Radiation Physics and Chemistry, volume 77, issue 4, pages 416-427

Structure and photochemistry of "bridged" bifunctional radical cations: Amidoesters vs. amides

Publication typeJournal Article
Publication date2008-04-01
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor2.9
ISSN0969806X
Radiation
Abstract
Abstract Structure and properties of the radical cations of “bridged” amidoesters (functional groups separated by 0–4 methylene groups and the corresponding dimethyl-substituted amides) were investigated by EPR, optical absorption spectroscopy and DFT calculations. The EPR spectra and thermal reactions of these species are similar. Meanwhile, for amidoesters with 2–4 methylene groups, the methylene “bridge” is involved in photochemistry, which can be explained by specific conformation of amidoester radical cations determined by interaction between the functional groups.

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Nuzhdin K. B. et al. Structure and photochemistry of "bridged" bifunctional radical cations: Amidoesters vs. amides // Radiation Physics and Chemistry. 2008. Vol. 77. No. 4. pp. 416-427.
GOST all authors (up to 50) Copy
Nuzhdin K. B., Feldman V. I., Feldman V. I. Structure and photochemistry of "bridged" bifunctional radical cations: Amidoesters vs. amides // Radiation Physics and Chemistry. 2008. Vol. 77. No. 4. pp. 416-427.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.radphyschem.2007.06.002
UR - https://doi.org/10.1016%2Fj.radphyschem.2007.06.002
TI - Structure and photochemistry of "bridged" bifunctional radical cations: Amidoesters vs. amides
T2 - Radiation Physics and Chemistry
AU - Nuzhdin, Kirill B
AU - Feldman, Vladimir I
AU - Feldman, Vladimir I.
PY - 2008
DA - 2008/04/01 00:00:00
PB - Elsevier
SP - 416-427
IS - 4
VL - 77
SN - 0969-806X
ER -
BibTex |
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BibTex Copy
@article{2008_Nuzhdin
author = {Kirill B Nuzhdin and Vladimir I Feldman and Vladimir I. Feldman},
title = {Structure and photochemistry of "bridged" bifunctional radical cations: Amidoesters vs. amides},
journal = {Radiation Physics and Chemistry},
year = {2008},
volume = {77},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016%2Fj.radphyschem.2007.06.002},
number = {4},
pages = {416--427},
doi = {10.1016/j.radphyschem.2007.06.002}
}
MLA
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MLA Copy
Nuzhdin, Kirill B., et al. “Structure and photochemistry of "bridged" bifunctional radical cations: Amidoesters vs. amides.” Radiation Physics and Chemistry, vol. 77, no. 4, Apr. 2008, pp. 416-427. https://doi.org/10.1016%2Fj.radphyschem.2007.06.002.
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