Journal of Chemical Thermodynamics, volume 89, pages 270-277
Standard molar volumes and expansibilities of 1,3-alkyl-N-substituted achiral glycolurils in water at T = (278.15 to 318.15) K and p = 0.1 MPa: A comparative analysis
Publication type: Journal Article
Publication date: 2015-10-01
Journal:
Journal of Chemical Thermodynamics
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.6
ISSN: 00219614, 10963626
Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics
General Materials Science
Abstract
Abstract Densities of aqueous solutions of achiral 1,3-dimethylglycoluril (1,3-DMGU) and 1,3-diethylglycoluril (1,3-DEGU) were measured using a hermetically sealed vibrating-tube densimeter, with an uncertainty of 1 · 10−5 g · cm−3, at T = (278.15, 288.15, 298.15, 308.15, and 318.15) K and p = (99.6 ± 0.8) kPa. The solute molality was ranged from (0.06 to 0.39) and from (0.01 to 0.07) mol · kg−1 for the aqueous 1,3-DMGU and 1,3-DEGU, respectively. The standard (at infinite dilution) molar volumes and isobaric expansibilities for the 1,3-dialkyl-N-substituted glycolurils compared in water were calculated and discussed in comparison with the previously derived molar enthalpies and heat capacities of their dissolution (hydration). The temperature-dependent behavior of packing-related hydration effects was described taking into account the structural features of a solute molecule.
Citations by journals
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Journal of Molecular Liquids
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Journal of Molecular Liquids
3 publications, 60%
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Journal of Chemical Thermodynamics
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2 publications, 40%
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Citations by publishers
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Elsevier
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Elsevier
5 publications, 100%
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Ivanov E. et al. Standard molar volumes and expansibilities of 1,3-alkyl-N-substituted achiral glycolurils in water at T = (278.15 to 318.15) K and p = 0.1 MPa: A comparative analysis // Journal of Chemical Thermodynamics. 2015. Vol. 89. pp. 270-277.
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Ivanov E., Lebedeva E., Abrosimov V. K., Baranov V. V., Gazieva G. A., Kravchenko A. N. Standard molar volumes and expansibilities of 1,3-alkyl-N-substituted achiral glycolurils in water at T = (278.15 to 318.15) K and p = 0.1 MPa: A comparative analysis // Journal of Chemical Thermodynamics. 2015. Vol. 89. pp. 270-277.
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TY - JOUR
DO - 10.1016/j.jct.2015.05.028
UR - https://doi.org/10.1016%2Fj.jct.2015.05.028
TI - Standard molar volumes and expansibilities of 1,3-alkyl-N-substituted achiral glycolurils in water at T = (278.15 to 318.15) K and p = 0.1 MPa: A comparative analysis
T2 - Journal of Chemical Thermodynamics
AU - Ivanov, Evgeniy
AU - Abrosimov, Vladimir K
AU - Baranov, Vladimir V.
AU - Gazieva, Galina A.
AU - Kravchenko, Angelina N.
AU - Lebedeva, Elena
PY - 2015
DA - 2015/10/01 00:00:00
PB - Elsevier
SP - 270-277
VL - 89
SN - 0021-9614
SN - 1096-3626
ER -
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@article{2015_Ivanov
author = {Evgeniy Ivanov and Vladimir K Abrosimov and Vladimir V. Baranov and Galina A. Gazieva and Angelina N. Kravchenko and Elena Lebedeva},
title = {Standard molar volumes and expansibilities of 1,3-alkyl-N-substituted achiral glycolurils in water at T = (278.15 to 318.15) K and p = 0.1 MPa: A comparative analysis},
journal = {Journal of Chemical Thermodynamics},
year = {2015},
volume = {89},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016%2Fj.jct.2015.05.028},
pages = {270--277},
doi = {10.1016/j.jct.2015.05.028}
}