Radiation Physics and Chemistry, volume 158, pages 115-121

Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes

Publication typeJournal Article
Publication date2019-05-01
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor2.9
ISSN0969806X
Radiation
Abstract
Abstract The composites with localization of copper nanoparticles on the surface of interpolymer films were prepared by X-ray irradiation of poly(1-vinyl-1,2,4-triazole) – poly(acrylic acid) – Cu2+ complexes. The kinetics of radiation-chemical reduction of ions Cu2+ in films of stoichiometric and nonstoichiometric complexes of poly(1-vinyl-1,2,4-triazole) – poly(acrylic acid) (PVT – PAA) was studied by EPR. The use of transmission electron microscopy with micro-diffraction mode showed that the preparation of metal nanoparticles occurs through the intermediate formation of copper protoxide. The efficiency of nanoparticle formation is determined by the ratio PVT/PAA in interpolymer films. The contrast of X-ray absorption by water-alcohol medium and interpolymer complexes with copper ions provides the favorable conditions for the formation of metal nanostructures in the near-surface layer of the films.

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Zezina E. et al. Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes // Radiation Physics and Chemistry. 2019. Vol. 158. pp. 115-121.
GOST all authors (up to 50) Copy
Zezina E., Emel’yanov A. M., Pozdnyakov A. S., Prozorova G. F., Abramchuk S. S., Feldman V. I., Zezin A. Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes // Radiation Physics and Chemistry. 2019. Vol. 158. pp. 115-121.
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TY - JOUR
DO - 10.1016/j.radphyschem.2019.01.019
UR - https://doi.org/10.1016%2Fj.radphyschem.2019.01.019
TI - Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes
T2 - Radiation Physics and Chemistry
AU - Zezina, Elena
AU - Emel’yanov, Artem M.
AU - Pozdnyakov, Alexander S.
AU - Prozorova, Galina F
AU - Abramchuk, Sergei S
AU - Feldman, Vladimir I.
AU - Zezin, A.
PY - 2019
DA - 2019/05/01 00:00:00
PB - Elsevier
SP - 115-121
VL - 158
SN - 0969-806X
ER -
BibTex
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BibTex Copy
@article{2019_Zezina,
author = {Elena Zezina and Artem M. Emel’yanov and Alexander S. Pozdnyakov and Galina F Prozorova and Sergei S Abramchuk and Vladimir I. Feldman and A. Zezin},
title = {Radiation-induced synthesis of copper nanostructures in the films of interpolymer complexes},
journal = {Radiation Physics and Chemistry},
year = {2019},
volume = {158},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016%2Fj.radphyschem.2019.01.019},
pages = {115--121},
doi = {10.1016/j.radphyschem.2019.01.019}
}
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