Polyhedron, volume 200, pages 115149
Design and synthesis of novel terpyridine-based ligands with one and two terminal aurophilic moieties and their Rh(III) and Ru(II) complexes for the adsorption on metal surfaces
Publication type: Journal Article
Publication date: 2021-05-01
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Novel terpyridine ligands with one and two terminal aurophilic sulfur containing fragments based on lipoic acid and their mononuclear ruthenium(II) and rhodium(III) complexes were synthesized. • Novel terpyridine ligands with one and two terminal aurophilic sulfur containing fragments were synthesized. • Mononuclear ruthenium(II) and rhodium(III) complex of these ligands were obtained. Complexes with 3,4- and 3,5-position of sulfur-containing substituents adsorb faster on the Au surface than 2,4-substituted analogs. Novel terpyridine ligands with one and two terminal aurophilic sulfur containing fragments, (S)-11-(4-([2,2′:6′,2″-terpyridin]-4′-yl)phenoxy)undecyl 5-(1,2-dithiolan-3-yl)pentanoate ( 7 ), (S)-((4-([2,2′:6′,2″-terpyridin]-4′-yl)-1,3-phenylene)bis(oxy))bis(undecane-11,1-diyl) bis(5-((S)-1,2-dithiolan-3-yl)pentanoate) ( 11a ), (S)-((4-([2,2′:6′,2″-terpyridin]-4′-yl)-1,2-phenylene)bis(oxy))bis(undecane-11,1-diyl) bis(5-((S)-1,2-dithiolan-3-yl)pentanoate) ( 11b ), (S)-((5-([2,2′:6′,2″-terpyridin]-4′-yl)-1,3-phenylene)bis(oxy))bis(undecane-11,1-diyl) bis(5-((S)-1,2-dithiolan-3-yl)pentanoate) ( 11c ) were synthesized and employed to synthesis of mononuclear ruthenium(II) and rhodium(III) complexes. Electrochemical studies of the obtained ligands and coordination compounds and their ability to chemisorb on gold electrodes surfaces have been carried out. Among the obtained metal complexes, compounds with the minimum time of chemisorption with the formation of Au-S bonds were revealed, which are complexes of 3,4- and 3,5-substituted phenylterpyridines.
Citations by journals
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Russian Chemical Bulletin
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Russian Chemical Bulletin
1 publication, 25%
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Polyhedron
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Polyhedron
1 publication, 25%
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Russian Journal of Organic Chemistry
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Russian Journal of Organic Chemistry
1 publication, 25%
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Russian Journal of General Chemistry
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Russian Journal of General Chemistry
1 publication, 25%
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Pleiades Publishing
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Pleiades Publishing
2 publications, 50%
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Springer Nature
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Springer Nature
1 publication, 25%
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Elsevier
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Elsevier
1 publication, 25%
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Salimova I. O. et al. Design and synthesis of novel terpyridine-based ligands with one and two terminal aurophilic moieties and their Rh(III) and Ru(II) complexes for the adsorption on metal surfaces // Polyhedron. 2021. Vol. 200. p. 115149.
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Salimova I. O., Berezina A. V., Shikholina I. A., Zyk N. V., Beloglazkina E. K. Design and synthesis of novel terpyridine-based ligands with one and two terminal aurophilic moieties and their Rh(III) and Ru(II) complexes for the adsorption on metal surfaces // Polyhedron. 2021. Vol. 200. p. 115149.
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TY - JOUR
DO - 10.1016/j.poly.2021.115149
UR - https://doi.org/10.1016%2Fj.poly.2021.115149
TI - Design and synthesis of novel terpyridine-based ligands with one and two terminal aurophilic moieties and their Rh(III) and Ru(II) complexes for the adsorption on metal surfaces
T2 - Polyhedron
AU - Salimova, Irina O
AU - Berezina, Anna V
AU - Shikholina, Ilona A
AU - Zyk, Nikolai V.
AU - Beloglazkina, Elena K.
PY - 2021
DA - 2021/05/01 00:00:00
PB - Elsevier
SP - 115149
VL - 200
SN - 0277-5387
ER -
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@article{2021_Salimova,
author = {Irina O Salimova and Anna V Berezina and Ilona A Shikholina and Nikolai V. Zyk and Elena K. Beloglazkina},
title = {Design and synthesis of novel terpyridine-based ligands with one and two terminal aurophilic moieties and their Rh(III) and Ru(II) complexes for the adsorption on metal surfaces},
journal = {Polyhedron},
year = {2021},
volume = {200},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016%2Fj.poly.2021.115149},
pages = {115149},
doi = {10.1016/j.poly.2021.115149}
}
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