Journal of Chemical Thermodynamics, volume 89, pages 270-277

Standard molar volumes and expansibilities of 1,3-alkyl-N-substituted achiral glycolurils in water at T = (278.15 to 318.15) K and p = 0.1 MPa: A comparative analysis

Publication typeJournal Article
Publication date2015-10-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor2.6
ISSN00219614, 10963626
Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics
General Materials Science
Abstract
Abstract Densities of aqueous solutions of achiral 1,3-dimethylglycoluril (1,3-DMGU) and 1,3-diethylglycoluril (1,3-DEGU) were measured using a hermetically sealed vibrating-tube densimeter, with an uncertainty of 1 · 10−5 g · cm−3, at T = (278.15, 288.15, 298.15, 308.15, and 318.15) K and p = (99.6 ± 0.8) kPa. The solute molality was ranged from (0.06 to 0.39) and from (0.01 to 0.07) mol · kg−1 for the aqueous 1,3-DMGU and 1,3-DEGU, respectively. The standard (at infinite dilution) molar volumes and isobaric expansibilities for the 1,3-dialkyl-N-substituted glycolurils compared in water were calculated and discussed in comparison with the previously derived molar enthalpies and heat capacities of their dissolution (hydration). The temperature-dependent behavior of packing-related hydration effects was described taking into account the structural features of a solute molecule.

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Ivanov E. et al. Standard molar volumes and expansibilities of 1,3-alkyl-N-substituted achiral glycolurils in water at T = (278.15 to 318.15) K and p = 0.1 MPa: A comparative analysis // Journal of Chemical Thermodynamics. 2015. Vol. 89. pp. 270-277.
GOST all authors (up to 50) Copy
Ivanov E., Lebedeva E., Abrosimov V. K., Baranov V. V., Gazieva G. A., Kravchenko A. N. Standard molar volumes and expansibilities of 1,3-alkyl-N-substituted achiral glycolurils in water at T = (278.15 to 318.15) K and p = 0.1 MPa: A comparative analysis // Journal of Chemical Thermodynamics. 2015. Vol. 89. pp. 270-277.
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TY - JOUR
DO - 10.1016/j.jct.2015.05.028
UR - https://doi.org/10.1016%2Fj.jct.2015.05.028
TI - Standard molar volumes and expansibilities of 1,3-alkyl-N-substituted achiral glycolurils in water at T = (278.15 to 318.15) K and p = 0.1 MPa: A comparative analysis
T2 - Journal of Chemical Thermodynamics
AU - Ivanov, Evgeniy
AU - Abrosimov, Vladimir K
AU - Baranov, Vladimir V.
AU - Gazieva, Galina A.
AU - Kravchenko, Angelina N.
AU - Lebedeva, Elena
PY - 2015
DA - 2015/10/01 00:00:00
PB - Elsevier
SP - 270-277
VL - 89
SN - 0021-9614
SN - 1096-3626
ER -
BibTex
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BibTex Copy
@article{2015_Ivanov
author = {Evgeniy Ivanov and Vladimir K Abrosimov and Vladimir V. Baranov and Galina A. Gazieva and Angelina N. Kravchenko and Elena Lebedeva},
title = {Standard molar volumes and expansibilities of 1,3-alkyl-N-substituted achiral glycolurils in water at T = (278.15 to 318.15) K and p = 0.1 MPa: A comparative analysis},
journal = {Journal of Chemical Thermodynamics},
year = {2015},
volume = {89},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016%2Fj.jct.2015.05.028},
pages = {270--277},
doi = {10.1016/j.jct.2015.05.028}
}
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