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Molecules, volume 23, issue 6, pages 1257

The Conversion of 5,5-Bi(1,2,3-dithiazolylidenes) into Isothiazolo[5,4-d]isothiazoles

Konstantinova Lidia ^{1, 2}

Baranovsky Ilia ¹

Strunyasheva Vlada ¹

Kalogirou Andreas ^{3, 4}

Popov Vadim ²

Lyssenko Konstantin ⁵

Koutentis Panayiotis ³

Rakitin Oleg ^{1, 2}

Hide authors affiliations Show authors affiliations: 5 affiliations

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia |

Nanotechnology Education and Research Center, South Ural State University, Chelyabinsk 454080, Russia |

Department of Chemistry, University of Cyprus, P.O. Box 20537, Nicosia 1678, Cyprus |

⁴

Department of Life Sciences, School of Sciences, European University Cyprus, 6 Diogenis Str., Engomi, P.O. Box 22006, Nicosia 1516, Cyprus |

⁵

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991, Russia |

Publication type: Journal Article

Publication date: 2018-05-24

Multidisciplinary Digital Publishing Institute (MDPI)

Journal: Molecules

Quartile SCImago

Quartile WOS

Impact factor: 4.6

ISSN: 14203049

DOI: 10.3390/molecules23061257

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PubMed ID: 29795048

Organic Chemistry

Drug Discovery

Physical and Theoretical Chemistry

Pharmaceutical Science

Molecular Medicine

Analytical Chemistry

Chemistry (miscellaneous)

Abstract

Thermolysis of 4,4′-dichloro-, 4,4′-diaryl-, and 4,4′-di(thien-2-yl)-5,5′-bi(1,2,3-dithiazol-ylidenes) affords the respective 3,6-dichloro-, 3,6-diaryl- and 3,6-di(thien-2-yl)isothiazolo[5,4-d]-isothiazoles in low to high yields. The transformation of the 4,4′-diaryl- and 4,4′-di(thien-2-yl)-5,5′-bi(1,2,3-dithiazolylidenes) occurs at lower temperatures in the presence of the thiophiles triphenylphosphine or tetraethylammonium iodide. Optimized reaction conditions and a mechanistic rationale for the thiophile-mediated ring transformation are presented.

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	1
Antibiotics	Antibiotics, 1, 14.29% Antibiotics 1 publication, 14.29%
Asian Journal of Organic Chemistry	Asian Journal of Organic Chemistry, 1, 14.29% Asian Journal of Organic Chemistry 1 publication, 14.29%
Bioorganic and Medicinal Chemistry	Bioorganic and Medicinal Chemistry, 1, 14.29% Bioorganic and Medicinal Chemistry 1 publication, 14.29%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 14.29% Russian Chemical Reviews 1 publication, 14.29%
	1

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	1
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 14.29% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 14.29%
Wiley	Wiley, 1, 14.29% Wiley 1 publication, 14.29%
Elsevier	Elsevier, 1, 14.29% Elsevier 1 publication, 14.29%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 14.29% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 14.29%
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Konstantinova L. et al. The Conversion of 5,5-Bi(1,2,3-dithiazolylidenes) into Isothiazolo[5,4-d]isothiazoles // Molecules. 2018. Vol. 23. No. 6. p. 1257.

GOST all authors (up to 50) Copy

Konstantinova L., Baranovsky I., Strunyasheva V., Kalogirou A., Popov V., Lyssenko K., Koutentis P., Rakitin O. The Conversion of 5,5-Bi(1,2,3-dithiazolylidenes) into Isothiazolo[5,4-d]isothiazoles // Molecules. 2018. Vol. 23. No. 6. p. 1257.

RIS |

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TY - JOUR

DO - 10.3390/molecules23061257

UR - https://doi.org/10.3390%2Fmolecules23061257

TI - The Conversion of 5,5-Bi(1,2,3-dithiazolylidenes) into Isothiazolo[5,4-d]isothiazoles

T2 - Molecules

AU - Konstantinova, Lidia

AU - Baranovsky, Ilia

AU - Strunyasheva, Vlada

AU - Kalogirou, Andreas

AU - Lyssenko, Konstantin

AU - Koutentis, Panayiotis

AU - Rakitin, Oleg

AU - Popov, Vadim

PY - 2018

DA - 2018/05/24 00:00:00

PB - Multidisciplinary Digital Publishing Institute (MDPI)

SP - 1257

IS - 6

VL - 23

PMID - 29795048

SN - 1420-3049

ER -

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@article{2018_Konstantinova,

author = {Lidia Konstantinova and Ilia Baranovsky and Vlada Strunyasheva and Andreas Kalogirou and Konstantin Lyssenko and Panayiotis Koutentis and Oleg Rakitin and Vadim Popov},

title = {The Conversion of 5,5-Bi(1,2,3-dithiazolylidenes) into Isothiazolo[5,4-d]isothiazoles},

journal = {Molecules},

year = {2018},

volume = {23},

publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},

month = {may},

url = {https://doi.org/10.3390%2Fmolecules23061257},

number = {6},

pages = {1257},

doi = {10.3390/molecules23061257}

}

MLA

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Konstantinova, Lidia, et al. “The Conversion of 5,5-Bi(1,2,3-dithiazolylidenes) into Isothiazolo[5,4-d]isothiazoles.” Molecules, vol. 23, no. 6, May. 2018, p. 1257. https://doi.org/10.3390%2Fmolecules23061257.

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Publisher

Multidisciplinary Digital Publishing Institute (MDPI)

Journal

Molecules

Quartile SCImago

Quartile WOS

Impact factor

4.6

ISSN

14203049 (Print)

Labs

Laboratory of Polyserazyrogenous Heterocycles

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