Radiation-induced synthesis of formic acid in the H2O–CO system: A matrix isolation study

Тип документаJournal Article
Дата публикации2020-08-16
Название журналаChemical Physics Letters
ИздательElsevier
КвартильQ2
ISSN00092614
  • Physical and Theoretical Chemistry
  • General Physics and Astronomy
Краткое описание
Abstract X-radiolysis of the noble-gas matrices containing both H2O and CO was investigated at 5 K using infrared spectroscopy. It was found that formic acid molecule (HCOOH) could be produced from the matrix-isolated H2O⋯CO complexes, either directly as a result of irradiation or upon the subsequent annealing activating the trans-HOCO + H reaction. The former way was observed in Kr, while the latter one in Xe matrix. Matrix-specific behavior and possible astrochemical implications are discussed.
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1. Ryazantsev S.V., Zasimov P.V., Feldman V.I. Radiation-induced synthesis of formic acid in the H2O–CO system: A matrix isolation study // Chemical Physics Letters. 2020. Т. 753. С. 137540.
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TY - JOUR

DO - 10.1016/j.cplett.2020.137540

UR - http://dx.doi.org/10.1016/j.cplett.2020.137540

TI - Radiation-induced synthesis of formic acid in the H2O–CO system: A matrix isolation study

T2 - Chemical Physics Letters

AU - Ryazantsev, Sergey V.

AU - Zasimov, Pavel V.

AU - Feldman, Vladimir I.

PY - 2020

DA - 2020/08

PB - Elsevier BV

SP - 137540

VL - 753

SN - 0009-2614

ER -

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@article{2020,

doi = {10.1016/j.cplett.2020.137540},

url = {https://doi.org/10.1016%2Fj.cplett.2020.137540},

year = 2020,

month = {aug},

publisher = {Elsevier {BV}},

volume = {753},

pages = {137540},

author = {Sergey V. Ryazantsev and Pavel V. Zasimov and Vladimir I. Feldman},

title = {Radiation-induced synthesis of formic acid in the H2O{\textendash}{CO} system: A matrix isolation study}

}

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Ryazantsev, Sergey V., Pavel V. Zasimov, и Vladimir I. Feldman. «Radiation-induced synthesis of formic acid in the H2O–CO system: A matrix isolation study». Chemical Physics Letters 753 (2020): 137540. Crossref. Web.