Russian Chemical Bulletin, volume 63, issue 12, pages 2630-2634

Synthesis, structure, and catalytic activity of new aluminum complexes formed with sterically bulky ligands

Publication typeJournal Article
Publication date2014-12-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor1.7
ISSN10665285, 15739171
General Chemistry
Abstract
A reaction of pyridine related ligands containing two hydroxyalkyl groups, 2,6-(HO-Z-CH2)2C5H3N (Z is 1,1-cyclohexylene, 2,2-adamantylene) with trimethylaluminum and trimethoxyaluminum leads to three new aluminum complexes with the Me-Al or MeO-Al bond: 2,6-C5H3N(CH2-Z-O)2Al-X (Z is 1,1-cyclohexylene, X = Me (5), OMe (6); Z is 2,2-adamantylene, X = Me (7)). The structures of new derivatives were confirmed by NMR spectroscopy and elemental analysis. The structure of complex 5 was studied by X-ray diffraction analysis. Complex 5 is a dimer in the solid state due to the formation of a four-membered ring...Al-O...Al-O.... Complexes 5 and 6 were studied as initiators of the ring-opening polymerization of ε-caprolactone.

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Zaitsev K. V. et al. Synthesis, structure, and catalytic activity of new aluminum complexes formed with sterically bulky ligands // Russian Chemical Bulletin. 2014. Vol. 63. No. 12. pp. 2630-2634.
GOST all authors (up to 50) Copy
Zaitsev K. V., Kuchuk E. A., Mankaev B. N., Churakov A., Zaitseva G., Lemenovskii D. A., Karlov S. Synthesis, structure, and catalytic activity of new aluminum complexes formed with sterically bulky ligands // Russian Chemical Bulletin. 2014. Vol. 63. No. 12. pp. 2630-2634.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s11172-014-0790-5
UR - https://doi.org/10.1007%2Fs11172-014-0790-5
TI - Synthesis, structure, and catalytic activity of new aluminum complexes formed with sterically bulky ligands
T2 - Russian Chemical Bulletin
AU - Zaitsev, K V
AU - Kuchuk, E A
AU - Mankaev, B N
AU - Churakov, A.V.
AU - Zaitseva, G.S.
AU - Lemenovskii, D A
AU - Karlov, S.S.
PY - 2014
DA - 2014/12/01 00:00:00
PB - Springer Nature
SP - 2630-2634
IS - 12
VL - 63
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
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BibTex Copy
@article{2014_Zaitsev
author = {K V Zaitsev and E A Kuchuk and B N Mankaev and A.V. Churakov and G.S. Zaitseva and D A Lemenovskii and S.S. Karlov},
title = {Synthesis, structure, and catalytic activity of new aluminum complexes formed with sterically bulky ligands},
journal = {Russian Chemical Bulletin},
year = {2014},
volume = {63},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1007%2Fs11172-014-0790-5},
number = {12},
pages = {2630--2634},
doi = {10.1007/s11172-014-0790-5}
}
MLA
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MLA Copy
Zaitsev, K. V., et al. “Synthesis, structure, and catalytic activity of new aluminum complexes formed with sterically bulky ligands.” Russian Chemical Bulletin, vol. 63, no. 12, Dec. 2014, pp. 2630-2634. https://doi.org/10.1007%2Fs11172-014-0790-5.
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