Journal of Organometallic Chemistry, volume 696, issue 2, pages 468-472
Alkynylation of ferrocene by terminal alkynes. Part I. A simple one-step synthesis of ferrocenylacetylenes
Publication type: Journal Article
Publication date: 2011-01-01
Journal:
Journal of Organometallic Chemistry
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor: 2.3
ISSN: 0022328X
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Ferrocene reacts with terminal alkynes in the presence of copper and iron salts to give 1-ferrocenyl-2-R-alkynes (R – substituent). This direct cross-coupling of ferrocenyl and alkynyl moieties allows for the preparation of ferrocenyl substituted alkynes in one step directly from ferrocene and a terminal alkyne avoiding prior preparation of other derivatives of ferrocene. This new synthetic reaction does not require special conditions, is promoted by the action of common iron and copper salts, and tolerates the presence of functional groups in the alkyne. Ferrocene reacts with terminal alkynes ( I ) in the presence of copper and iron salts to give 1-ferrocenyl substituted acetylenes ( II ) characterized by NMR and LDI studies. The reaction tolerates the presence of functional groups in alkyne and can be named a “direct alkynylation of ferrocene”. ► Ferrocene reacts with terminal alkynes in the presence of copper and iron salts. ► The reaction gives 1-ferrocenyl substituted acetylenes. ► The presence of functional groups in alkyne is tolerated. ► This reaction can be named a “direct alkynylation of ferrocene”.
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1 publication, 7.14%
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Citations by publishers
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6
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6 publications, 42.86%
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Elsevier
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1 publication, 7.14%
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1 publication, 7.14%
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American Chemical Society (ACS)
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1 publication, 7.14%
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1 publication, 7.14%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Dyadchenko V. P. et al. Alkynylation of ferrocene by terminal alkynes. Part I. A simple one-step synthesis of ferrocenylacetylenes // Journal of Organometallic Chemistry. 2011. Vol. 696. No. 2. pp. 468-472.
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Dyadchenko V. P., Dyadchenko M. A., Okulov V. N., Lemenovskii D. A. Alkynylation of ferrocene by terminal alkynes. Part I. A simple one-step synthesis of ferrocenylacetylenes // Journal of Organometallic Chemistry. 2011. Vol. 696. No. 2. pp. 468-472.
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TY - JOUR
DO - 10.1016/j.jorganchem.2010.09.039
UR - https://doi.org/10.1016%2Fj.jorganchem.2010.09.039
TI - Alkynylation of ferrocene by terminal alkynes. Part I. A simple one-step synthesis of ferrocenylacetylenes
T2 - Journal of Organometallic Chemistry
AU - Dyadchenko, Victor P.
AU - Dyadchenko, Marina A
AU - Okulov, Vladimir N
AU - Lemenovskii, Dmitri A
PY - 2011
DA - 2011/01/01 00:00:00
PB - Elsevier
SP - 468-472
IS - 2
VL - 696
SN - 0022-328X
ER -
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@article{2011_Dyadchenko,
author = {Victor P. Dyadchenko and Marina A Dyadchenko and Vladimir N Okulov and Dmitri A Lemenovskii},
title = {Alkynylation of ferrocene by terminal alkynes. Part I. A simple one-step synthesis of ferrocenylacetylenes},
journal = {Journal of Organometallic Chemistry},
year = {2011},
volume = {696},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.jorganchem.2010.09.039},
number = {2},
pages = {468--472},
doi = {10.1016/j.jorganchem.2010.09.039}
}
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MLA
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Dyadchenko, Victor P., et al. “Alkynylation of ferrocene by terminal alkynes. Part I. A simple one-step synthesis of ferrocenylacetylenes.” Journal of Organometallic Chemistry, vol. 696, no. 2, Jan. 2011, pp. 468-472. https://doi.org/10.1016%2Fj.jorganchem.2010.09.039.