ChemSusChem, volume 14, issue 6, pages 1574-1585
The Misconception of Mg2+ Insertion into Prussian Blue Analogue Structures from Aqueous Solution
Komayko Alena I
1, 2
,
Trussov Ivan A
1
,
Arkharova Natalya A
3
,
Presnov Denis E.
4, 5, 6
,
Levin Eduard E.
2, 3
,
Nikitina Victoria A.
1, 2
Publication type: Journal Article
Publication date: 2021-02-10
Journal:
ChemSusChem
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 8.4
ISSN: 18645631, 1864564X
General Chemical Engineering
General Materials Science
General Energy
Environmental Chemistry
Abstract
Prussian Blue analogs (PBA) are commonly believed to reversibly insert divalent ions, such as calcium and magnesium, rendering them as perspective cathode materials for aqueous magnesium-ion batteries. In this work, we show that Mg 2+ insertion into nanosized PBA materials is a misconception and provide conclusive evidence for the unfeasibility of this process for both cation-rich and cation-poor nickel, iron and copper hexacyanoferrates. Based on structural, electrochemical, IR spectroscopy and quartz crystal microbalance data, we deduce the charge compensation of PBA redox by protons rather than by divalent ions in aqueous Mg 2+ solution. The reversible insertion of protons involves complex lattice water rearrangements, while the presence of Mg 2+ ion and Mg salt anion stabilizes the proton (de)insertion reaction due to local pH effects and anion adsorption at the PBA surface. The obtained results draw attention to the design of proton-based batteries operating in environmentally benign aqueous solutions with low acidity.
Citations by journals
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1 publication, 4.76%
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1 publication, 4.76%
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1 publication, 4.76%
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1 publication, 4.76%
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1 publication, 4.76%
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1 publication, 4.76%
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1 publication, 4.76%
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1 publication, 4.76%
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1
2
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Citations by publishers
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1
2
3
4
5
6
7
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Wiley
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Wiley
7 publications, 33.33%
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American Chemical Society (ACS)
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6 publications, 28.57%
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Royal Society of Chemistry (RSC)
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3 publications, 14.29%
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Elsevier
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Elsevier
2 publications, 9.52%
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Springer Nature
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Springer Nature
1 publication, 4.76%
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KeAi Communications Co.
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KeAi Communications Co.
1 publication, 4.76%
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American Association for the Advancement of Science (AAAS)
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American Association for the Advancement of Science (AAAS)
1 publication, 4.76%
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1
2
3
4
5
6
7
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Komayko A. I. et al. The Misconception of Mg2+ Insertion into Prussian Blue Analogue Structures from Aqueous Solution // ChemSusChem. 2021. Vol. 14. No. 6. pp. 1574-1585.
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Komayko A. I., Ryazantsev S. V., Trussov I. A., Arkharova N. A., Presnov D. E., Levin E. E., Nikitina V. A. The Misconception of Mg2+ Insertion into Prussian Blue Analogue Structures from Aqueous Solution // ChemSusChem. 2021. Vol. 14. No. 6. pp. 1574-1585.
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TY - JOUR
DO - 10.1002/cssc.202002916
UR - https://doi.org/10.1002%2Fcssc.202002916
TI - The Misconception of Mg2+ Insertion into Prussian Blue Analogue Structures from Aqueous Solution
T2 - ChemSusChem
AU - Komayko, Alena I
AU - Trussov, Ivan A
AU - Arkharova, Natalya A
AU - Ryazantsev, Sergey V
AU - Presnov, Denis E.
AU - Levin, Eduard E.
AU - Nikitina, Victoria A.
PY - 2021
DA - 2021/02/10 00:00:00
PB - Wiley
SP - 1574-1585
IS - 6
VL - 14
SN - 1864-5631
SN - 1864-564X
ER -
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@article{2021_Komayko,
author = {Alena I Komayko and Ivan A Trussov and Natalya A Arkharova and Sergey V Ryazantsev and Denis E. Presnov and Eduard E. Levin and Victoria A. Nikitina},
title = {The Misconception of Mg2+ Insertion into Prussian Blue Analogue Structures from Aqueous Solution},
journal = {ChemSusChem},
year = {2021},
volume = {14},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002%2Fcssc.202002916},
number = {6},
pages = {1574--1585},
doi = {10.1002/cssc.202002916}
}
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Komayko, Alena I., et al. “The Misconception of Mg2+ Insertion into Prussian Blue Analogue Structures from Aqueous Solution.” ChemSusChem, vol. 14, no. 6, Feb. 2021, pp. 1574-1585. https://doi.org/10.1002%2Fcssc.202002916.