Journal of Radioanalytical and Nuclear Chemistry, volume 107, issue 2, pages 81-93

Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices

Publication typeJournal Article
Publication date1986-11-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor1.6
ISSN02365731, 15882780
Spectroscopy
Analytical Chemistry
Health, Toxicology and Mutagenesis
Public Health, Environmental and Occupational Health
Pollution
Radiology Nuclear Medicine and imaging
Nuclear Energy and Engineering
Abstract
ESR spectra of γ-irradiated, at 77 K, acetone and CH3COEt solutions /0.1–22%/ in CFCl3 were studied. The yields of monomer and dimer radical cations of ketones and RCHCOCH3 radicals depend on ketone concentration in CFCl3. When exposed to light the dimeric radical cations are transformed into RCHCOMe, while the monomeric radical cations disappear without further radical production. Different types of solid phase ion-molecular reaction for monomer and dimer radical cations are discussed.

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Belevsky V. N., Belopushkin S. I., Feldman V. I. Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices // Journal of Radioanalytical and Nuclear Chemistry. 1986. Vol. 107. No. 2. pp. 81-93.
GOST all authors (up to 50) Copy
Belevsky V. N., Belopushkin S. I., Feldman V. I. Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices // Journal of Radioanalytical and Nuclear Chemistry. 1986. Vol. 107. No. 2. pp. 81-93.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/BF02163444
UR - https://doi.org/10.1007%2FBF02163444
TI - Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Belevsky, V N
AU - Belopushkin, S I
AU - Feldman, V I
PY - 1986
DA - 1986/11/01 00:00:00
PB - Springer Nature
SP - 81-93
IS - 2
VL - 107
SN - 0236-5731
SN - 1588-2780
ER -
BibTex |
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BibTex Copy
@article{1986_Belevsky
author = {V N Belevsky and S I Belopushkin and V I Feldman},
title = {Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {1986},
volume = {107},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007%2FBF02163444},
number = {2},
pages = {81--93},
doi = {10.1007/BF02163444}
}
MLA
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MLA Copy
Belevsky, V. N., et al. “Formation and reactions of monomeric and dimeric radical cations of aliphatic ketones in freon matrices.” Journal of Radioanalytical and Nuclear Chemistry, vol. 107, no. 2, Nov. 1986, pp. 81-93. https://doi.org/10.1007%2FBF02163444.
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