Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes

Zezina E.A., Emel’yanov A.I., Pozdnyakov A.S., Prozorova G.F., Abramchuk S.S., Feldman V.I., Zezin A.A.
Тип документаJournal Article
Дата публикации2019-05-01
Название журналаRadiation Physics and Chemistry
Издатель
  • Radiation
Краткое описание
Abstract The composites with localization of copper nanoparticles on the surface of interpolymer films were prepared by X-ray irradiation of poly(1-vinyl-1,2,4-triazole) – poly(acrylic acid) – Cu2+ complexes. The kinetics of radiation-chemical reduction of ions Cu2+ in films of stoichiometric and nonstoichiometric complexes of poly(1-vinyl-1,2,4-triazole) – poly(acrylic acid) (PVT – PAA) was studied by EPR. The use of transmission electron microscopy with micro-diffraction mode showed that the preparation of metal nanoparticles occurs through the intermediate formation of copper protoxide. The efficiency of nanoparticle formation is determined by the ratio PVT/PAA in interpolymer films. The contrast of X-ray absorption by water-alcohol medium and interpolymer complexes with copper ions provides the favorable conditions for the formation of metal nanostructures in the near-surface layer of the films.
Пристатейные ссылки: 26
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1. Zezina E.A. и др. Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes // Radiation Physics and Chemistry. 2019. Т. 158. С. 115–121.
RIS |
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TY - JOUR

DO - 10.1016/j.radphyschem.2019.01.019

UR - http://dx.doi.org/10.1016/j.radphyschem.2019.01.019

TI - Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes

T2 - Radiation Physics and Chemistry

AU - Zezina, Elena A.

AU - Emel’yanov, Artem I.

AU - Pozdnyakov, Alexander S.

AU - Prozorova, Galina F.

AU - Abramchuk, Sergei S.

AU - Feldman, Vladimir I.

AU - Zezin, Alexey A.

PY - 2019

DA - 2019/05

PB - Elsevier BV

SP - 115-121

VL - 158

SN - 0969-806X

ER -

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@article{2019,

doi = {10.1016/j.radphyschem.2019.01.019},

url = {https://doi.org/10.1016%2Fj.radphyschem.2019.01.019},

year = 2019,

month = {may},

publisher = {Elsevier {BV}},

volume = {158},

pages = {115--121},

author = {Elena A. Zezina and Artem I. Emel'yanov and Alexander S. Pozdnyakov and Galina F. Prozorova and Sergei S. Abramchuk and Vladimir I. Feldman and Alexey A. Zezin},

title = {Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes}

}

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Zezina, Elena A. et al. “Radiation-Induced Synthesis of Copper Nanostructures in the Films of Interpolymer Complexes.” Radiation Physics and Chemistry 158 (2019): 115–121. Crossref. Web.