Journal of Radioanalytical and Nuclear Chemistry, volume 96, issue 2, pages 137-151

Reactions of the radical cations of aliphatic aldehydes in freon matrices

Publication typeJournal Article
Publication date1985-10-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor1.6
ISSN02365731, 15882780
Spectroscopy
Analytical Chemistry
Health, Toxicology and Mutagenesis
Public Health, Environmental and Occupational Health
Pollution
Radiology Nuclear Medicine and imaging
Nuclear Energy and Engineering
Abstract
ESR spectra of γ-irradiated, at −196 °C, solutions of acetic and propionic aldehydes in freon-11 and freon-113 affected by aldehyde concentration, temperature, and the action of light have been studied. It has been shown that the radical cations CH3CHO+ are converted into neutral radicals CH3ĊO and CH3ĊHOH and the cations CH3CH2CHO+. are converted to RĊO and CH3ĊHCHO due to ion-molecular reactions of proton transfer /CH3ĊO and CH3ĊHCHO/ of hydrogen atom transfer /CH3ĊHOH/.

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Belevskii V. N., Belopushkin S. I., Feldman V. I. Reactions of the radical cations of aliphatic aldehydes in freon matrices // Journal of Radioanalytical and Nuclear Chemistry. 1985. Vol. 96. No. 2. pp. 137-151.
GOST all authors (up to 50) Copy
Belevskii V. N., Belopushkin S. I., Feldman V. I. Reactions of the radical cations of aliphatic aldehydes in freon matrices // Journal of Radioanalytical and Nuclear Chemistry. 1985. Vol. 96. No. 2. pp. 137-151.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/BF02163080
UR - https://doi.org/10.1007%2FBF02163080
TI - Reactions of the radical cations of aliphatic aldehydes in freon matrices
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Belevskii, V N
AU - Belopushkin, S I
AU - Feldman, V I
PY - 1985
DA - 1985/10/01 00:00:00
PB - Springer Nature
SP - 137-151
IS - 2
VL - 96
SN - 0236-5731
SN - 1588-2780
ER -
BibTex |
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BibTex Copy
@article{1985_Belevskii,
author = {V N Belevskii and S I Belopushkin and V I Feldman},
title = {Reactions of the radical cations of aliphatic aldehydes in freon matrices},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {1985},
volume = {96},
publisher = {Springer Nature},
month = {oct},
url = {https://doi.org/10.1007%2FBF02163080},
number = {2},
pages = {137--151},
doi = {10.1007/BF02163080}
}
MLA
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MLA Copy
Belevskii, V. N., et al. “Reactions of the radical cations of aliphatic aldehydes in freon matrices.” Journal of Radioanalytical and Nuclear Chemistry, vol. 96, no. 2, Oct. 1985, pp. 137-151. https://doi.org/10.1007%2FBF02163080.
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