Russian Journal of Inorganic Chemistry, volume 64, issue 2, pages 207-215

Synthesis, Structure, Optical, and Electrochemical Properties of Iridium(III) Complexes with 2-Arylphenantroimidazoles and Dibenzoylmethane

Publication typeJournal Article
Publication date2019-02-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor2.1
ISSN00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
New cyclometalated neutral iridium(III) complexes [Ir(L)2(dbm)] have been synthesized, where L is 2-arylphenanthroimidazoles with various electron-donor or acceptor substituents, dbm is dibenzoyl-methane. The compositions and structures of the ligands and complexes have been studied by X-ray diffraction and high-resolution mass spectrometry. In the absorption spectra of the complexes, a bathochromic shift of the absorption maxima is observed with an increase in the electron donor properties of the ligands. All the complexes show the reversible redox behavior; redox potentials fall in the range of 0.8–1.6 V. The combination of the obtained results allows us to consider the synthesized compounds as potential photosensitizers in solar cells.

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GOST Copy
Bilyalova A. et al. Synthesis, Structure, Optical, and Electrochemical Properties of Iridium(III) Complexes with 2-Arylphenantroimidazoles and Dibenzoylmethane // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 2. pp. 207-215.
GOST all authors (up to 50) Copy
Bilyalova A., Tatarin S. V., Kalle P., Smirnov D. E., Zharinova I. S., Kiselev Yu. M., Dolzhenko V. D., Bezzubov S. I. Synthesis, Structure, Optical, and Electrochemical Properties of Iridium(III) Complexes with 2-Arylphenantroimidazoles and Dibenzoylmethane // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 2. pp. 207-215.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0036023619020037
UR - https://doi.org/10.1134%2FS0036023619020037
TI - Synthesis, Structure, Optical, and Electrochemical Properties of Iridium(III) Complexes with 2-Arylphenantroimidazoles and Dibenzoylmethane
T2 - Russian Journal of Inorganic Chemistry
AU - Bilyalova, A.A.
AU - Tatarin, S V
AU - Kalle, P
AU - Smirnov, D E
AU - Zharinova, I S
AU - Kiselev, Yu M
AU - Dolzhenko, V D
AU - Bezzubov, S I
PY - 2019
DA - 2019/02/01 00:00:00
PB - Pleiades Publishing
SP - 207-215
IS - 2
VL - 64
SN - 0036-0236
SN - 1531-8613
ER -
BibTex |
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BibTex Copy
@article{2019_Bilyalova,
author = {A.A. Bilyalova and S V Tatarin and P Kalle and D E Smirnov and I S Zharinova and Yu M Kiselev and V D Dolzhenko and S I Bezzubov},
title = {Synthesis, Structure, Optical, and Electrochemical Properties of Iridium(III) Complexes with 2-Arylphenantroimidazoles and Dibenzoylmethane},
journal = {Russian Journal of Inorganic Chemistry},
year = {2019},
volume = {64},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134%2FS0036023619020037},
number = {2},
pages = {207--215},
doi = {10.1134/S0036023619020037}
}
MLA
Cite this
MLA Copy
Bilyalova, A.A., et al. “Synthesis, Structure, Optical, and Electrochemical Properties of Iridium(III) Complexes with 2-Arylphenantroimidazoles and Dibenzoylmethane.” Russian Journal of Inorganic Chemistry, vol. 64, no. 2, Feb. 2019, pp. 207-215. https://doi.org/10.1134%2FS0036023619020037.
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