Chemical Physics Letters, volume 437, issue 4-6, pages 207-211
Reactions of H atoms produced by electron irradiation of benzene in solid xenon: IR spectrum of cylohexadienyl radical and possible involvement of HXeC6 H5
Publication type: Journal Article
Publication date: 2007-04-01
Journal:
Chemical Physics Letters
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 00092614
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Abstract Chemical reactions induced by fast electron irradiation of benzene in solid xenon were studied by EPR and FTIR spectroscopy. Irradiation at 16 K leads to H atoms and phenyl radicals. Annealing at 45 K results in formation of HXeH and cyclohexadienyl radical ( C 6 H 7 ). A strong IR absorption at 618/620 cm −1 and several weaker bands were assigned to cyclohexadienyl radical from comparison with EPR data and DFT calculations. A computationally stable molecule HXeC 6 H 5 was not found experimentally, which means that it is either not formed or not stabilized under the experimental conditions used.
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- We do not take into account publications that without a DOI.
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- Statistics recalculated weekly.
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Feldman V. I. et al. Reactions of H atoms produced by electron irradiation of benzene in solid xenon: IR spectrum of cylohexadienyl radical and possible involvement of HXeC6H5 // Chemical Physics Letters. 2007. Vol. 437. No. 4-6. pp. 207-211.
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Feldman V. I., Sukhov F. F., Logacheva E. A., Orlov A. Yu., Tyulpina I. V., Tyurin D. A. Reactions of H atoms produced by electron irradiation of benzene in solid xenon: IR spectrum of cylohexadienyl radical and possible involvement of HXeC6H5 // Chemical Physics Letters. 2007. Vol. 437. No. 4-6. pp. 207-211.
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TY - JOUR
DO - 10.1016/j.cplett.2007.02.039
UR - https://doi.org/10.1016%2Fj.cplett.2007.02.039
TI - Reactions of H atoms produced by electron irradiation of benzene in solid xenon: IR spectrum of cylohexadienyl radical and possible involvement of HXeC6H5
T2 - Chemical Physics Letters
AU - Feldman, Vladimir I.
AU - Sukhov, Fedor F
AU - Logacheva, Elizaveta A
AU - Orlov, Aleksei Yu
AU - Tyulpina, Irina V
AU - Tyurin, Daniil A
PY - 2007
DA - 2007/04/01 00:00:00
PB - Elsevier
SP - 207-211
IS - 4-6
VL - 437
SN - 0009-2614
ER -
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@article{2007_Feldman,
author = {Vladimir I. Feldman and Fedor F Sukhov and Elizaveta A Logacheva and Aleksei Yu Orlov and Irina V Tyulpina and Daniil A Tyurin},
title = {Reactions of H atoms produced by electron irradiation of benzene in solid xenon: IR spectrum of cylohexadienyl radical and possible involvement of HXeC6H5},
journal = {Chemical Physics Letters},
year = {2007},
volume = {437},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016%2Fj.cplett.2007.02.039},
number = {4-6},
pages = {207--211},
doi = {10.1016/j.cplett.2007.02.039}
}
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Feldman, Vladimir I., et al. “Reactions of H atoms produced by electron irradiation of benzene in solid xenon: IR spectrum of cylohexadienyl radical and possible involvement of HXeC6H5.” Chemical Physics Letters, vol. 437, no. 4-6, Apr. 2007, pp. 207-211. https://doi.org/10.1016%2Fj.cplett.2007.02.039.