Mendeleev Communications, volume 31, issue 1, pages 58-61

Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal

Publication typeJournal Article
Publication date2021-01-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor1.9
ISSN09599436, 1364551X
General Chemistry
Abstract
Almost equal molecular sizes of diiodoacetylene (C2I2) and the [Br3]− anion result in isomorphic neutral cocrystal (DMFc–C2I2) and [DMFc]+Br3− salt. This isomorphic pair of neutral and ionic crystals provides a unique example for the analysis of different types of bonding resulting in isotypic solid-state structures. Their energy frameworks visualize the obvious difference between their energetic structures: the lattice of DMFc–C2I2 is built upon the chains stabilized by I···(η5-C5Me5) halogen bonds; at the same time, [DMFc]+Br3− consists of electrostatically assembled layers associated by Br···π(Cp*) XBs interactions.

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Torubaev Y. V. et al. Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal // Mendeleev Communications. 2021. Vol. 31. No. 1. pp. 58-61.
GOST all authors (up to 50) Copy
Torubaev Y. V., Skabitsky I. V., Saratov G. A., Barzilovich P. Yu. Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal // Mendeleev Communications. 2021. Vol. 31. No. 1. pp. 58-61.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2021.01.017
UR - https://doi.org/10.1016%2Fj.mencom.2021.01.017
TI - Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal
T2 - Mendeleev Communications
AU - Torubaev, Yu. V.
AU - Skabitsky, I. V.
AU - Saratov, Georgy A
AU - Barzilovich, Petr Yu
PY - 2021
DA - 2021/01/01 00:00:00
PB - Elsevier
SP - 58-61
IS - 1
VL - 31
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
Cite this
BibTex Copy
@article{2021_Torubaev
author = {Yu. V. Torubaev and I. V. Skabitsky and Georgy A Saratov and Petr Yu Barzilovich},
title = {Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.mencom.2021.01.017},
number = {1},
pages = {58--61},
doi = {10.1016/j.mencom.2021.01.017}
}
MLA
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Torubaev, Yu. V., et al. “Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal.” Mendeleev Communications, vol. 31, no. 1, Jan. 2021, pp. 58-61. https://doi.org/10.1016%2Fj.mencom.2021.01.017.
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