Open Access

Applied Surface Science, volume 433, pages 582-588

XPS study of the surface chemistry of UO 2 (111) single crystal film

Maslakov Konstantin ¹

Kalmykov Stepan N.

Petrov Vladimir G

Teterin Yury A ^{2, 3}

Popel Aleksej J ^{4, 5}

Teterin Anton Yu ³

Ivanov Kirill E ³

Farnan Ian ⁶

Springell Ross

Scott Thomas B

Kalmykov Stepan N. ^{2, 3}

Petrov Vladimir G ¹

Springell R. ⁷

Scott Thomas B. ⁸

Hide authors affiliations Show authors affiliations: 8 affiliations

Lomonosov Moscow State Univ. |

Lomonosov Moscow State University |

NRC Kurchatov Institute |

⁴

University of Cambridge |

⁵

IMPERIAL COLLEGE LONDON |

⁶

Univ. of Cambridge |

⁷

Interface Analysis Centre School of Physics University of Bristol Bristol BS8 1TL UK |

⁸

The Bristol Centre for Nanoscience and Quantum Information

Publication type: Journal Article

Publication date: 2018-03-01

Elsevier

Journal: Applied Surface Science

Quartile SCImago

Quartile WOS

Impact factor: 6.7

ISSN: 01694332

DOI: 10.1016/j.apsusc.2017.10.019

Copy DOI

Surfaces, Coatings and Films

General Chemistry

General Physics and Astronomy

Condensed Matter Physics

Surfaces and Interfaces

Abstract

Abstract A (111) air-exposed surface of UO 2 thin film (150 nm) on (111) YSZ (yttria-stabilized zirconia) before and after the Ar + etching and subsequent in situ annealing in the spectrometer analytic chamber was studied by XPS technique. The U 5f, U 4f and O 1s electron peak intensities were employed for determining the oxygen coefficient k O = 2 + x of a UO 2+ x oxide on the surface. It was found that initial surface (several nm) had k O = 2.20. A 20 s Ar + etching led to formation of oxide UO 2.12 , whose composition does not depend significantly on the etching time (up to 180 s). Ar + etching and subsequent annealing at temperatures 100–380 °C in vacuum was established to result in formation of stable well-organized structure UO 2.12 reflected in the U 4f XPS spectra as high intensity (∼28% of the basic peak) shake-up satellites 6.9 eV away from the basic peaks, and virtually did not change the oxygen coefficient of the sample surface. This agrees with the suggestion that a stable (self-assembling) phase with the oxygen coefficient k O ≈ 2.12 forms on the UO 2 surface.

By date By citations

Citations by journals

	1 2 3 4
Applied Surface Science	Applied Surface Science, 4, 11.43% Applied Surface Science 4 publications, 11.43%
Surface Science	Surface Science, 3, 8.57% Surface Science 3 publications, 8.57%
Inorganic Chemistry	Inorganic Chemistry, 3, 8.57% Inorganic Chemistry 3 publications, 8.57%
ChemCatChem	ChemCatChem, 2, 5.71% ChemCatChem 2 publications, 5.71%
ACS applied materials & interfaces	ACS applied materials & interfaces, 2, 5.71% ACS applied materials & interfaces 2 publications, 5.71%
International Journal of Quantum Chemistry	International Journal of Quantum Chemistry, 1, 2.86% International Journal of Quantum Chemistry 1 publication, 2.86%
Radiochemistry	Radiochemistry, 1, 2.86% Radiochemistry 1 publication, 2.86%
Journal of Radioanalytical and Nuclear Chemistry	Journal of Radioanalytical and Nuclear Chemistry, 1, 2.86% Journal of Radioanalytical and Nuclear Chemistry 1 publication, 2.86%
Science of the Total Environment	Science of the Total Environment, 1, 2.86% Science of the Total Environment 1 publication, 2.86%
Journal of Hazardous Materials	Journal of Hazardous Materials, 1, 2.86% Journal of Hazardous Materials 1 publication, 2.86%
Reports on Progress in Physics	Reports on Progress in Physics, 1, 2.86% Reports on Progress in Physics 1 publication, 2.86%
Algal Research	Algal Research, 1, 2.86% Algal Research 1 publication, 2.86%
Journal of Nuclear Materials	Journal of Nuclear Materials, 1, 2.86% Journal of Nuclear Materials 1 publication, 2.86%
Progress in Nuclear Energy	Progress in Nuclear Energy, 1, 2.86% Progress in Nuclear Energy 1 publication, 2.86%
Colloids and Surfaces A: Physicochemical and Engineering Aspects	Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1, 2.86% Colloids and Surfaces A: Physicochemical and Engineering Aspects 1 publication, 2.86%
Biotechnology and Bioengineering	Biotechnology and Bioengineering, 1, 2.86% Biotechnology and Bioengineering 1 publication, 2.86%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 2.86% Journal of Physical Chemistry C 1 publication, 2.86%
ACS Catalysis	ACS Catalysis, 1, 2.86% ACS Catalysis 1 publication, 2.86%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 2.86% ACS Applied Energy Materials 1 publication, 2.86%
Sustainable Energy and Fuels	Sustainable Energy and Fuels, 1, 2.86% Sustainable Energy and Fuels 1 publication, 2.86%
ACS Materials Au	ACS Materials Au, 1, 2.86% ACS Materials Au 1 publication, 2.86%
Advances in Physics	Advances in Physics, 1, 2.86% Advances in Physics 1 publication, 2.86%
Chemosphere	Chemosphere, 1, 2.86% Chemosphere 1 publication, 2.86%
Molecules	Molecules, 1, 2.86% Molecules 1 publication, 2.86%
Small	Small, 1, 2.86% Small 1 publication, 2.86%
	1 2 3 4

