Physical Chemistry Chemical Physics, volume 2, issue 1, pages 29-35

Effect of matrix and substituent on the electronic structure of trapped benzene radical cations

Feldman Vladimir I. ^{1, 2}

Sukhov Fedor ¹

Orlov Aleksei ²

Kadam Ramakant ³

Itagaki Yoshiteru ³

Lund Anders ³

Hide authors affiliations Show authors affiliations: 3 affiliations

Karpov Institute of Physical Chemistry, Vorontsovo Pole Str. 10, Moscow, Russia |

Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Profsoyuznaya Str. 70, Moscow, Russia |

Department of Physical and Measurement Technology, Linköping University of Technology, Linköping, Sweden |

Publication type: Journal Article

Publication date: 2000-01-01

Royal Society of Chemistry (RSC)

Journal: Physical Chemistry Chemical Physics

Quartile SCImago

Quartile WOS

Impact factor: 3.3

ISSN: 14639076, 14639084

DOI: 10.1039/a906483d

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Physical and Theoretical Chemistry

General Physics and Astronomy

Abstract

The structure and dynamics of the radical cations produced from benzene, monodeuterated benzene and toluene in various low-temperature matrices were characterized by EPR and ENDOR spectroscopy. It was found that the nature of the matrix had a dramatic effect on the EPR spectra of benzene cation. Rigid structures corresponding to the 2B1g and 2B2g states are revealed in solid argon and halocarbon (CFCl3) matrices, respectively, whereas only dynamically averaged patterns are observed in other hosts used (krypton, xenon, sulfur hexafluoride). Deuterium monosubstitution has no appreciable effect on the cation structure observed in argon and halocarbon matrices, which implies matrix control of the preferred electronic state. In contrast, the toluene radical cation exhibits only a 2B2g-like structure both in argon and in CFCl3 matrices, that is, the internal structural effect strongly predominates over environment effects in this case. The results are discussed in qualitative terms taking into consideration the matrix and substituent effects on the charge distribution in benzene cation.

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Citations by journals

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Chemical Physics Letters	Chemical Physics Letters, 1, 3.7% Chemical Physics Letters 1 publication, 3.7%
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Chemical Reviews	Chemical Reviews, 1, 3.7% Chemical Reviews 1 publication, 3.7%
Journal of Chemical Research	Journal of Chemical Research, 1, 3.7% Journal of Chemical Research 1 publication, 3.7%
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Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 3.7% Journal of Physical Chemistry C 1 publication, 3.7%
European Journal of Inorganic Chemistry	European Journal of Inorganic Chemistry, 1, 3.7% European Journal of Inorganic Chemistry 1 publication, 3.7%
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International Journal of Molecular Sciences	International Journal of Molecular Sciences, 1, 3.7% International Journal of Molecular Sciences 1 publication, 3.7%
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Citations by publishers

	1 2 3 4 5 6 7
American Chemical Society (ACS)	American Chemical Society (ACS), 7, 25.93% American Chemical Society (ACS) 7 publications, 25.93%
Elsevier	Elsevier, 4, 14.81% Elsevier 4 publications, 14.81%
Wiley	Wiley, 4, 14.81% Wiley 4 publications, 14.81%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 11.11% Royal Society of Chemistry (RSC) 3 publications, 11.11%
Springer Nature	Springer Nature, 2, 7.41% Springer Nature 2 publications, 7.41%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 3.7% American Institute of Physics (AIP) 1 publication, 3.7%
Pleiades Publishing	Pleiades Publishing, 1, 3.7% Pleiades Publishing 1 publication, 3.7%
SAGE	SAGE, 1, 3.7% SAGE 1 publication, 3.7%
IOP Publishing	IOP Publishing, 1, 3.7% IOP Publishing 1 publication, 3.7%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 3.7% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 3.7%
	1 2 3 4 5 6 7

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Feldman V. I. et al. Effect of matrix and substituent on the electronic structure of trapped benzene radical cations // Physical Chemistry Chemical Physics. 2000. Vol. 2. No. 1. pp. 29-35.

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Feldman V. I., Sukhov F., Orlov A., Kadam R., Itagaki Y., Lund A. Effect of matrix and substituent on the electronic structure of trapped benzene radical cations // Physical Chemistry Chemical Physics. 2000. Vol. 2. No. 1. pp. 29-35.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1039/a906483d

UR - https://doi.org/10.1039%2Fa906483d

TI - Effect of matrix and substituent on the electronic structure of trapped benzene radical cations

T2 - Physical Chemistry Chemical Physics

AU - Sukhov, Fedor

AU - Orlov, Aleksei

AU - Kadam, Ramakant

AU - Itagaki, Yoshiteru

AU - Feldman, Vladimir I.

AU - Lund, Anders

PY - 2000

DA - 2000/01/01 00:00:00

PB - Royal Society of Chemistry (RSC)

SP - 29-35

IS - 1

VL - 2

SN - 1463-9076

SN - 1463-9084

ER -

BibTex |

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@article{2000_Feldman,

author = {Fedor Sukhov and Aleksei Orlov and Ramakant Kadam and Yoshiteru Itagaki and Vladimir I. Feldman and Anders Lund},

title = {Effect of matrix and substituent on the electronic structure of trapped benzene radical cations},

journal = {Physical Chemistry Chemical Physics},

year = {2000},

volume = {2},

publisher = {Royal Society of Chemistry (RSC)},

month = {jan},

url = {https://doi.org/10.1039%2Fa906483d},

number = {1},

pages = {29--35},

doi = {10.1039/a906483d}

}

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Feldman, Vladimir I., et al. “Effect of matrix and substituent on the electronic structure of trapped benzene radical cations.” Physical Chemistry Chemical Physics, vol. 2, no. 1, Jan. 2000, pp. 29-35. https://doi.org/10.1039%2Fa906483d.

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Publisher

Royal Society of Chemistry (RSC)

Journal

Physical Chemistry Chemical Physics

Quartile SCImago

Quartile WOS

Impact factor

3.3

ISSN

14639076 (Print)
14639084 (Electronic)

Labs

Laboratory of High Energy Chemistry

Profiles

Feldman, Vladimir I