ACS Applied Energy Materials, volume 1, issue 11, pages 5842-5846

Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode

Publication typeJournal Article
Publication date2018-11-02
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor6.4
ISSN25740962
Materials Chemistry
Electrochemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Chemical Engineering (miscellaneous)
Abstract
Sodium (de)intercalation in the Na4MnV(PO4)3 NASICON-type cathode has been studied with operando synchrotron X-ray powder diffraction and galvanostatic cycling up to 3.8 and 4.0 V cutoff voltages. Symmetry reduction from rhombohedral to monoclinic was observed immediately after the start of the electrochemical desodiation, with restoring of the rhombohedral phase at 3.8 V. Cycling within the 2.5–3.8 V potential range proceeds through both solid-solution and two-phase processes. An additional voltage plateau at ∼3.9 V is observed, associated with “unlocking” of the Na1 site in the rhombohedral phase. Reverse insertion of Na+ cations proceeds via the entire solid-solution region. The experimentally observed discharge capacity increases by ≈14% after raising cutoff voltage.

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Zakharkin M. V. et al. Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode // ACS Applied Energy Materials. 2018. Vol. 1. No. 11. pp. 5842-5846.
GOST all authors (up to 50) Copy
Zakharkin M. V., Drozhzhin O. A., Tereshchenko I. V., Chernyshov D. O., Abakumov A. M., Antipov E. V., Stevenson K. J. Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode // ACS Applied Energy Materials. 2018. Vol. 1. No. 11. pp. 5842-5846.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acsaem.8b01269
UR - https://doi.org/10.1021%2Facsaem.8b01269
TI - Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode
T2 - ACS Applied Energy Materials
AU - Tereshchenko, Ivan V.
AU - Zakharkin, Maxim V.
AU - Drozhzhin, Oleg A.
AU - Abakumov, Artem M.
AU - Stevenson, Keith J
AU - Chernyshov, D. O.
AU - Antipov, Evgeny V.
PY - 2018
DA - 2018/11/02 00:00:00
PB - American Chemical Society (ACS)
SP - 5842-5846
IS - 11
VL - 1
SN - 2574-0962
ER -
BibTex |
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BibTex Copy
@article{2018_Zakharkin
author = {Ivan V. Tereshchenko and Maxim V. Zakharkin and Oleg A. Drozhzhin and Artem M. Abakumov and Keith J Stevenson and D. O. Chernyshov and Evgeny V. Antipov},
title = {Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode},
journal = {ACS Applied Energy Materials},
year = {2018},
volume = {1},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021%2Facsaem.8b01269},
number = {11},
pages = {5842--5846},
doi = {10.1021/acsaem.8b01269}
}
MLA
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MLA Copy
Zakharkin, Maxim V., et al. “Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode.” ACS Applied Energy Materials, vol. 1, no. 11, Nov. 2018, pp. 5842-5846. https://doi.org/10.1021%2Facsaem.8b01269.
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