Citations by publishers

	2 4 6 8 10 12 14
Elsevier	Elsevier, 14, 40% Elsevier 14 publications, 40%
American Chemical Society (ACS)	American Chemical Society (ACS), 9, 25.71% American Chemical Society (ACS) 9 publications, 25.71%
Wiley	Wiley, 5, 14.29% Wiley 5 publications, 14.29%
Pleiades Publishing	Pleiades Publishing, 1, 2.86% Pleiades Publishing 1 publication, 2.86%
Springer Nature	Springer Nature, 1, 2.86% Springer Nature 1 publication, 2.86%
IOP Publishing	IOP Publishing, 1, 2.86% IOP Publishing 1 publication, 2.86%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 2.86% Royal Society of Chemistry (RSC) 1 publication, 2.86%
Taylor & Francis	Taylor & Francis, 1, 2.86% Taylor & Francis 1 publication, 2.86%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 2.86% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 2.86%
	2 4 6 8 10 12 14

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0],"imageUrls":["","","","","","",""],"datasets":[{"label":"Citations number","data":[3,6,4,6,5,7,4],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["8.57","17.14","11.43","17.14","14.29","20","11.43"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Applied Surface Science","Surface Science","Inorganic Chemistry","ChemCatChem","ACS applied materials & interfaces","International Journal of Quantum Chemistry","Radiochemistry","Journal of Radioanalytical and Nuclear Chemistry","Science of the Total Environment","Journal of Hazardous Materials","Reports on Progress in Physics","Algal Research","Journal of Nuclear Materials","Progress in Nuclear Energy","Colloids and Surfaces A: Physicochemical and Engineering Aspects","Biotechnology and Bioengineering","Journal of Physical Chemistry C","ACS Catalysis","ACS Applied Energy Materials","Sustainable Energy and Fuels","ACS Materials Au","Advances in Physics","Chemosphere","Molecules","Small"],"ids":[12539,510,24714,10149,1458,15897,14503,12902,2679,23695,9609,23237,21537,15703,21908,18397,8859,4873,6419,14712,28555,19475,22418,1770,9872],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[4,3,3,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[11.43,8.57,8.57,5.71,5.71,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","American Chemical Society (ACS)","Wiley","Pleiades Publishing","Springer Nature","IOP Publishing","Royal Society of Chemistry (RSC)","Taylor & Francis","Multidisciplinary Digital Publishing Institute (MDPI)"],"ids":[17,40,11,101,8,2075,123,18,202],"codes":[0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp"],"datasets":[{"label":"","data":[14,9,5,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[40,25.71,14.29,2.86,2.86,2.86,2.86,2.86,2.86],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Metrics

Cite this

GOST |

Cite this

GOST Copy

Maslakov K. et al. XPS study of the surface chemistry of UO 2 (111) single crystal film // Applied Surface Science. 2018. Vol. 433. pp. 582-588.

GOST all authors (up to 50) Copy

Maslakov K., Teterin Y. A., Popel A. J., Teterin A. Yu., Ivanov K. E., Kalmykov S. N., Petrov V. G., Springell R., Scott T. B., Farnan I., Kalmykov S. N., Petrov V. G., Springell R., Scott T. B. XPS study of the surface chemistry of UO 2 (111) single crystal film // Applied Surface Science. 2018. Vol. 433. pp. 582-588.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.apsusc.2017.10.019

UR - https://doi.org/10.1016%2Fj.apsusc.2017.10.019

TI - XPS study of the surface chemistry of UO 2 (111) single crystal film

T2 - Applied Surface Science

AU - Maslakov, Konstantin

AU - Teterin, Yury A

AU - Popel, Aleksej J

AU - Teterin, Anton Yu

AU - Ivanov, Kirill E

AU - Kalmykov, Stepan N.

AU - Petrov, Vladimir G

AU - Springell, Ross

AU - Scott, Thomas B

AU - Farnan, Ian

AU - Kalmykov, Stepan N.

AU - Petrov, Vladimir G

AU - Springell, R.

AU - Scott, Thomas B.

PY - 2018

DA - 2018/03/01 00:00:00

PB - Elsevier

SP - 582-588

VL - 433

SN - 0169-4332

ER -

BibTex

Cite this

BibTex Copy

@article{2018_Maslakov,

author = {Konstantin Maslakov and Yury A Teterin and Aleksej J Popel and Anton Yu Teterin and Kirill E Ivanov and Stepan N. Kalmykov and Vladimir G Petrov and Ross Springell and Thomas B Scott and Ian Farnan and Stepan N. Kalmykov and Vladimir G Petrov and R. Springell and Thomas B. Scott},

title = {XPS study of the surface chemistry of UO 2 (111) single crystal film},

journal = {Applied Surface Science},

year = {2018},

volume = {433},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016%2Fj.apsusc.2017.10.019},

pages = {582--588},

doi = {10.1016/j.apsusc.2017.10.019}

}

Found error?

Publisher

Elsevier

Journal

Applied Surface Science

Quartile SCImago

Quartile WOS

Impact factor

6.7

ISSN

01694332 (Print)

Labs

Laboratory of Dosimetry and Environmental Radioactivity (DiROS)

Profiles