Reactive and Functional Polymers, volume 154, pages 104648
Sodium 3-azidopropyldialkoxysilanolate - A versatile route towards new functional 1,2,3–triazole based hyperbranched polyorganoalkoxysiloxanes
Migulin Dmitry
1
,
Zezin A.
1, 2
,
Zezina Elena
2
,
Milenin Sergey
,
Cherkaev Georgy
1
,
Muzafarov Aziz
,
Milenin Sergey A
1
,
Publication type: Journal Article
Publication date: 2020-09-01
Journal:
Reactive and Functional Polymers
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.1
ISSN: 13815148
Materials Chemistry
General Chemistry
Biochemistry
General Chemical Engineering
Polymers and Plastics
Environmental Chemistry
Abstract
Abstract A new type of hybrid organosilicone polymer combining the coordination ability of triazole rings with the advantages of the highly branched topological structure of the flexible polysiloxane backbone was synthesized, characterized and exploited for the formation and stabilization of silver nanoparticles. In this study a series of functional 3-azidopropylethoxysiloxanes and poly-1,2,3-triazoleorganoethoxysiloxanes with controlled molecular architectures were synthesized and characterized for the first time using controlled condensation of the new AB2-type sodiumoxo-3-azidopropyldiethoxysilane monomer and the Copper(I)-catalyzed azide-alkyne cycloaddition “Click chemistry” process. The new 1,2,3-triazole-based hybrid polymers with a functional hyperbranched polyethoxysiloxane polymer backbone showed the ability to stabilize ultrasmall silver nanoparticles. The synthesized structures were characterized using 29Si NMR, 1H NMR, FTIR, Mass-spectrometry, and GPC. Polymer nanocomposites with the stabilized silver nanoparticles were characterized by transmission electron microscopy (TEM).
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1
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Migulin D. et al. Sodium 3-azidopropyldialkoxysilanolate - A versatile route towards new functional 1,2,3–triazole based hyperbranched polyorganoalkoxysiloxanes // Reactive and Functional Polymers. 2020. Vol. 154. p. 104648.
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Migulin D., Milenin S., Cherkaev G., Zezin A., Zezina E., Muzafarov A., Milenin S. A., Muzafarov A. M. Sodium 3-azidopropyldialkoxysilanolate - A versatile route towards new functional 1,2,3–triazole based hyperbranched polyorganoalkoxysiloxanes // Reactive and Functional Polymers. 2020. Vol. 154. p. 104648.
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TY - JOUR
DO - 10.1016/j.reactfunctpolym.2020.104648
UR - https://doi.org/10.1016%2Fj.reactfunctpolym.2020.104648
TI - Sodium 3-azidopropyldialkoxysilanolate - A versatile route towards new functional 1,2,3–triazole based hyperbranched polyorganoalkoxysiloxanes
T2 - Reactive and Functional Polymers
AU - Migulin, Dmitry
AU - Milenin, Sergey
AU - Cherkaev, Georgy
AU - Zezin, A.
AU - Zezina, Elena
AU - Muzafarov, Aziz
AU - Milenin, Sergey A
AU - Muzafarov, Aziz M.
PY - 2020
DA - 2020/09/01 00:00:00
PB - Elsevier
SP - 104648
VL - 154
SN - 1381-5148
ER -
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@article{2020_Migulin,
author = {Dmitry Migulin and Sergey Milenin and Georgy Cherkaev and A. Zezin and Elena Zezina and Aziz Muzafarov and Sergey A Milenin and Aziz M. Muzafarov},
title = {Sodium 3-azidopropyldialkoxysilanolate - A versatile route towards new functional 1,2,3–triazole based hyperbranched polyorganoalkoxysiloxanes},
journal = {Reactive and Functional Polymers},
year = {2020},
volume = {154},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016%2Fj.reactfunctpolym.2020.104648},
pages = {104648},
doi = {10.1016/j.reactfunctpolym.2020.104648}
}