Chemistry - A European Journal, volume 25, issue 16, pages 4225-4233
Assembly of Tetrazolylfuroxan Organic Salts: Multipurpose Green Energetic Materials with High Enthalpies of Formation and Excellent Detonation Performance
Muravyev Nikita
2
,
Pivkina Alla
2
,
Suponitsky Kyrill Yu.
3, 4
,
Ananyev Ivan V
3
,
Khakimov Dmitry
1, 5
,
Makhova Nina N.
1
Publication type: Journal Article
Publication date: 2019-02-19
Journal:
Chemistry - A European Journal
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.3
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
A series of highly energetic organic salts comprising a tetrazolylfuroxan anion, explosophoric azido or azo functionalities, and nitrogen-rich cations were synthesized by simple, efficient, and scalable chemical routes. These energetic materials were fully characterized by IR and multinuclear NMR (1 H, 13 C, 14 N, 15 N) spectroscopy, elemental analysis, and differential scanning calorimetry (DSC). Additionally, the structure of an energetic salt consisting of an azidotetrazolylfuroxan anion and a 3,6,7-triamino-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazolium cation was confirmed by single-crystal X-ray diffraction. The synthesized compounds exhibit good experimental densities (1.57-1.71 g cm-3 ), very high enthalpies of formation (818-1363 kJ mol-1 ), and, as a result, excellent detonation performance (detonation velocities 7.54-8.26 kms-1 and detonation pressures 23.4-29.3 GPa). Most of the synthesized energetic salts have moderate sensitivity toward impact and friction, which makes them promising candidates for a variety of energetic applications. At the same time, three compounds have impact sensitivity on the primary explosives level (1.5-2.7 J). These results along with high detonation parameters and high nitrogen contents (66.0-70.2 %) indicate that these three compounds may serve as potential environmentally friendly alternatives to lead-based primary explosives.
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5
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Citations by publishers
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2
4
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10
12
14
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Wiley
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13 publications, 22.41%
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Elsevier
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10 publications, 17.24%
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American Chemical Society (ACS)
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7 publications, 12.07%
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Springer Nature
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6 publications, 10.34%
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5 publications, 8.62%
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2 publications, 3.45%
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1 publication, 1.72%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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1 publication, 1.72%
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Society of Synthetic Organic Chemistry
|
Society of Synthetic Organic Chemistry
1 publication, 1.72%
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2
4
6
8
10
12
14
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Larin A. A. et al. Assembly of Tetrazolylfuroxan Organic Salts: Multipurpose Green Energetic Materials with High Enthalpies of Formation and Excellent Detonation Performance // Chemistry - A European Journal. 2019. Vol. 25. No. 16. pp. 4225-4233.
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Larin A. A., Muravyev N., Pivkina A., Suponitsky K. Y., Ananyev I. V., Khakimov D., Fershtat L. L., Makhova N. N. Assembly of Tetrazolylfuroxan Organic Salts: Multipurpose Green Energetic Materials with High Enthalpies of Formation and Excellent Detonation Performance // Chemistry - A European Journal. 2019. Vol. 25. No. 16. pp. 4225-4233.
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TY - JOUR
DO - 10.1002/chem.201806378
UR - https://doi.org/10.1002%2Fchem.201806378
TI - Assembly of Tetrazolylfuroxan Organic Salts: Multipurpose Green Energetic Materials with High Enthalpies of Formation and Excellent Detonation Performance
T2 - Chemistry - A European Journal
AU - Muravyev, Nikita
AU - Pivkina, Alla
AU - Suponitsky, Kyrill Yu.
AU - Ananyev, Ivan V
AU - Fershtat, Leonid L.
AU - Makhova, Nina N.
AU - Larin, Alexander A
AU - Khakimov, Dmitry
PY - 2019
DA - 2019/02/19 00:00:00
PB - Wiley
SP - 4225-4233
IS - 16
VL - 25
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2019_Larin,
author = {Nikita Muravyev and Alla Pivkina and Kyrill Yu. Suponitsky and Ivan V Ananyev and Leonid L. Fershtat and Nina N. Makhova and Alexander A Larin and Dmitry Khakimov},
title = {Assembly of Tetrazolylfuroxan Organic Salts: Multipurpose Green Energetic Materials with High Enthalpies of Formation and Excellent Detonation Performance},
journal = {Chemistry - A European Journal},
year = {2019},
volume = {25},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002%2Fchem.201806378},
number = {16},
pages = {4225--4233},
doi = {10.1002/chem.201806378}
}
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MLA
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Larin, Alexander A., et al. “Assembly of Tetrazolylfuroxan Organic Salts: Multipurpose Green Energetic Materials with High Enthalpies of Formation and Excellent Detonation Performance.” Chemistry - A European Journal, vol. 25, no. 16, Feb. 2019, pp. 4225-4233. https://doi.org/10.1002%2Fchem.201806378.