Mendeleev Communications, volume 31, issue 1, pages 58-61
Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5 Me5 )2 Fe/C2 I2 cocrystal and ionic [(C5 Me5 )2 Fe]Br3 crystal
Publication type: Journal Article
Publication date: 2021-01-01
Journal:
Mendeleev Communications
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Almost equal molecular sizes of diiodoacetylene (C2I2) and the [Br3]− anion result in isomorphic neutral cocrystal (DMFc–C2I2) and [DMFc]+Br3− salt. This isomorphic pair of neutral and ionic crystals provides a unique example for the analysis of different types of bonding resulting in isotypic solid-state structures. Their energy frameworks visualize the obvious difference between their energetic structures: the lattice of DMFc–C2I2 is built upon the chains stabilized by I···(η5-C5Me5) halogen bonds; at the same time, [DMFc]+Br3− consists of electrostatically assembled layers associated by Br···π(Cp*) XBs interactions.
Citations by journals
1
2
3
4
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Journal of Structural Chemistry
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Journal of Structural Chemistry
4 publications, 25%
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Molecules
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Molecules
2 publications, 12.5%
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CrystEngComm
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CrystEngComm
2 publications, 12.5%
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Journal of Organometallic Chemistry
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Journal of Organometallic Chemistry
1 publication, 6.25%
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Chemistry
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Chemistry
1 publication, 6.25%
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Polyhedron
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Polyhedron
1 publication, 6.25%
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Inorganica Chimica Acta
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Inorganica Chimica Acta
1 publication, 6.25%
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Acta crystallographica. Section C, Structural chemistry
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Acta crystallographica. Section C, Structural chemistry
1 publication, 6.25%
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Russian Journal of Inorganic Chemistry
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Russian Journal of Inorganic Chemistry
1 publication, 6.25%
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Russian Chemical Bulletin
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Russian Chemical Bulletin
1 publication, 6.25%
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Chemistry - A European Journal
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Chemistry - A European Journal
1 publication, 6.25%
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3
4
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Citations by publishers
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3
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5
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Pleiades Publishing
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Pleiades Publishing
5 publications, 31.25%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
3 publications, 18.75%
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Elsevier
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Elsevier
3 publications, 18.75%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
2 publications, 12.5%
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International Union of Crystallography (IUCr)
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International Union of Crystallography (IUCr)
1 publication, 6.25%
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Springer Nature
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Springer Nature
1 publication, 6.25%
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Wiley
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Wiley
1 publication, 6.25%
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1
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5
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Torubaev Y. V. et al. Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal // Mendeleev Communications. 2021. Vol. 31. No. 1. pp. 58-61.
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Torubaev Y. V., Skabitsky I. V., Saratov G. A., Barzilovich P. Yu. Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal // Mendeleev Communications. 2021. Vol. 31. No. 1. pp. 58-61.
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TY - JOUR
DO - 10.1016/j.mencom.2021.01.017
UR - https://doi.org/10.1016%2Fj.mencom.2021.01.017
TI - Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal
T2 - Mendeleev Communications
AU - Torubaev, Yu. V.
AU - Skabitsky, I. V.
AU - Saratov, Georgy A
AU - Barzilovich, Petr Yu
PY - 2021
DA - 2021/01/01 00:00:00
PB - Elsevier
SP - 58-61
IS - 1
VL - 31
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2021_Torubaev
author = {Yu. V. Torubaev and I. V. Skabitsky and Georgy A Saratov and Petr Yu Barzilovich},
title = {Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.mencom.2021.01.017},
number = {1},
pages = {58--61},
doi = {10.1016/j.mencom.2021.01.017}
}
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Torubaev, Yu. V., et al. “Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal.” Mendeleev Communications, vol. 31, no. 1, Jan. 2021, pp. 58-61. https://doi.org/10.1016%2Fj.mencom.2021.01.017.