Formation of Metal-Polymer Hybrid Nanostructures during Radiation-Induced Reduction of Metal Ions in Poly(acrylic acid)-Poly(ethylenimine) Complexes

Zezin A.A., Feldman V.I., Abramchuk S.S., Ivanchenko V.K., Zezina E.A., Shmakova N.A., Shvedunov V.I.
Тип документаJournal Article
Дата публикации2011-04-27
Название журналаPolymer Science Series C
Издатель
  • Materials Chemistry
  • General Chemistry
  • Polymers and Plastics
Краткое описание
The formation of nanoparticles during the radiation-induced chemical reduction of silver ions, copper ions, and nickel ions in films based on poly(acrylic acid)-poly(ethylenimine) complexes are studied via electron microscopy. This approach allows preparation of composites containing nanoparticles that are randomly distributed in the polymer matrix and materials with a regular spatial distribution of nanoparticles across the film thickness and in subsurface layers. The structure of metal-polymer hybrid materials is dependent on the irradiation conditions, the type of reduced metal ions, and their initial content in polymer matrices. The ratio between the rate of nucleation and the rate of growth of nanoparticles in the matrices of interpolyelectrolyte complexes depends on the intensity of the absorbed dose and on the mechanisms of reduction of metal ions and formation of clusters. The IR spectroscopic studies reveal the effect of nanoparticles on the chemical structure of the polymer matrix.
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1. Zezin A.A. и др. Formation of metal-polymer hybrid nanostructures during radiation-induced reduction of metal ions in poly(acrylic acid)-poly(ethylenimine) complexes // Polymer Science Series C. 2011. Т. 53. № 1. С. 61–67.
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TY - JOUR

DO - 10.1134/s1811238211060038

UR - http://dx.doi.org/10.1134/S1811238211060038

TI - Formation of metal-polymer hybrid nanostructures during radiation-induced reduction of metal ions in poly(acrylic acid)-poly(ethylenimine) complexes

T2 - Polymer Science Series C

AU - Zezin, A. A.

AU - Feldman, V. I.

AU - Abramchuk, S. S.

AU - Ivanchenko, V. K.

AU - Zezina, E. A.

AU - Shmakova, N. A.

AU - Shvedunov, V. I.

PY - 2011

DA - 2011/09

PB - Pleiades Publishing Ltd

SP - 61-67

IS - 1

VL - 53

SN - 1811-2382

SN - 1555-614X

ER -

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@article{2011,

doi = {10.1134/s1811238211060038},

url = {https://doi.org/10.1134%2Fs1811238211060038},

year = 2011,

month = {sep},

publisher = {Pleiades Publishing Ltd},

volume = {53},

number = {1},

pages = {61--67},

author = {A. A. Zezin and V. I. Feldman and S. S. Abramchuk and V. K. Ivanchenko and E. A. Zezina and N. A. Shmakova and V. I. Shvedunov},

title = {Formation of metal-polymer hybrid nanostructures during radiation-induced reduction of metal ions in poly(acrylic acid)-poly(ethylenimine) complexes}

}

MLA
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Zezin, A. A. et al. “Formation of Metal-Polymer Hybrid Nanostructures During Radiation-Induced Reduction of Metal Ions in Poly(acrylic Acid)-Poly(ethylenimine) Complexes.” Polymer Science Series C 53.1 (2011): 61–67. Crossref. Web.