Talanta, volume 221, pages 121485

Extraction and ICP-OES determination of heavy metals using tetrabutylammonium bromide aqueous biphasic system and oleophilic collector

Smirnova Svetlana V ¹

Ilin Dmitry ¹

Pletnev Igor V ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Chemistry Department , Lomonosov Moscow State University , Leninskie Gory 1 , Moscow 119991 , Russia. |

Publication type: Journal Article

Publication date: 2021-01-01

Elsevier

Journal: Talanta

Quartile SCImago

Quartile WOS

Impact factor: 6.1

ISSN: 00399140, 18733573

DOI: 10.1016/j.talanta.2020.121485

Copy DOI

Analytical Chemistry

Abstract

Preconcentration of Cd(II), Co(II), Cu(II), Ni(II), Pb(II), and Zn(II) in aqueous biphasic system tetrabutylammonium bromide (TBAB) – H 2 O – (NH 4 ) 2 SO 4 followed by ICP-OES determination is reported for the first time. All metal ions extracted quantitatively with 4-(2-pyridylazo)-resorcinol. Nonwoven polypropylene collector was used to capture the extract and to assist phase separation. The concentrate was eluted with 0.3 mol L −1 nitric acid and introduced directly into ICP-OES sampling line. Detection limits for cadmium, cobalt, copper, nickel, lead, and zinc were 0.012, 0.2, 0.17, 0.11, 0.2, and 0.4 μg L −1 , respectively; preconcentration factor was 150. The method accuracy was verified by the analysis of certified reference materials samples of waste waters and surface water, as well as the real samples of spring and well water. The use of oleophilic polypropylene collector allowed to handle small volume extract, attain high preconcentration factor and significantly decrease detection limits for ICP-OES determination of heavy metals. • Tetrabutylammonium bromide based aqueous biphasic system for extraction of metal ions with 4-(2-pyridylazo)-resorcinol. • Phase separation by filtering through nonwoven polypropylene collector. • Sensitive ICP-AES determination of Cd, Co, Cu, Ni, Pb and Zn after extraction. • Analysis of certified reference materials and real samples of spring and well water.

By date By citations

Citations by journals

	1 2 3
Journal of Analytical Chemistry	Journal of Analytical Chemistry, 3, 5.66% Journal of Analytical Chemistry 3 publications, 5.66%
Talanta	Talanta, 3, 5.66% Talanta 3 publications, 5.66%
Microchemical Journal	Microchemical Journal, 3, 5.66% Microchemical Journal 3 publications, 5.66%
Foods	Foods, 2, 3.77% Foods 2 publications, 3.77%
Food Chemistry	Food Chemistry, 2, 3.77% Food Chemistry 2 publications, 3.77%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 1.89% Russian Chemical Reviews 1 publication, 1.89%
Molecules	Molecules, 1, 1.89% Molecules 1 publication, 1.89%
International Journal of Molecular Sciences	International Journal of Molecular Sciences, 1, 1.89% International Journal of Molecular Sciences 1 publication, 1.89%
Nanotechnology for Environmental Engineering	Nanotechnology for Environmental Engineering, 1, 1.89% Nanotechnology for Environmental Engineering 1 publication, 1.89%
Ionics	Ionics, 1, 1.89% Ionics 1 publication, 1.89%
Journal of Applied Electrochemistry	Journal of Applied Electrochemistry, 1, 1.89% Journal of Applied Electrochemistry 1 publication, 1.89%
Journal of Applied Spectroscopy	Journal of Applied Spectroscopy, 1, 1.89% Journal of Applied Spectroscopy 1 publication, 1.89%
Sensors	Sensors, 1, 1.89% Sensors 1 publication, 1.89%
Journal of Cleaner Production	Journal of Cleaner Production, 1, 1.89% Journal of Cleaner Production 1 publication, 1.89%
Chemical Engineering Science	Chemical Engineering Science, 1, 1.89% Chemical Engineering Science 1 publication, 1.89%
Journal of Food Composition and Analysis	Journal of Food Composition and Analysis, 1, 1.89% Journal of Food Composition and Analysis 1 publication, 1.89%
Analytica Chimica Acta	Analytica Chimica Acta, 1, 1.89% Analytica Chimica Acta 1 publication, 1.89%
Nanotechnology	Nanotechnology, 1, 1.89% Nanotechnology 1 publication, 1.89%
TrAC - Trends in Analytical Chemistry	TrAC - Trends in Analytical Chemistry, 1, 1.89% TrAC - Trends in Analytical Chemistry 1 publication, 1.89%
Separation and Purification Technology	Separation and Purification Technology, 1, 1.89% Separation and Purification Technology 1 publication, 1.89%
International Journal of Environmental Science and Technology	International Journal of Environmental Science and Technology, 1, 1.89% International Journal of Environmental Science and Technology 1 publication, 1.89%
Analytical Chemistry	Analytical Chemistry, 1, 1.89% Analytical Chemistry 1 publication, 1.89%
IOP Conference Series: Earth and Environmental Science	IOP Conference Series: Earth and Environmental Science, 1, 1.89% IOP Conference Series: Earth and Environmental Science 1 publication, 1.89%
ACS ES&T Water	ACS ES&T Water, 1, 1.89% ACS ES&T Water 1 publication, 1.89%
RSC Advances	RSC Advances, 1, 1.89% RSC Advances 1 publication, 1.89%
Analytical Methods	Analytical Methods, 1, 1.89% Analytical Methods 1 publication, 1.89%
New Journal of Chemistry	New Journal of Chemistry, 1, 1.89% New Journal of Chemistry 1 publication, 1.89%
Journal of Analytical Atomic Spectrometry	Journal of Analytical Atomic Spectrometry, 1, 1.89% Journal of Analytical Atomic Spectrometry 1 publication, 1.89%
International Journal of Environmental Analytical Chemistry	International Journal of Environmental Analytical Chemistry, 1, 1.89% International Journal of Environmental Analytical Chemistry 1 publication, 1.89%
	1 2 3

