Radiation Physics and Chemistry, volume 110, pages 17-23
Kinetics and mechanism of the radiation-chemical synthesis of krypton hydrides in solid krypton matrices
Publication type: Journal Article
Publication date: 2015-05-01
Journal:
Radiation Physics and Chemistry
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor: 2.9
ISSN: 0969806X
Radiation
Abstract
Abstract The processes occurring in the X-irradiated C2H2/Kr and HCl/Kr systems in the temperature range of 7–30 K were studied using a combination of FTIR and EPR spectroscopy. In both cases, irradiation results in effective decomposition of isolated molecules (C2H2 or HCl) and production of trapped H atoms. The thermal decay of trapped atoms in solid krypton was attributed to “local” reactions (below 21 K) and long-range mobility activated in the temperature range of 23–27 K. Two krypton hydrides, HKrCCH and HKrCl, were synthesized from the radiation-induced hydrogen atoms. In the case of C2H2/Kr system, competitive reaction channels of H atoms at various absorbed doses were investigated in details, and HKrCCH was found to be one of the main reaction products. The X-ray radiolysis in krypton matrices was concluded to be a promising method to obtain krypton hydrides.
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- We do not take into account publications that without a DOI.
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Kameneva S. V., Kobzarenko A. V., Feldman V. I. Kinetics and mechanism of the radiation-chemical synthesis of krypton hydrides in solid krypton matrices // Radiation Physics and Chemistry. 2015. Vol. 110. pp. 17-23.
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Kameneva S. V., Kobzarenko A. V., Feldman V. I. Kinetics and mechanism of the radiation-chemical synthesis of krypton hydrides in solid krypton matrices // Radiation Physics and Chemistry. 2015. Vol. 110. pp. 17-23.
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TY - JOUR
DO - 10.1016/j.radphyschem.2015.01.007
UR - https://doi.org/10.1016%2Fj.radphyschem.2015.01.007
TI - Kinetics and mechanism of the radiation-chemical synthesis of krypton hydrides in solid krypton matrices
T2 - Radiation Physics and Chemistry
AU - Kobzarenko, Alexey V
AU - Kameneva, Svetlana V
AU - Feldman, Vladimir I.
PY - 2015
DA - 2015/05/01 00:00:00
PB - Elsevier
SP - 17-23
VL - 110
SN - 0969-806X
ER -
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@article{2015_Kameneva,
author = {Alexey V Kobzarenko and Svetlana V Kameneva and Vladimir I. Feldman},
title = {Kinetics and mechanism of the radiation-chemical synthesis of krypton hydrides in solid krypton matrices},
journal = {Radiation Physics and Chemistry},
year = {2015},
volume = {110},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016%2Fj.radphyschem.2015.01.007},
pages = {17--23},
doi = {10.1016/j.radphyschem.2015.01.007}
}
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