Journal of Solid State Chemistry, volume 286, pages 121294
Anionic substitution in LiMnPO4 : The Li1-x Mn1+x (PO4 )1-y-z (VO4 )y (OH)4z solid solutions prepared with a microwave-assisted hydrothermal method
Publication type: Journal Article
Publication date: 2020-06-01
Journal:
Journal of Solid State Chemistry
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3.3
ISSN: 00224596, 1095726X
Materials Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Inorganic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Abstract
Attempts to introduce vanadium doping into the olivine-structured LiMnPO 4 cathode material for the Li-ion batteries resulted in the ( y + z )PO 4 3− → y VO 4 3− + 4 z OH − ( y < 0.17, z ≤ 0.1) co-substitution and the formation of the hydrotriphylite-type Li 1− x Mn 1+ x (PO 4 ) 1− y−z (VO 4 ) y (OH) 4z solid solutions. Their crystal structure and chemical composition were studied with Rietveld structure refinement from synchrotron X-ray powder diffraction data, energy-dispersive X-ray analysis, infrared and Raman spectroscopy, electron energy loss analysis and mass spectrometry. Li 0.96 Mn 1.04 (PO 4 ) 0.74 (VO 4 ) 0.16 (OH) 0.4 crystallizes in the space group Pnma and a = 10.5150(2) Å, b = 6.11773(9) Å and c = 4.78555(9) Å with up to 5% of Mn in the Li position. Charge compensation is achieved through partial oxidation of the Mn cations to the oxidation state above +2. The heterovalent substitution in anionic sublattice and defectiveness of the cationic one cause blocking of Li-ion diffusion channels that drastically impede the electrochemical performance resulting in electrochemical capacity not exceeding 35 mAh g −1 . • Li 1− x Mn 1+ x (PO 4 ) 1− y−z (VO 4 ) y (OH) 4z solid solutions were prepared by microwave hydrothermal method. • The crystal structure was determined from synchrotron X-ray powder diffraction data. • VO 4 3− and OH − groups simultaneously incorporate into anionic sublattice. • “LiMn(PO 4 ) 1− y (VO 4 ) y “ demonstrate limited electrochemical activity in Li-ion cell.
Citations by journals
|
1
|
|
|
Materials Research Bulletin
|
Materials Research Bulletin
1 publication, 14.29%
|
|
Radiation Physics and Chemistry
|
Radiation Physics and Chemistry
1 publication, 14.29%
|
|
Journal of Solid State Electrochemistry
|
Journal of Solid State Electrochemistry
1 publication, 14.29%
|
|
Journal of Power Sources
|
Journal of Power Sources
1 publication, 14.29%
|
|
Electroanalysis
|
Electroanalysis
1 publication, 14.29%
|
|
Energy Storage Materials
|
Energy Storage Materials
1 publication, 14.29%
|
|
1
|
Citations by publishers
|
1
2
3
4
|
|
|
Elsevier
|
Elsevier
4 publications, 57.14%
|
|
Springer Nature
|
Springer Nature
1 publication, 14.29%
|
|
Wiley
|
Wiley
1 publication, 14.29%
|
|
1
2
3
4
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2020,2021,2022,2023,2024],"ids":[0,0,0,0,0],"codes":[0,0,0,0,0],"imageUrls":["","","","",""],"datasets":[{"label":"Citations number","data":[1,0,2,3,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["14.29",0,"28.57","42.86","14.29"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Materials Research Bulletin","Radiation Physics and Chemistry","Journal of Solid State Electrochemistry","Journal of Power Sources","Electroanalysis","Energy Storage Materials"],"ids":[9849,14769,10804,14844,11049,3858],"codes":[0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp"],"datasets":[{"label":"","data":[1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[14.29,14.29,14.29,14.29,14.29,14.29],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Springer Nature","Wiley"],"ids":[17,8,11],"codes":[0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[4,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":[57.14,14.29,14.29],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Kirsanova M. A., Ryazantsev S., Abakumov A. M. Anionic substitution in LiMnPO4: The Li1-xMn1+x(PO4)1-y-z(VO4)y(OH)4z solid solutions prepared with a microwave-assisted hydrothermal method // Journal of Solid State Chemistry. 2020. Vol. 286. p. 121294.
GOST all authors (up to 50)
Copy
Kirsanova M. A., Ryazantsev S., Abakumov A. M. Anionic substitution in LiMnPO4: The Li1-xMn1+x(PO4)1-y-z(VO4)y(OH)4z solid solutions prepared with a microwave-assisted hydrothermal method // Journal of Solid State Chemistry. 2020. Vol. 286. p. 121294.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.jssc.2020.121294
UR - https://doi.org/10.1016%2Fj.jssc.2020.121294
TI - Anionic substitution in LiMnPO4: The Li1-xMn1+x(PO4)1-y-z(VO4)y(OH)4z solid solutions prepared with a microwave-assisted hydrothermal method
T2 - Journal of Solid State Chemistry
AU - Kirsanova, Maria A
AU - Ryazantsev, Sergey
AU - Abakumov, Artem M.
PY - 2020
DA - 2020/06/01 00:00:00
PB - Elsevier
SP - 121294
VL - 286
SN - 0022-4596
SN - 1095-726X
ER -
Cite this
BibTex
Copy
@article{2020_Kirsanova,
author = {Maria A Kirsanova and Sergey Ryazantsev and Artem M. Abakumov},
title = {Anionic substitution in LiMnPO4: The Li1-xMn1+x(PO4)1-y-z(VO4)y(OH)4z solid solutions prepared with a microwave-assisted hydrothermal method},
journal = {Journal of Solid State Chemistry},
year = {2020},
volume = {286},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016%2Fj.jssc.2020.121294},
pages = {121294},
doi = {10.1016/j.jssc.2020.121294}
}
Profiles