Journal of Chemical Thermodynamics, volume 115, pages 148-155

Standard volumetric properties of a chiral pharmaceutical Albicar in water H/D isotopologues in the temperature range from (278.15 to 318.15) K and at ambient pressure

Publication typeJournal Article
Publication date2017-12-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor2.6
ISSN00219614, 10963626
Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics
General Materials Science
Abstract
Abstract Densities of solutions of the chiral (in the racemic form) trans-dimethyldiethylglycoluril (1,4-diethyl-3,6-dimethyltetrahydroimidazo[4,5-d]imidazole-2,5(1H,3H)-dione), being a promising tranquilizer Albicar, in ordinary (H2O) and heavy (D2O) water were measured using the Anton Paar DMA 5000 M high-precision vibrating tube densimeter. All experiments were performed within the temperature range between 278.15 K and 318.15 K (with a step of 10 K) at the pressure to be ca. 99.6 kPa. The solution aquamolality was ranged from ca. 0.02 to ca. 0.2 mol (55.51 mol of solvent)−1 for each of H/D isotopically distinguishable systems compared. The standard (partial at infinite dilution) molar volumes as well as expansibilities of the solute were derived from the solution density data. The behavior of solvent isotope effects (IEs) on the considered quantities were described taking account of structure- and interaction-related features of H2O and D2O media. It was confirmed that the Albicar hydration is enhanced overall in the D2O medium. The volumetric characteristics for the heterocyclic solute being studied were discussed in comparison with those for Mebicar (1,3,4,6-tetramethyl-derivative) and Bicaret (1,3,4,6-tetraethyl-derivative), using the previous our results.

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Ivanov E., Lebedeva E. Yu., Kravchenko A. N. Standard volumetric properties of a chiral pharmaceutical Albicar in water H/D isotopologues in the temperature range from (278.15 to 318.15) K and at ambient pressure // Journal of Chemical Thermodynamics. 2017. Vol. 115. pp. 148-155.
GOST all authors (up to 50) Copy
Ivanov E., Lebedeva E. Yu., Kravchenko A. N. Standard volumetric properties of a chiral pharmaceutical Albicar in water H/D isotopologues in the temperature range from (278.15 to 318.15) K and at ambient pressure // Journal of Chemical Thermodynamics. 2017. Vol. 115. pp. 148-155.
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TY - JOUR
DO - 10.1016/j.jct.2017.07.034
UR - https://doi.org/10.1016%2Fj.jct.2017.07.034
TI - Standard volumetric properties of a chiral pharmaceutical Albicar in water H/D isotopologues in the temperature range from (278.15 to 318.15) K and at ambient pressure
T2 - Journal of Chemical Thermodynamics
AU - Ivanov, Evgeniy
AU - Lebedeva, Elena Yu
AU - Kravchenko, Angelina N.
PY - 2017
DA - 2017/12/01 00:00:00
PB - Elsevier
SP - 148-155
VL - 115
SN - 0021-9614
SN - 1096-3626
ER -
BibTex
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BibTex Copy
@article{2017_Ivanov
author = {Evgeniy Ivanov and Elena Yu Lebedeva and Angelina N. Kravchenko},
title = {Standard volumetric properties of a chiral pharmaceutical Albicar in water H/D isotopologues in the temperature range from (278.15 to 318.15) K and at ambient pressure},
journal = {Journal of Chemical Thermodynamics},
year = {2017},
volume = {115},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016%2Fj.jct.2017.07.034},
pages = {148--155},
doi = {10.1016/j.jct.2017.07.034}
}
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