Russian Chemical Bulletin, volume 61, issue 11, pages 2056-2064
Interaction of 18-crown-6 with yttrium chloride: Inner-sphere transformations of complexes under conditions of solid-state thermolysis
Publication type: Journal Article
Publication date: 2012-11-01
Journal:
Russian Chemical Bulletin
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.7
ISSN: 10665285, 15739171
General Chemistry
Abstract
The reactions of [YCl2(H2O)6]Cl with 18-crown-6 in aliphatic alcohol solutions afford the complexes [Y(H2O)3(18-crown-6)]Cl3·1.25H2O (1) and [Y(H2O)8]Cl3·(18-crown-6)·4H2O (2), in which the inner coordination sphere of yttrium consists of nine and eight oxygen atoms, respectively. The inner-sphere transformations of complexes 1 and 2 under conditions of solid-state thermolysis were investigated. After the removal of coordinated water molecules from compound 1, the complex undergoes a structural transformation at temperatures above 180 °C, resulting in that two chloride anions enter into the coordination sphere of yttrium. For compound 2, a double exothermic effect is observed in the temperature range of 160–300 °C due to the formation of a certain new structural species containing chloride ions and 18-crown-6 in the inner coordination sphere.
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Dobrokhotova Z. V. et al. Interaction of 18-crown-6 with yttrium chloride: Inner-sphere transformations of complexes under conditions of solid-state thermolysis // Russian Chemical Bulletin. 2012. Vol. 61. No. 11. pp. 2056-2064.
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Dobrokhotova Z. V., Petrosyants S. P., Ilyukhin A. B., Novotortsev V. M. Interaction of 18-crown-6 with yttrium chloride: Inner-sphere transformations of complexes under conditions of solid-state thermolysis // Russian Chemical Bulletin. 2012. Vol. 61. No. 11. pp. 2056-2064.
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TY - JOUR
DO - 10.1007/s11172-012-0287-z
UR - https://doi.org/10.1007%2Fs11172-012-0287-z
TI - Interaction of 18-crown-6 with yttrium chloride: Inner-sphere transformations of complexes under conditions of solid-state thermolysis
T2 - Russian Chemical Bulletin
AU - Dobrokhotova, Zh V
AU - Petrosyants, S P
AU - Ilyukhin, A. B.
AU - Novotortsev, V. M.
PY - 2012
DA - 2012/11/01 00:00:00
PB - Springer Nature
SP - 2056-2064
IS - 11
VL - 61
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2012_Dobrokhotova,
author = {Zh V Dobrokhotova and S P Petrosyants and A. B. Ilyukhin and V. M. Novotortsev},
title = {Interaction of 18-crown-6 with yttrium chloride: Inner-sphere transformations of complexes under conditions of solid-state thermolysis},
journal = {Russian Chemical Bulletin},
year = {2012},
volume = {61},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007%2Fs11172-012-0287-z},
number = {11},
pages = {2056--2064},
doi = {10.1007/s11172-012-0287-z}
}
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MLA
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Dobrokhotova, Zh V., et al. “Interaction of 18-crown-6 with yttrium chloride: Inner-sphere transformations of complexes under conditions of solid-state thermolysis.” Russian Chemical Bulletin, vol. 61, no. 11, Nov. 2012, pp. 2056-2064. https://doi.org/10.1007%2Fs11172-012-0287-z.
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