Russian Chemical Reviews, volume 87, issue 1, pages 89-108

Synthesis of glycolurils and their analogues

Publication typeJournal Article
Publication date2018-01-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor7.7
ISSN0036021X, 14684837
General Chemistry
Abstract

Glycolurils — tetrahydroimidazo[4,5-d]imidazole-2,5(1H,3H)-diones — have found widespread applications in various fields of science and technology. Among them, there are pharmacologically active compounds (antibacterial, nootropic, neurotropic agents, etc.), explosives, gelators, etc. They are used as building blocks in supramolecular chemistry. Therefore, the development of new methods for the synthesis of glycolurils and their analogues has constantly attracted the attention of researchers. In this review, we analyze various approaches to the synthesis of glycolurils and their analogues. The review covers both classical reactions of ureas and related compounds with α-dicarbonyl compounds or with 4,5-dihydroxyimida-zolidin-2-ones (-thiones) and their imino analogues and new original reactions of 4,5-dihydroxyimidazolidin-2-ones (-thiones), imidazolinones and their bicyclic analogues with ureas and KNCS in the presence of acids, condensations of 1,4-disubstituted 1,4-diaza-1,3-dienes with isocyanic and/or isothiocyanic acids or isocyanates, triazine ring contraction in imidazotriazines to give the imidazolidine ring, and transformations of urazoles.

The bibliography includes 129 references.

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Kravchenko A. N., Baranov V. V., Gazieva G. A. Synthesis of glycolurils and their analogues // Russian Chemical Reviews. 2018. Vol. 87. No. 1. pp. 89-108.
GOST all authors (up to 50) Copy
Kravchenko A. N., Baranov V. V., Gazieva G. A. Synthesis of glycolurils and their analogues // Russian Chemical Reviews. 2018. Vol. 87. No. 1. pp. 89-108.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1070/RCR4763
UR - https://doi.org/10.1070%2FRCR4763
TI - Synthesis of glycolurils and their analogues
T2 - Russian Chemical Reviews
AU - Kravchenko, Angelina N.
AU - Baranov, Vladimir V.
AU - Gazieva, Galina A.
PY - 2018
DA - 2018/01/01 00:00:00
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
SP - 89-108
IS - 1
VL - 87
SN - 0036-021X
SN - 1468-4837
ER -
BibTex |
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BibTex Copy
@article{2018_Kravchenko
author = {Angelina N. Kravchenko and Vladimir V. Baranov and Galina A. Gazieva},
title = {Synthesis of glycolurils and their analogues},
journal = {Russian Chemical Reviews},
year = {2018},
volume = {87},
publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},
month = {jan},
url = {https://doi.org/10.1070%2FRCR4763},
number = {1},
pages = {89--108},
doi = {10.1070/RCR4763}
}
MLA
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MLA Copy
Kravchenko, Angelina N., et al. “Synthesis of glycolurils and their analogues.” Russian Chemical Reviews, vol. 87, no. 1, Jan. 2018, pp. 89-108. https://doi.org/10.1070%2FRCR4763.
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