Russian Journal of Inorganic Chemistry, volume 66, issue 2, pages 202-216
NMR Spectroscopy—A Versatile Tool for Studying the Structure and Magnetic Properties of Paramagnetic Lanthanide Complexes in Solutions (Review)
Publication type: Journal Article
Publication date: 2021-02-20
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 2.1
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Abstract Coordination compounds of lanthanides attract increasing attention of researchers due to their unique physical and chemical properties, including interesting optical and magnetic behavior. Fine tuning of properties of functional materials based on them is possible by controlling the structure of complexes. This review describes the approach of applying NMR spectroscopy to solve the challenging problem of identification of paramagnetic lanthanide complexes, as well as to establish a correlation between the structure of the coordination sphere of lanthanide ions and the magnetic characteristics of the complexes. It has been shown how the analysis of lanthanide-induced shifts (LIS) and lanthanide-induced relaxation (LIR) in series of isostructural compounds contributes to the identification of spectral–structural correlations, which, in combination with X-ray diffraction and quantum-chemical data, make it possible not only to establish the structure of the compound in solution, but also to perform a primary assessment of the possibility of using lanthanides complexes as single molecule magnets.
Citations by journals
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Russian Journal of Inorganic Chemistry
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1 publication, 5.88%
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1 publication, 5.88%
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Physica Status Solidi (B): Basic Research
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1 publication, 5.88%
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Citations by publishers
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Pleiades Publishing
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Pleiades Publishing
5 publications, 29.41%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
5 publications, 29.41%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
2 publications, 11.76%
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World Scientific
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2 publications, 11.76%
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Elsevier
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Elsevier
2 publications, 11.76%
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Wiley
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Wiley
1 publication, 5.88%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Gorbunova Y. G. et al. NMR Spectroscopy—A Versatile Tool for Studying the Structure and Magnetic Properties of Paramagnetic Lanthanide Complexes in Solutions (Review) // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 2. pp. 202-216.
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Gorbunova Y. G., Martynov A. G., Birin K. P., Tsivadze A. Y. NMR Spectroscopy—A Versatile Tool for Studying the Structure and Magnetic Properties of Paramagnetic Lanthanide Complexes in Solutions (Review) // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 2. pp. 202-216.
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TY - JOUR
DO - 10.1134/S0036023621020091
UR - https://doi.org/10.1134%2FS0036023621020091
TI - NMR Spectroscopy—A Versatile Tool for Studying the Structure and Magnetic Properties of Paramagnetic Lanthanide Complexes in Solutions (Review)
T2 - Russian Journal of Inorganic Chemistry
AU - Gorbunova, Yu. G.
AU - Martynov, A G
AU - Birin, K P
AU - Tsivadze, A. Yu.
PY - 2021
DA - 2021/02/20 00:00:00
PB - Pleiades Publishing
SP - 202-216
IS - 2
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2021_Gorbunova,
author = {Yu. G. Gorbunova and A G Martynov and K P Birin and A. Yu. Tsivadze},
title = {NMR Spectroscopy—A Versatile Tool for Studying the Structure and Magnetic Properties of Paramagnetic Lanthanide Complexes in Solutions (Review)},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134%2FS0036023621020091},
number = {2},
pages = {202--216},
doi = {10.1134/S0036023621020091}
}
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Gorbunova, Yu. G., et al. “NMR Spectroscopy—A Versatile Tool for Studying the Structure and Magnetic Properties of Paramagnetic Lanthanide Complexes in Solutions (Review).” Russian Journal of Inorganic Chemistry, vol. 66, no. 2, Feb. 2021, pp. 202-216. https://doi.org/10.1134%2FS0036023621020091.