroxo groups forming negatively charged layers. The space between these layers is filled by ammonium cations and water molecules, forming a highly stable structure due to hydrogen bonding. Highly soluble macroporous amorphous germanium oxide (HSGO) is then synthesized by mild treatment of APG. The compound forms highly oversaturated metastable germanium oxide solution with a solubility of 100 g/L, over 20 times higher than the solubility of amorphous germanium oxide. HSGO solution is a versatile reagent that can react with basic and acidic reagents to give a diverse range of salts including, e.g., germanium sulfide, germanium hydrophosphate, and potassium germanate. In the absence of acid or base, the aqueous HSGO solution yields hexagonal germanium oxide under ambient conditions.
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- We do not take into account publications that without a DOI.
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- Statistics recalculated weekly.
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Grishanov D. A. et al. Crystalline Ammonium Peroxogermanate as a Waste-Free, Fully Recyclable Versatile Precursor for Germanium Compounds // Inorganic Chemistry. 2019. Vol. 58. No. 3. pp. 1905-1911.
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Grishanov D. A., Churakov A. V., Medvedev A. G., Mikhaylov A., Lev O., Prikhodchenko P. V. Crystalline Ammonium Peroxogermanate as a Waste-Free, Fully Recyclable Versatile Precursor for Germanium Compounds // Inorganic Chemistry. 2019. Vol. 58. No. 3. pp. 1905-1911.
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TY - JOUR
DO - 10.1021/acs.inorgchem.8b02747
UR - https://doi.org/10.1021%2Facs.inorgchem.8b02747
TI - Crystalline Ammonium Peroxogermanate as a Waste-Free, Fully Recyclable Versatile Precursor for Germanium Compounds
T2 - Inorganic Chemistry
AU - Grishanov, Dmitry A
AU - Churakov, Andrei V.
AU - Medvedev, Alexander G.
AU - Mikhaylov, Alexey
AU - Lev, Ovadia
AU - Prikhodchenko, Petr V.
PY - 2019
DA - 2019/01/16 00:00:00
PB - American Chemical Society (ACS)
SP - 1905-1911
IS - 3
VL - 58
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2019_Grishanov,
author = {Dmitry A Grishanov and Andrei V. Churakov and Alexander G. Medvedev and Alexey Mikhaylov and Ovadia Lev and Petr V. Prikhodchenko},
title = {Crystalline Ammonium Peroxogermanate as a Waste-Free, Fully Recyclable Versatile Precursor for Germanium Compounds},
journal = {Inorganic Chemistry},
year = {2019},
volume = {58},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021%2Facs.inorgchem.8b02747},
number = {3},
pages = {1905--1911},
doi = {10.1021/acs.inorgchem.8b02747}
}
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Grishanov, Dmitry A., et al. “Crystalline Ammonium Peroxogermanate as a Waste-Free, Fully Recyclable Versatile Precursor for Germanium Compounds.” Inorganic Chemistry, vol. 58, no. 3, Jan. 2019, pp. 1905-1911. https://doi.org/10.1021%2Facs.inorgchem.8b02747.