Journal of Physical Chemistry Letters, volume 10, issue 4, pages 813-818
γ-Ray-induced degradation in the triple-cation perovskite solar cells
Akbulatov Azat F
2
,
Tsarev Sergey
1
,
Luchkin Sergey
1
,
ZHIDKOV I. S.
3
,
Kurmaev Erst Z
3, 4
,
Troshin Pavel A.
1, 2
Publication type: Journal Article
Publication date: 2019-01-08
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.7
ISSN: 19487185
Physical and Theoretical Chemistry
General Materials Science
Abstract
We report on the impact of γ radiation (0-500 Gy) on triple-cation Cs0.15MA0.10FA0.75Pb(Br0.17I0.83)3 perovskite solar cells. A set of experiments was designed to reveal the individual contributions of the hole-collecting bottom electrode, perovskite absorber, and electron transport layer (ETL) to the overall solar cell degradation under radiation exposure. We show that the glass/ITO/PEDOT:PSS hole-collecting electrode withstands a 500 Gy dose without any losses in the solar cell performance. In contrast, the perovskite absorber films and PC61BM ETL are very sensitive to γ rays, as can be concluded from the radiation-induced decay of the solar cell efficiency by ∼32-41%. Red shift of the perovskite emission bands and strong enhancement of the photoluminescence suggest that γ rays induce phase segregation of iodine-rich and bromine-rich domains, which represents the first reported example of the radiation-induced halide phase separation in perovskite films. The degradation pathway revealed here emphasizes the need for developing a new generation of metal halide absorbers and ETL materials with improved radiation stability to enable potential space applications of perovskite photovoltaics.
Citations by journals
|
1
2
3
4
|
|
|
Journal of Physical Chemistry Letters
|
Journal of Physical Chemistry Letters
4 publications, 10.53%
|
|
ACS applied materials & interfaces
|
ACS applied materials & interfaces
3 publications, 7.89%
|
|
Advanced Materials
|
Advanced Materials
3 publications, 7.89%
|
|
Journal of Physical Chemistry C
|
Journal of Physical Chemistry C
3 publications, 7.89%
|
|
Joule
|
Joule
2 publications, 5.26%
|
|
Radiation Physics and Chemistry
|
Radiation Physics and Chemistry
2 publications, 5.26%
|
|
Advanced Energy Materials
|
Advanced Energy Materials
2 publications, 5.26%
|
|
Advanced Optical Materials
|
Advanced Optical Materials
2 publications, 5.26%
|
|
ACS Applied Energy Materials
|
ACS Applied Energy Materials
2 publications, 5.26%
|
|
ACS Energy Letters
|
ACS Energy Letters
2 publications, 5.26%
|
|
Materials
|
Materials
1 publication, 2.63%
|
|
Journal of Luminescence
|
Journal of Luminescence
1 publication, 2.63%
|
|
Journal of Semiconductors
|
Journal of Semiconductors
1 publication, 2.63%
|
|
Nano Energy
|
Nano Energy
1 publication, 2.63%
|
|
Polymer Degradation and Stability
|
Polymer Degradation and Stability
1 publication, 2.63%
|
|
Small
|
Small
1 publication, 2.63%
|
|
Advanced Materials Technologies
|
Advanced Materials Technologies
1 publication, 2.63%
|
|
Journal of Materials Chemistry C
|
Journal of Materials Chemistry C
1 publication, 2.63%
|
|
Acta Physica Sinica
|
Acta Physica Sinica
1 publication, 2.63%
|
|
Journal of Applied Physics
|
Journal of Applied Physics
1 publication, 2.63%
|
|
Inorganics
|
Inorganics
1 publication, 2.63%
|
|
1
2
3
4
|
Citations by publishers
|
2
4
6
8
10
12
14
|
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
14 publications, 36.84%
|
|
Wiley
|
Wiley
9 publications, 23.68%
|
|
Elsevier
|
Elsevier
7 publications, 18.42%
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 5.26%
|
|
IOP Publishing
|
IOP Publishing
1 publication, 2.63%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
1 publication, 2.63%
|
|
Chinese Physical Society
|
Chinese Physical Society
1 publication, 2.63%
|
|
American Institute of Physics (AIP)
|
American Institute of Physics (AIP)
