Chemical Physics Letters, volume 753, pages 137540

Radiation-induced synthesis of formic acid in the H2O–CO system: A matrix isolation study

Publication typeJournal Article
Publication date2020-08-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor2.8
ISSN00092614
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Abstract X-radiolysis of the noble-gas matrices containing both H2O and CO was investigated at 5 K using infrared spectroscopy. It was found that formic acid molecule (HCOOH) could be produced from the matrix-isolated H2O⋯CO complexes, either directly as a result of irradiation or upon the subsequent annealing activating the trans-HOCO + H reaction. The former way was observed in Kr, while the latter one in Xe matrix. Matrix-specific behavior and possible astrochemical implications are discussed.

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Ryazantsev S. V. et al. Radiation-induced synthesis of formic acid in the H2O–CO system: A matrix isolation study // Chemical Physics Letters. 2020. Vol. 753. p. 137540.
GOST all authors (up to 50) Copy
Ryazantsev S. V., Zasimov P. V., Feldman V. I. Radiation-induced synthesis of formic acid in the H2O–CO system: A matrix isolation study // Chemical Physics Letters. 2020. Vol. 753. p. 137540.
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RIS Copy
TY - JOUR
DO - 10.1016/j.cplett.2020.137540
UR - https://doi.org/10.1016%2Fj.cplett.2020.137540
TI - Radiation-induced synthesis of formic acid in the H2O–CO system: A matrix isolation study
T2 - Chemical Physics Letters
AU - Ryazantsev, Sergey V
AU - Zasimov, Pavel V
AU - Feldman, Vladimir I.
PY - 2020
DA - 2020/08/01 00:00:00
PB - Elsevier
SP - 137540
VL - 753
SN - 0009-2614
ER -
BibTex
Cite this
BibTex Copy
@article{2020_Ryazantsev,
author = {Sergey V Ryazantsev and Pavel V Zasimov and Vladimir I. Feldman},
title = {Radiation-induced synthesis of formic acid in the H2O–CO system: A matrix isolation study},
journal = {Chemical Physics Letters},
year = {2020},
volume = {753},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016%2Fj.cplett.2020.137540},
pages = {137540},
doi = {10.1016/j.cplett.2020.137540}
}
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