Journal of Physical Chemistry Letters, volume 11, issue 7, pages 2630-2636

Unravelling the Material Composition Effects on the Gamma Ray Stability of Lead Halide Perovskite Solar Cells: MAPbI3 Breaks the Records

Publication typeJournal Article
Publication date2020-03-17
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.7
ISSN19487185
Physical and Theoretical Chemistry
General Materials Science
Abstract
In this work, we report a comparative study of the gamma ray stability of perovskite solar cells based on a series of perovskite absorbers including MAPbI3 (MA = methylammonium), MAPbBr3, Cs0.15FA0.85PbI3 (FA = formamidinim), Cs0.1MA0.15FA0.75PbI3, CsPbI3, and CsPbBr3. We reveal that the composition of the perovskite material strongly affects the radiation stability of the solar cells. In particular, solar cells based on the MAPbI3 were found to be the most resistant to gamma rays since this perovskite undergoes rapid self-healing due to the special gas-phase chemistry analyzed with ab initio calculations. The fact that the solar cells based on MAPbI3 can withstand 1000 kRad gamma ray dose without any noticeable degradation of the photovoltaic properties) is particularly exciting and shifts the paradigm of research in this field towards designing more dynamic rather than intrinsically robust (e.g. inorganic) materials.

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Boldyreva A. G. et al. Unravelling the Material Composition Effects on the Gamma Ray Stability of Lead Halide Perovskite Solar Cells: MAPbI3 Breaks the Records // Journal of Physical Chemistry Letters. 2020. Vol. 11. No. 7. pp. 2630-2636.
GOST all authors (up to 50) Copy
Boldyreva A. G., ZHIDKOV I. S., Gutsev L. G., Kurmaev E. Z., Ramachandran B. R., Petrov V. G., Stevenson K. J., Aldoshin S. M., Troshin P. A. Unravelling the Material Composition Effects on the Gamma Ray Stability of Lead Halide Perovskite Solar Cells: MAPbI3 Breaks the Records // Journal of Physical Chemistry Letters. 2020. Vol. 11. No. 7. pp. 2630-2636.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.jpclett.0c00581
UR - https://doi.org/10.1021%2Facs.jpclett.0c00581
TI - Unravelling the Material Composition Effects on the Gamma Ray Stability of Lead Halide Perovskite Solar Cells: MAPbI3 Breaks the Records
T2 - Journal of Physical Chemistry Letters
AU - Boldyreva, Aleksandra G
AU - ZHIDKOV, I. S.
AU - Gutsev, Lavrenty G
AU - Ramachandran, B. Ramu
AU - Petrov, Vladimir G
AU - Stevenson, Keith J
AU - Troshin, Pavel A.
AU - Kurmaev, E. Z.
AU - Aldoshin, S. M.
PY - 2020
DA - 2020/03/17 00:00:00
PB - American Chemical Society (ACS)
SP - 2630-2636
IS - 7
VL - 11
SN - 1948-7185
ER -
BibTex |
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BibTex Copy
@article{2020_Boldyreva,
author = {Aleksandra G Boldyreva and I. S. ZHIDKOV and Lavrenty G Gutsev and B. Ramu Ramachandran and Vladimir G Petrov and Keith J Stevenson and Pavel A. Troshin and E. Z. Kurmaev and S. M. Aldoshin},
title = {Unravelling the Material Composition Effects on the Gamma Ray Stability of Lead Halide Perovskite Solar Cells: MAPbI3 Breaks the Records},
journal = {Journal of Physical Chemistry Letters},
year = {2020},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021%2Facs.jpclett.0c00581},
number = {7},
pages = {2630--2636},
doi = {10.1021/acs.jpclett.0c00581}
}
MLA
Cite this
MLA Copy
Boldyreva, Aleksandra G., et al. “Unravelling the Material Composition Effects on the Gamma Ray Stability of Lead Halide Perovskite Solar Cells: MAPbI3 Breaks the Records.” Journal of Physical Chemistry Letters, vol. 11, no. 7, Mar. 2020, pp. 2630-2636. https://doi.org/10.1021%2Facs.jpclett.0c00581.
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