1 publication, 2.63%
|
|
2
4
6
8
10
12
14
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0],"codes":[0,0,0,0,0,0],"imageUrls":["","","","","",""],"datasets":[{"label":"Citations number","data":[2,6,12,6,7,5],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["5.26","15.79","31.58","15.79","18.42","13.16"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Physical Chemistry Letters","ACS applied materials & interfaces","Advanced Materials","Journal of Physical Chemistry C","Joule","Radiation Physics and Chemistry","Advanced Energy Materials","Advanced Optical Materials","ACS Applied Energy Materials","ACS Energy Letters","Materials","Journal of Luminescence","Journal of Semiconductors","Nano Energy","Polymer Degradation and Stability","Small","Advanced Materials Technologies","Journal of Materials Chemistry C","Acta Physica Sinica","Journal of Applied Physics","Inorganics"],"ids":[21963,1458,25159,8859,22630,14769,22475,2077,6419,9022,25198,7075,18069,23236,10686,9872,114,3848,19189,11951,4005],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/uHl9M7oE4uFd6rEwxtu87cdHS4Etul2pdLbot8Qu_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp"],"datasets":[{"label":"","data":[4,3,3,3,2,2,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[10.53,7.89,7.89,7.89,5.26,5.26,5.26,5.26,5.26,5.26,2.63,2.63,2.63,2.63,2.63,2.63,2.63,2.63,2.63,2.63,2.63],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Wiley","Elsevier","Multidisciplinary Digital Publishing Institute (MDPI)","IOP Publishing","Royal Society of Chemistry (RSC)","Chinese Physical Society","American Institute of Physics (AIP)"],"ids":[40,11,17,202,2075,123,3809,250],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/uHl9M7oE4uFd6rEwxtu87cdHS4Etul2pdLbot8Qu_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp"],"datasets":[{"label":"","data":[14,9,7,2,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[36.84,23.68,18.42,5.26,2.63,2.63,2.63,2.63],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Boldyreva A. G. et al. γ-Ray-induced degradation in the triple-cation perovskite solar cells // Journal of Physical Chemistry Letters. 2019. Vol. 10. No. 4. pp. 813-818.
GOST all authors (up to 50)
Copy
Boldyreva A. G., Akbulatov A. F., Tsarev S., Luchkin S., ZHIDKOV I. S., Kurmaev E. Z., Stevenson K. J., Petrov V. G., Troshin P. A. γ-Ray-induced degradation in the triple-cation perovskite solar cells // Journal of Physical Chemistry Letters. 2019. Vol. 10. No. 4. pp. 813-818.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.jpclett.8b03222
UR - https://doi.org/10.1021%2Facs.jpclett.8b03222
TI - γ-Ray-induced degradation in the triple-cation perovskite solar cells
T2 - Journal of Physical Chemistry Letters
AU - Kurmaev, Erst Z
AU - ZHIDKOV, I. S.
AU - Stevenson, Keith J
AU - Troshin, Pavel A.
AU - Boldyreva, Aleksandra G
AU - Akbulatov, Azat F
AU - Tsarev, Sergey
AU - Luchkin, Sergey
AU - Petrov, Vladimir G
PY - 2019
DA - 2019/01/08 00:00:00
PB - American Chemical Society (ACS)
SP - 813-818
IS - 4
VL - 10
SN - 1948-7185
ER -
Cite this
BibTex
Copy
@article{2019_Boldyreva,
author = {Erst Z Kurmaev and I. S. ZHIDKOV and Keith J Stevenson and Pavel A. Troshin and Aleksandra G Boldyreva and Azat F Akbulatov and Sergey Tsarev and Sergey Luchkin and Vladimir G Petrov},
title = {γ-Ray-induced degradation in the triple-cation perovskite solar cells},
journal = {Journal of Physical Chemistry Letters},
year = {2019},
volume = {10},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021%2Facs.jpclett.8b03222},
number = {4},
pages = {813--818},
doi = {10.1021/acs.jpclett.8b03222}
}
Cite this
MLA
Copy
Boldyreva, Aleksandra G., et al. “γ-Ray-induced degradation in the triple-cation perovskite solar cells.” Journal of Physical Chemistry Letters, vol. 10, no. 4, Jan. 2019, pp. 813-818. https://doi.org/10.1021%2Facs.jpclett.8b03222.