Russian Journal of Organic Chemistry, volume 56, issue 4, pages 569-575
Heptalene Synthesis by Addition of Aryl Acetylenes to Azulenes
Publication type: Journal Article
Publication date: 2020-04-01
Journal:
Russian Journal of Organic Chemistry
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 0.8
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
Abstract Aryl acetylenes bearing electron-withdrawing groups have been found that can add to azulenes and yield 1,2-substituted heptalenes. Theoretical studies of the reaction mechanism helped to design the candidate molecules that have then been tested in the synthetic work. New heptalenes are obtained by reacting methyl (4-nitrophenyl)propiolate with either 4,6,8-trimethylazulene or guaiazulene, as well as 3-(4-nitrophenyl)-2-propyn-1-ol with guaiazulene. This opens a new synthetic route to 1-aryl-substituted heptalenes.
Citations by journals
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1
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Journal of Chemical Physics
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Journal of Chemical Physics
1 publication, 50%
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Matter
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Matter
1 publication, 50%
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1
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Citations by publishers
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1
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American Institute of Physics (AIP)
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American Institute of Physics (AIP)
1 publication, 50%
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Elsevier
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Elsevier
1 publication, 50%
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1
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GOST
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Briling K. R., Laikov D. Heptalene Synthesis by Addition of Aryl Acetylenes to Azulenes // Russian Journal of Organic Chemistry. 2020. Vol. 56. No. 4. pp. 569-575.
GOST all authors (up to 50)
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Briling K. R., Laikov D. Heptalene Synthesis by Addition of Aryl Acetylenes to Azulenes // Russian Journal of Organic Chemistry. 2020. Vol. 56. No. 4. pp. 569-575.
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TY - JOUR
DO - 10.1134/S1070428020040028
UR - https://doi.org/10.1134%2FS1070428020040028
TI - Heptalene Synthesis by Addition of Aryl Acetylenes to Azulenes
T2 - Russian Journal of Organic Chemistry
AU - Briling, K R
AU - Laikov, D.N.
PY - 2020
DA - 2020/04/01 00:00:00
PB - Pleiades Publishing
SP - 569-575
IS - 4
VL - 56
SN - 1070-4280
SN - 1608-3393
ER -
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BibTex
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@article{2020_Briling,
author = {K R Briling and D.N. Laikov},
title = {Heptalene Synthesis by Addition of Aryl Acetylenes to Azulenes},
journal = {Russian Journal of Organic Chemistry},
year = {2020},
volume = {56},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134%2FS1070428020040028},
number = {4},
pages = {569--575},
doi = {10.1134/S1070428020040028}
}
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MLA
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Briling, K. R., and D.N. Laikov. “Heptalene Synthesis by Addition of Aryl Acetylenes to Azulenes.” Russian Journal of Organic Chemistry, vol. 56, no. 4, Apr. 2020, pp. 569-575. https://doi.org/10.1134%2FS1070428020040028.
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