Citations by publishers

	5 10 15 20
Elsevier	Elsevier, 20, 37.74% Elsevier 20 publications, 37.74%
Springer Nature	Springer Nature, 8, 15.09% Springer Nature 8 publications, 15.09%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 6, 11.32% Royal Society of Chemistry (RSC) 6 publications, 11.32%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 5, 9.43% Multidisciplinary Digital Publishing Institute (MDPI) 5 publications, 9.43%
Pleiades Publishing	Pleiades Publishing, 3, 5.66% Pleiades Publishing 3 publications, 5.66%
Taylor & Francis	Taylor & Francis, 3, 5.66% Taylor & Francis 3 publications, 5.66%
IOP Publishing	IOP Publishing, 2, 3.77% IOP Publishing 2 publications, 3.77%
American Chemical Society (ACS)	American Chemical Society (ACS), 2, 3.77% American Chemical Society (ACS) 2 publications, 3.77%
Wiley	Wiley, 2, 3.77% Wiley 2 publications, 3.77%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.89% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.89%
	5 10 15 20

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023,2024],"ids":[0,0,0,0],"codes":[0,0,0,0],"imageUrls":["","","",""],"datasets":[{"label":"Citations number","data":[15,13,18,7],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["28.3","24.53","33.96","13.21"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Analytical Chemistry","Talanta","Microchemical Journal","Foods","Food Chemistry","Russian Chemical Reviews","Molecules","International Journal of Molecular Sciences","Nanotechnology for Environmental Engineering","Ionics","Journal of Applied Electrochemistry","Journal of Applied Spectroscopy","Sensors","Journal of Cleaner Production","Chemical Engineering Science","Journal of Food Composition and Analysis","Analytica Chimica Acta","Nanotechnology","TrAC - Trends in Analytical Chemistry","Separation and Purification Technology","International Journal of Environmental Science and Technology","Analytical Chemistry","IOP Conference Series: Earth and Environmental Science","ACS ES&T Water","RSC Advances","Analytical Methods","New Journal of Chemistry","Journal of Analytical Atomic Spectrometry","International Journal of Environmental Analytical Chemistry"],"ids":[21398,4331,15101,11536,20876,23802,1770,14627,1984,12191,12525,21731,18435,1744,15716,7328,19094,16187,434,21492,14886,18157,6042,27543,3100,15295,1404,22157,1754],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp"],"datasets":[{"label":"","data":[3,3,3,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[5.66,5.66,5.66,3.77,3.77,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89,1.89],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Springer Nature","Royal Society of Chemistry (RSC)","Multidisciplinary Digital Publishing Institute (MDPI)","Pleiades Publishing","Taylor & Francis","IOP Publishing","American Chemical Society (ACS)","Wiley","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[17,8,123,202,101,18,2075,40,11,9422],"codes":[0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[20,8,6,5,3,3,2,2,2,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[37.74,15.09,11.32,9.43,5.66,5.66,3.77,3.77,3.77,1.89],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Metrics

Cite this

GOST |

Cite this

GOST Copy

Smirnova S. V., Ilin D., Pletnev I. V. Extraction and ICP-OES determination of heavy metals using tetrabutylammonium bromide aqueous biphasic system and oleophilic collector // Talanta. 2021. Vol. 221. p. 121485.

GOST all authors (up to 50) Copy

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.talanta.2020.121485

UR - https://doi.org/10.1016%2Fj.talanta.2020.121485

TI - Extraction and ICP-OES determination of heavy metals using tetrabutylammonium bromide aqueous biphasic system and oleophilic collector

T2 - Talanta

AU - Smirnova, Svetlana V

AU - Ilin, Dmitry

AU - Pletnev, Igor V

PY - 2021

DA - 2021/01/01 00:00:00

PB - Elsevier

SP - 121485

VL - 221

SN - 0039-9140

SN - 1873-3573

ER -

BibTex

Cite this

BibTex Copy

@article{2021_Smirnova,

author = {Svetlana V Smirnova and Dmitry Ilin and Igor V Pletnev},

title = {Extraction and ICP-OES determination of heavy metals using tetrabutylammonium bromide aqueous biphasic system and oleophilic collector},

journal = {Talanta},

year = {2021},

volume = {221},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016%2Fj.talanta.2020.121485},

pages = {121485},

doi = {10.1016/j.talanta.2020.121485}

}

Found error?

Publisher

Elsevier

Journal

Talanta

Quartile SCImago

Quartile WOS

Impact factor

6.1

ISSN

00399140 (Print)
18733573 (Electronic)

Labs

Concentration Laboratory

Profiles